NOVEL HETEROARYL-TRIAZOLE AND HETEROARYL-TETRAZOLE COMPOUNDS AS PESTICIDESThe present invention relates to novel heteroaryl-triazole and heteroaryl-tetrazole compounds of the general formula (I), in which the structural elements Y, Q1, Q2, R1, R2, R3, R4 and R5 have the meaning given in the description, to formulations and compositions comprising such compounds and for their use in the control of animal pests including arthropods and insects in plant protection and to their use for control of ectoparasites on animals.A compound of formula (i)whereinx is o or s;q1and q2independently is cr5or n, provided that q1and q2at least one of which is n;y is a direct bond or ch2；r1is hydrogen; optionally substituted by one selected from-cn, -conh2、-cooh、-no2and-si (ch)3)3c substituted by a substituent of1-c6an alkyl group; c1-c6a haloalkyl group; c2-c6an alkenyl group; c2-c6a haloalkenyl group; c2-c6an alkynyl group; c2-c6a haloalkynyl group; c3-c4cycloalkyl-c1-c2alkyl-, wherein said c3-c4cycloalkyl is optionally substituted with 1 or 2 halogen atoms; optionally substituted by halogen atoms or c 1-c3haloalkyl-substituted oxetan-3-yl-ch2-or benzyl;r2is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, wherein the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is optionally substituted with 1 to 3 substituents, provided that the substituents are not on any carbon adjacent to the carbon bonded to the c ═ x 'group, each substituent being independently selected from c1-c3alkyl radical, c1-c3haloalkyl, c1-c3haloalkylthio, c1-c3alkoxy radical, c1-c3haloalkoxy, halogen, -no2、-sf5、-cn、-conh2-cooh and-c (s) nh2；r3is c1-c3alkyl or c1-c3a haloalkyl group;r4is pyridine, pyrimidine, pyrazine or pyridazine, wherein the pyridine, pyrimidine, pyrazine or pyridazine is substituted with 2 to 3 substituents independently selected from the group consisting of:halogen, hydroxy and ketonecn、-cooh、-so2nh2、-conh2、-csnh2、-no2、-sf5、-nh2；and in each case optionally substituted c1-c6alkyl radical, c3-c6cycloalkyl radical, c1-c6haloalkyl, c1-c6alkoxy radical, c1-c6haloalkoxy, c1-c6alkylthio radical, c1-c6alkylsulfinyl radical, c1-c6alkylsulfonyl radical, c3-c6cycloalkyl sulfanyl, c3-c6cycloalkyl sulfinyl radical, c3-c6cycloalkylsulfonyl radical, c1-c6haloalkylthio, c1-c6haloalkylsulfinyl radical, c1-c6haloalkylsulfonyl, -nh (c)1-c6alkyl), -n (c)1-c6alkyl radical)2、-nhco-c1-c6alkyl, -n (c)1-c6alkyl) co-c1-c6alkyl, -co2c1-c6alkyl, -conh (c) 1-c6alkyl), -con (c)1-c6alkyl radical)2、-c(＝noc1-c6alkyl) h, -c (═ noc)1-c6alkyl) -c1-c6alkyl, phenyl and 5 to 6 membered heteroaryl;orr4is pyridine, pyrimidine, pyrazine or pyridazine, wherein the pyridine, pyrimidine, pyrazine or pyridazine is substituted with a total of 1 to 3 substituents, provided that at least 1 and up to 3 substituents are independently selected from group a consisting of:-cn、-cooh、-so2nh2、-conh2、-csnh2、-no2、-sf5、-nh2substituted c3-c4a cycloalkyl group;and c1-c3alkyl and c1-c3alkoxy, both substituted with 1 to 3 substituents independently selected from:-nh2、-oh、-no2、-cn、-sh、co2c1-c4alkyl, -conh2、sf5、-so2nh2、c3-c4cycloalkyl radical, c2-c4alkenyl radical, c5-c6cycloalkenyl radical, c2-c4alkynyl, -nh (c)1-c6alkyl), -n (c)1-c6alkyl radical)2、n-c1-c4alkanoylamino, c1-c4alkoxy radical, c1-c4haloalkoxy, c2-c4alkenyloxy radical, c2-c4alkynyloxy, c3-c4cycloalkoxy, c5-c6cycloalkenyloxy, c1-c4alkoxycarbonyl group, c2-c4alkenyloxycarbonyl radical, c2-c4alkynyloxycarbonyl group, c6-、c10-、c14-aryloxycarbonyl group, c1-c4alkanoyl radical, c2-c4alkenylcarbonyl group, c2-c4alkynyl carbonyl group, c6-、c10-、c14-arylcarbonyl group, c1-c4alkylthio radical, c1-c4haloalkylthio, c3-c4cycloalkylthio radical, c2-c4alkenylthio radical, c5-c6cycloalkenylthio group, c2-c4alkynylthio, c1-c4alkylsulfinyl radical, c1-c4haloalkylsulfinyl radical, c1-c4alkylsulfonyl radical, c1-c4haloalkylsulfonyl, -so2-nh(c1-c6alkyl), -so2-n(c1-c6alkyl radical)2、c1-c4alkyl phosphinyl group, c1-c4alkylphosphono, n-c 1-c4alkylaminocarbonyl, n-di-c1-c4alkylaminocarbonyl, n-c1-c4alkanoylaminocarbonyl, n-c1-c4alkanoyl-n-c1-c4alkylaminocarbonyl radical, c6-、c10-、c14-aryl, c6-、c10-、c14aryloxy, benzyl, benzyloxy, benzylthio, c6-、c10-、c14-arylthio group, c6-、c10-、c14arylamino, benzylamino, heterocyclyl, heteroaryl and trialkylsilyl groups, and substituents bonded by double bonds, such as c1-c4alkylene (e.g., methylene or ethylene), oxo, imino, and substituted imino;and in each case optionally substituted-co2-c1-c6alkyl radical, c5-c6cycloalkyl radical, c4-c6alkyl radical, c4-c6haloalkyl, c4-c6alkoxy radical, c1-c6haloalkoxy, c1-c6alkylthio radical, c1-c6alkylsulfinyl radical, c1-c6alkylsulfonyl radical, c3-c6cycloalkyl sulfanyl, c3-c6cycloalkyl sulfinyl radical, c3-c6cycloalkylsulfonyl radical, c1-c6haloalkylthio, c1-c6haloalkylsulfinyl radical, c1-c6haloalkylsulfonyl group, c2-c4alkenylsulfanyl, c2-c4alkenylsulfinyl, c2-c4alkenylsulfonyl radical, c2-c4alkynyl thioalkyl, c2-c4alkynylsulfinyl group, c2-c4alkynylsulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, s-c1-c6alkyl sulfinyl, s-c3-c6cycloalkyl sulfinato, s-c2-c6alkenylsulfinimidoyl, s-c 2-c6alkynyl sulfinato, s-phenyl sulfinato, s-c1-c6alkyl sulfonyl imide acyl, s-c3-c6cycloalkyl sulfonylimidoyl, s-c2-c6alkenyl sulfonyl imide acyl, s-c2-c6alkynyl sulfonyl imide acyl,s-phenylsulfonylimidoyl, -nh (c)1-c6alkyl), -n (c)1-c6alkyl radical)2、-nhco-c1-c6alkyl, -n (c)1-c6alkyl) co-c1-c6alkyl, -n (c)3-c6cycloalkyl) co-c1-c6alkyl, -nhco-c3-c6cycloalkyl, -nhco-c1-c6alkyl-c3-c6cycloalkyl, -n (c)1-...
살충제로서의 신규 헤테로아릴-트리아졸 및 헤테로아릴-테트라졸 화합물본 발명은 화학식 (I)의 신규 헤테로아릴-트리아졸 및 헤테로아릴-테트라졸 화합물, 이러한 화합물을 포함하는 제제 및 조성물, 및 식물 보호에서 절지동물 및 곤충을 포함한 동물 해충의 방제에서의 그의 용도, 및 동물 상의 외부기생충의 방제를 위한 그의 용도에 관한 것이다.[이미지] 여기서 구조적 요소 Y, Q1, Q2, R1, R2, R3, R4 및 R5는 명세서에 주어진 의미를 갖는다.하기 화학식 (I)의 화합물.[이미지]여기서X는 O 또는 S이고;Q1 및 Q2는 독립적으로 CR5 또는 N이고, 단 Q1 및 Q2 중 적어도 1개는 N이고;Y는 직접 결합 또는 CH2이고;R1은 수소; -CN, -CONH2, -COOH, -NO2 및 -Si(CH3)3으로부터 선택된 1개의 치환기로 임의로 치환된 C1-C6알킬; C1-C6할로알킬; C2-C6알케닐; C2-C6할로알케닐; C2-C6알키닐; C2-C6할로알키닐; C3-C4시클로알킬-C1-C2알킬- (여기서 C3-C4시클로알킬은 1 또는 2개의 할로겐 원자로 임의로 치환됨); 옥세탄-3-일-CH2-; 또는 할로겐 원자 또는 C1-C3할로알킬로 임의로 치환된 벤질이고;R2는 페닐, 피리딘, 피리미딘, 피라진 또는 피리다진이고, 여기서 페닐, 피리딘, 피리미딘, 피라진 또는 피리다진은 1 내지 3개의 치환기로 임의로 치환되고, 단 치환기(들)는 C=X-기에 결합된 탄소와 인접한 탄소 상에는 존재하지 않고, 각각은 독립적으로 C1-C3알킬, C1-C3할로알킬, C1-C3할로알킬티오, C1-C3알콕시, C1-C3할로알콕시, 할로겐, -NO2, -SF5, -CN, -CONH2, -COOH 및 -C(S)NH2로 이루어진 군으로부터 선택되고;R3은 C1-C3알킬 또는 C1-C3할로알킬이고;R4는 피리딘, 피리미딘, 피라진 또는 피리다진이고, 여기서 피리딘, 피리미딘, 피라진 또는 피리다진은 하기로 이루어진 군으로부터 독립적으로 선택된 2 내지 3개의 치환기로 치환되거나:할로겐, 히드록시, -CN, -COOH, -SO2NH2, -CONH2, -CSNH2, -NO2, -SF5, -NH2;및 각 경우에 임의로 치환된 C1-C6알킬, C3-C6시클로알킬, C1-C6할로알킬, C1-C6알콕시, C1-C6할로알콕시, C1-C6알킬티오, C1-C6알킬술피닐, C1-C6알킬술포닐, C3-C6시클로알킬술파닐, C3-C6시클로알킬술피닐, C3-C6시클로알킬술포닐, C1-C6할로알킬티오, C1-C6할로알킬술피닐, C1-C6할로알킬술포닐, -NH(C1-C6알킬), -N(C1-C6알킬)2, -NHCO-C1-C6알킬, -N(C1-C6알킬)CO-C1-C6알킬, -CO2C1-C6알킬, -CONH(C1-C6알킬), -CON(C1-C6알킬)2, -C(=NOC1-C6알킬)H, -C(=NOC1-C6알킬)-C1-C6알킬, 페닐 및 5- 내지 6-원 헤테로아릴;또는R4는 피리딘, 피리미딘, 피라진 또는 피리다진이고, 여기서 피리딘, 피리미딘, 피라진 또는 피리다진은 총 1 내지 3개의 치환기(들)로 치환되고, 단 적어도 1개 및 최대 3개의 치환기(들)는 독립적으로 하기로 이루어진 A군으로부터 선택되고:-CN, -COOH, -SO2NH2, -CONH2, -CSNH2, -NO2, -SF5, -NH2, 치환된 C3-C4시클로알킬;및 C1-C3알킬 및 C1-C3알콕시, 둘 다 하기로 이루어진 군으로부터 독립적으로 선택된 1 내지 3개의 치환기로 치환됨: -NH2, -OH, -NO2, -CN, -SH, CO2C1-C4알킬, -CONH2, SF5, -SO2NH2, C3-C4시클로알킬, C2-C4알케닐, C5-C6시클로알케닐, C2-C4알키닐, -NH(C1-C6알킬), -N(C1-C6알킬)2, N-C1-C4알카노일아미노, C1-C4알콕시, C1-C4할로알콕시, C2-C4알케닐옥시, C2-C4알키닐옥시, C3-C4시클로알콕시, C5-C6시클로알케닐옥시, C1-C4알콕시카르보닐, C2-C4알케닐옥시카르보닐, C2-C4알키닐옥시카르보닐, C6-,C10-,C14-아릴옥시카르보닐, C1-C4알카노일, C2-C4알케닐카르보닐, C2-C4알키닐카르보닐, C6-,C10-,C14-아릴카르보닐, C1-C4알킬티오, C1-C4할로알킬티오, C3-C4시클로알킬티오, C2-C4알케닐티오, C5-C6시클로알케닐티오, C2-C4알키닐티오, C1-C4알킬술피닐, C1-C4할로알킬술피닐, C1-C4알킬술포닐, C1-C4할로알킬술포닐, -SO2-NH(C1-C6알킬), -SO2-N(C1-C6알킬)2, C1-C4알킬포스피닐, C1-C4알킬포스포닐, N-C1-C4알킬아미노카르보닐, N,N-디-C1-C4알킬아미노카르보닐, N-C1-C4알카노일아미노카르보닐, N-C1-C4알카노일-N-C1-C4알킬아미노카르보닐, C6-,C10-,C14-아릴, C6-,C10-,C14-아릴옥시, 벤질, 벤질옥시, 벤질티오, C6-,C10-,C14-아릴티오, C6-,C10-,C14-아릴아미노, 벤질아미노, 헤테로시클릴, 헤테로아릴 및 트리알킬실릴, 및 이중 결합을 통해 결합된 치환기, 예컨대 C1-C4알킬리덴 (예를 들어, 메틸리덴 또는 에틸리덴), 옥소 기, 이미노 기 및 치환된 이미노 기;및 각 경우에 임의로 치환된 -CO2-C1-C6알킬, C5-C6시클로알킬, C4-C6알킬, C4-C6할로알킬, C4-C6알콕시, C1-C6할로알콕시, C1-C6알킬티오, C1-C6알킬술피닐, C1-C6알킬술포닐, C3-C6시클로알킬술파닐, C3-C6시클로알킬술피닐, C3-C6시클로알킬술포닐, C1-C6할로알킬티오, C1-C6할로알킬술피닐, C1-C6할로알킬술포닐, C2-C4알케닐술파닐, C2-C4알케닐술피닐, C2-C4알케닐술포닐, C2-C4알키닐술파닐, C2-C4알키닐술피닐, C2-C4알키닐술포닐, 페닐술파닐, 페닐술피닐, 페닐술포닐, S-C1-C6알킬술핀이미도일, S-C3-C6시클로알킬술핀이미도일, S-C2-C6알케닐술핀이미도일, S-C2-C6알키닐술핀이미도일, S-페닐술핀이미도일, S-C1-C6알킬술폰이미도일, S-C3-C6시클로알킬술폰이미도일, S-C2-C6알케닐술폰이미도일, S-C2-C6알키닐술폰이미도일, S-페닐술폰이미도일, -NH(C1-C6알킬), -N(C1-C6알킬)2, -NHCO-C1-C6알킬, -N(C1-C6알킬)CO-C1-C6알킬, -N(C3-C6시클로알킬)CO-C1-C6알킬, -NHCO-C3-C6시클로알킬, -NHCO-C1-C6알킬-C3-C6시클로알킬, -N(C1-C6알킬)CO-(C3-C6시클로알킬), -N(C3-C6시클로알킬)CO-(C3-C6시클로알킬), -N(C1-C6알킬)CO-페닐, -N(C3-C6시클로알킬)CO-페닐, -NHCO-페닐, -N(CO-C1-C6알킬)2, -N(CO-C3-C6시클로알킬)2, -N(CO-페닐)2, -N(CO-C3-C6시클로알킬)(CO-C1-C6알킬), -N(CO-C3-C6시클로알킬)(CO-페닐), -N(CO-C1-C6알킬)(CO-페닐), -CONH(C1-C6알킬), -CON(C1-C6알킬)2, -CONH(C3-C6시클로알킬), -CON(C1-C6알킬)(C3-C6시클로알킬), -CON(C3-C6시클로알킬)2, -CONH-SO2-C1-C6알킬, -CONH-SO2-페닐, -CONH-SO2-(C3-C6시클로알킬), -CON(C1-C6알킬)-SO2-C1-C6알킬, -CON(C1-C6알킬)-SO2-페닐, -CON(C1-C6알킬)-SO2-(C3-C6시클로알킬), -CONH-페닐, -CON(C1-C6알킬)페닐, -CON(C3-C6시클로알킬)페닐, -N(SO2C1-C6알킬)2, -N(SO2C1-C6할로알킬)2, -N(SO2C3-C6시클로알킬)2, -N(SO2C1-C6알킬)SO2-페닐, -N(SO2C3-C6시클로알킬)SO2-페닐, -NHSO2-C1-C6알킬, -NHSO2-C1-C6할로알킬, -N(C1-C6알킬)SO2-C1-C6알킬, -N(C3-C6시클로알킬)SO2-C1-C6알킬, -NHSO2-페닐, -N(C1-C6알킬)SO2-페닐, -N(C3-C6시클로알킬)SO2-페닐, -NHSO2-C3-C6시클로알킬, -N(C1-C6알킬)SO2-(C3-C6시클로알킬), -N(C3-C6시클로알킬)SO2-(C3-C6시클로알킬), -SO2NH(C1-C6알킬), -SO2N(C1-C6알킬)2, -SO2N(C1-C6알킬)(C3-C6시클로알킬), -SO2NH(C3-C6시클로알킬), -SO2N(C3-C6시클로알킬)2, -SO2NH(페닐), -SO2N(C1-C6알킬)(페닐), -SO2N(C1-C4시클로알킬)(페닐), -NHCS-C1-C6알킬, -N(C1-C6알킬)CS-C1-C6알킬, -N(C3-C6시클로알킬)CS-C1-C6알킬, -NHCS-C3-C6시클로알킬, -N(C1-C6알킬)CS-(C3-C6시클로알킬), -N(C3-C6시클로알킬)CS-(C3-C6시클로알킬), -N(C1-C6알킬)CS-페닐, -N(C3-C6시클로알킬)CS-페닐, -NHCS-페닐, -CSNH(C1-C6알킬), -CSN(C1-C6알킬)2, -CSNH(C3-C6시클로알킬), -CSN(C1-C6알킬)(C3-C6시클로알킬), -CSN(C3-C6시클로알킬)2, -CSNH-페닐, -CSN(C1-C6알킬)페닐, -CSN(C3-C6시클로알킬)페닐, -C(=NOC1-C6알킬)H, -C(=NOC1-C6알킬)-C1-C6알킬, 페닐 및 5- 내지 6-원 헤테로아릴;다른 1 내지 2개의 임의적인 치환기(들)는 각각 독립적으로 하기로 이루어진 B군으로부터 선택되거나:할로겐, 히드록시, -CN, -COOH, -CONH2, -NO2, -NH2;및 각 경우에 임의로 치환된 C1-C6알킬, C3-C6시클로알킬, C1-C6할로알킬, C1-C6알콕시, C1-C6할로알콕시, C1-C6알킬티오, C1-C6알킬술피닐, C1-C6알킬술포닐, C1-C6할로알킬티오, C1-C6할로알킬술피닐, C1-C6할로알킬술포닐, -NH(C1-C6알킬), -N(C1-C6알킬)2, -NHCO-C1-C6알킬, -N(C1-C6알킬)CO-C1-C6알킬, -CO2C1-C6알킬, -CONH(C1-C6알킬), -CON(C1-C6알킬)2, -C(=NOC1-C6알킬)H, -C(=NOC1-C6알킬)-C1-C6알킬, 페닐 및 5- 내지 6-원 헤테로아릴;또는R4는 하기로 이루어진 군으로부터 독립적으로 선택된 1 내지 3개의 치환기로 임의로 치환된 5-원 헤테로아릴이거나:할로겐, 히드록시, -CN, -COOH, -CONH2, -CSNH2, -SO2NH2, -NO2, -SF5, -NH2;및 각 경우에 임의로 치환된 -CO2-C1-C6알킬, C1-C6알킬, C3-C6시클로알킬, C1-C6할로알킬, C1-C6알콕시, C1-C6할로알콕시, C1-C6알킬티오, C1-C6알킬술피닐, C1-C6알킬술포닐, C3-C6시클로알킬술파닐, C3-C6시클로알킬술피닐, C3-C6시클로...