Pesticidal mixtures comprising cyanosulfoximine compoundsThe present invention relates to pesticidal mixtures comprising as active components 1 ) at least one cyanosulfoximine compound I of the formula ( I ) wherein R1, R2 and G are defined as in the description; and 2) at least one fungicidal compounds Il selected from azoles, strobilurins, carboxamides, carbamates, heterocyclic and various other compounds as defined in the description, in synergistically effective amounts. The invention relates further to methods and use of these mixtures for combating insects, arachnids or nematodes and harmful fungis in and on plants, and for protecting such plants being infested with pests, especially also for protecting seeds.The pesticide combination that comprises at least two kinds of reactive compounds with the synergistic effective dose, wherein:1) at least a reactive compound i cyanosulfoximine compounds that is formula i:formula (i) whereing is selected from:and wherein # is meant connecting key in formula i;r 1be cl or cf 3withr 2be selected from hydrogen, chlorine, ch 3or c 2h 5or its enantiomter or diastereoisomer, be the pure or form of mixtures of these enantiomters and/or diastereoisomer;with2) at least a reactive compound ii is the fungicidal compounds that is selected from group ii.a-ii.f:the ii.a azole, as triazole type, imidazoles, pyrazoles, thiazoles is with the oxazole class, it is selected from penta ring bacterium, benomyl, bitertanol, bromuconazole, carbendazim, cyproconazole, cyanogen frost azoles difenoconazole, alkene azoles alcohol, alkene azoles alcohol m, imazalil, oxole bacterium, guardian, kobam, fluquinconazole, rh-7592, flusilazole, flutriafol, furidazol, own azoles alcohol, hydroxyisoxazole, imazalil, imazalil sulphate, the acid amides azoles, cycltebuconazole, encircle penta azoles bacterium, nitrile bacterium azoles, oxpoconazol, paclobutrazol, pefurazoate, penconazole, prochloraz, propiconazole, prothioconazoles, simeconazoles, triazolone, triadimenol, tebuconazole, fluorine ether azoles, thiabendazole, triticonazole, fluorine bacterium azoles, uniconazole p, 1-(4-chloro-phenyl)-2-([1,2,4] triazol-1-yl)-suberol;ii.b is selected from following strobilurins class: the nitrile fluoxastrobin, ether bacterium amine, enestroburin, fluoxastrobin, the imines bacterium, fork phenalgin acid amides, orysastrobin, pyridine oxygen bacterium, pyraclostrobin, pyribencarb, oxime bacterium ester, 2-(neighbour-(2,5-dimethyl phenoxy methylene) phenyl)-3-methoxy-methyl acrylate, 2-(2-(6-(3-chloro-2-methyl-phenoxy group)-5-fluoro-pyrimidine-4-base oxygen base)-phenyl)-2-methoxyimino-n-methyl-acetamide and 3-methoxyl group-2-(2-(n-(4-methoxyl group-phenyl)-cyclopropane formyl imines sulfidomethyl)-phenyl)-methyl acrylate;ii.c is selected from following carboxylic acid amides: m 9834, smart m 9834, benodanil, bixafen, boscalid, carboxin, carpropamide, dimethomorph, two chlorine zarilamids, fenhexamid, fluorine pyrrole bacterium acid amides, flutolanil, the spirit of furan pyrazoles, flumorph, fluorine biphenyl bacterium, fluorine pyrrole bacterium amine, isopyrazam, mandipropamid amine, third oxygen embroidery amine that goes out, metalaxyl, metalaxyl-m, the spirit of fenfuram evil frost, oxycarboxin, terramycin, the pyrrole metsulfovax, the silicon metsulfovax, thifluzamide, tiadinil, zoxamide, 5-fluoro-1, the 3-dimethyl-[2-(1 for 1h-pyrazoles-4-formic acid, 2-dimethyl-propyl group)-phenyl]-acid amides, 3-(4-chlorphenyl)-3-(2-isopropoxy carbonyl amino-3-methylbutyryl base amino) methyl propionate, 2-chloro-n-(1,1,3-trimethyl-1,2-dihydroindene-4-yl)-vitamin pp, n-(3-ethyl-3,5-5-trimethyl-cyclohexyl)-3-formoxyl amino-2-hydroxyl-benzamide, n-(2-{4-[3-(4-chlorphenyl) propargyl oxygen base]-the 3-methoxyphenyl } ethyl)-2-methane sulfonyl amino-3-methylbutyryl amine, n-(2-{4-[3-(4-chlorphenyl)-propargyl oxygen base]-the 3-methoxyphenyl } ethyl)-2-ethane sulfuryl amino-3-methyl-butyramide, n-(6-methoxyl group-pyridin-3-yl) cyclopropane-formamide, 2-amino-4-methyl-thiazole-5-formamide, n-(2-cyano-phenyl)-3,4-two chloroisothiazoles-5-formamide, n-(4 '-bromo biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, n-(4 '-trifluoromethyl-biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, n-(4 '-chloro-3 '-fluorine biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, n-(4 '-bromo biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, n-(4 '-trifluoromethyl-biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, n-(4 '-chloro-3 '-fluorine biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, n-(3 ', 4 '-two chloro-4-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide, n-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide; n-(3 ', 4 '-two chloro-4-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide, n-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide, (2-(1 for n-, the 3-dimethylbutyl)-and phenyl)-1,3-dimethyl-5-fluoro-1h-pyrazole-4-carboxamide, n-(4 '-chloro-3 ', 5-two fluoro-biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(4 '-chloro-3 ', 5-two fluoro-biphenyl-2-yl)-3-trifluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(3 ', 4 '-two chloro-5-fluoro-biphenyl-2-yls)-3-trifluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(3 ', 5-two fluoro-4 '-methyl-biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(3 ', 5-two fluoro-4 '-methyl-biphenyl-2-yl)-3-trifluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(suitable-2-dicyclo third-2-base-phenyl)-3-d...
시아노술폭시민 화합물을 포함하는 살충 혼합물본 발명은 활성 성분으로서 1) 화학식 I의 1종 이상의 시아노술폭시민 화합물 I; 및 2) 아졸, 스트로빌루린, 카르복스아미드, 카르바메이트, 헤테로시클릭 및 명세서에 정의된 다양한 기타 화합물로부터 선택되는 1종 이상의 살진균 화합물 II를 상승작용적 유효량으로 포함하는 살충 혼합물에 관한 것이다. [화학식 I]  (상기 식에서, R1, R2 및 G는 명세서에서 정의된 바와 같다.) 본 발명은 또한 식물 내 및 상에서 곤충류, 거미류 또는 선충류 및 유해 진균을 퇴치하고, 해충으로 감염된 상기 식물을 보호하고, 특히 또한 종자를 보호하기 위한 방법 및 상기 혼합물의 용도에 관한 것이다.1) 하기 화학식 I의 시아노술폭시민 화합물 또는 이의 순수 거울상이성질체 또는 부분입체이성질체 또는 이들 거울상이성질체 및/또는 부분입체이성질체의 혼합물인 1종 이상의 활성 화합물 I, 및2) 하기 II.A 내지 II.F 군으로부터 선택되는 살진균 화합물인 1종 이상의 활성 화합물 II의 적어도 2종의 활성 화합물을 상승작용적 유효량으로 포함하는 살충 혼합물.[화학식 I][이미지](상기 식에서, G는 [이미지] 또는 [이미지] 로부터 선택되고, 여기서, #은 화학식 I에서의 결합을 나타내고,R1은 Cl 또는 CF3이고,R2는 수소, 클로로, CH3 또는 C2H5로부터 선택됨);II.A 아자코나졸, 베노밀, 비테르타놀, 브로무코나졸, 카르벤다짐, 시프로코나졸, 시아조파미드, 디페노코나졸, 디니코나졸, 디니코나졸-M, 에닐코나졸, 에폭시코나졸, 에타복삼, 에트리디아졸, 플루퀸코나졸, 펜부코나졸, 풀루실라졸, 플루트리아폴, 푸베리다졸, 헥사코나졸, 히멕사졸, 이마잘릴, 이마잘릴-술페이트, 이미벤코나졸, 이프코나졸, 메트코나졸, 미클로부타닐, 옥스포코나졸, 파클로부트라졸, 페푸라조에이트, 펜코나졸, 프로클로라즈, 프로피코나졸, 프로티오코나졸, 시메코나졸, 트리아디메폰, 트리아디메놀, 테부코나졸, 테트라코나졸, 티아벤다졸, 트리티코나졸, 트리플루미졸, 유니코나졸 및 1-(4-클로로페닐)-2-([1,2,4]트리아졸-1-일)-시클로헵탄올로 이루어진 군으로부터 선택되는 트리아졸, 이미다졸, 피라졸, 티아졸 및 옥사졸과 같은 아졸;II.B 아족시스트로빈, 디목시스트로빈, 에네스트로부린, 플루옥사스트로빈, 크레속심-메틸, 메토미노스트로빈, 오리사스트로빈, 피콕시스트로빈, 피라클로스트로빈, 피리벤카르브, 트리플록시스트로빈, 메틸 2-(오르토-(2,5-디메틸페닐옥시메틸렌)페닐)-3-메톡시-아크릴레이트, 2-(2-(6-(3-클로로-2-메틸-페녹시)-5-플루오로-피리미딘-4-일옥시)-페닐)-2-메톡시이미노-N-메틸-아세트아미드 및 3-메톡시-2-(2-(N-(4-메톡시-페닐)-시클로-프로판카르복스이미도일술파닐메틸)-페닐)-아크릴산 메틸 에스테르로 이루어진 군으로부터 선택되는 스트로빌루린;II.C 베날락실, 베날락실-M, 베노다닐, 빅사펜, 보스칼리드, 카르복신, 카르프로파미드, 디메토모르프, 디클로시메트, 펜헥사미드, 플루오피람, 풀루톨라닐, 푸라메트피르, 플루모르프, 플루메토베르, 플루오피콜리드(피코벤즈아미드), [이미지], 만디프로파미드, 메프로닐, 메탈락실, 메페녹삼, 오푸라세, 옥사딕실, 옥시카르복신, 옥시테트라시클린, 펜티오피라드, 실티오팜, 티플루자미드, 티아디닐, 족스아미드, 5-플루오로-1,3-디메틸-1H-피라졸-4-카르복실산 [2-(1,2-디메틸-프로필)-페닐]-아미드, 메틸-3-(4-클로로페닐)-3-(2-이소프로폭시카르보닐아미노-3-메틸부티릴아미노)프로피오네이트, 2-클로로-N-(1,1,3-트리메틸-인단-4-일)-니코틴아미드, N-(3-에틸-3,5-5-트리메틸-시클로헥실)-3-포르밀아미노-2-히드록시-벤즈아미드, N-(2-{4-[3-(4-클로로페닐)프로프-2-이닐옥시]-3-메톡시페닐}에틸)-2-메탄술포닐아미노-3-메틸부티르아미드, N-(2-{4-[3-(4-클로로페닐)-프로프-2-이닐옥시]-3-메톡시페닐}에틸)-2-에탄술포닐아미노-3-메틸-부티르아미드, N-(6-메톡시-피리딘-3-일)시클로프로판-카르복스아미드, 2-아미노-4-메틸-티아졸-5-카르복스아미드, N-(2-시아노페닐)-3,4-디클로로이소티아졸-5-카르복스아미드, N-(4'-브로모바이페닐-2-일)-4-디플루오로메틸-2-메틸티아졸-5-카르복스아미드, N-(4'-트리플루오로메틸바이페닐-2-일)-4-디플루오로메틸-2-메틸티아졸-5-카르복스아미드, N-(4'-클로로-3'-플루오로바이페닐-2-일)-4-디플루오로메틸-2-메틸티아졸-5-카르복스아미드, N-(4'-브로모바이페닐-2-일)-4-디플루오로메틸-2-메틸티아졸-5-카르복스아미드, N-(4'-트리플루오로메틸바이페닐-2-일)-4-디플루오로메틸-2-메틸티아졸-5-카르복스아미드, N-(4'-클로로-3'-플루오로바이페닐-2-일)-4-디플루오로메틸-2-메틸티아졸-5-카르복스아미드, N-(3',4'-디클로로-4-플루오로바이페닐-2-일)-3-디플루오로메틸-1-메틸피라졸-4-카르복스아미드, N-(3',4'-디클로로-5-플루오로바이페닐-2-일)-3-디플루오로메틸-1-메틸피라졸-4-카르복스아미드, N-(3',4'-디클로로-4-플루오로바이페닐-2-일)-3-디플루오로메틸-1-메틸피라졸-4-카르복스아미드, N-(3',4'-디클로로-5-플루오로바이페닐-2-일)-3-디플루오로메틸-1-메틸피라졸-4-카르복스아미드, N-(2-(1,3-디메틸부틸)-페닐)-1,3-디메틸-5-플루오로-1H-피라졸-4-카르복스아미드, N-(4'-클로로-3',5-디플루오로-바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(4'-클로로-3',5-디플루오로-바이페닐-2-일)-3-트리플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3',4'-디클로로-5-플루오로-바이페닐-2-일)-3-트리플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3',5-디플루오로-4'-메틸-바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3',5-디플루오로-4'-메틸-바이페닐-2-일)-3-트리플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(시스-2-바이시클로프로필-2-일-페닐)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(트랜스-2-바이시클로프로필-2-일-페닐)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2',4'-디플루오로바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(2',4'-디클로로바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(2',4'-디플루오로바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2',4'-디클로로바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2',5'-디플루오로바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(2',5'-디클로로바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(2',5'-디플루오로바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2',5'-디클로로바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3',5'-디플루오로바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(3',5'-디클로로바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(3',5'-디플루오로바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3',5'-디클로로바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3'-플루오로바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(3'-클로로바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(3'-플루오로바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3'-클로로바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2'-플루오로바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(2'-클로로바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(2'-플루오로바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2'-클로르바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2'-플루오로-4'-클로로-5'-메틸바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(3',4',5'-트리플루오로바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(3',4',5'-트리플루오로바이페닐-2-일)-1-메틸-3-디플루오로메틸-1H-피라졸-4-카르복스아미드, N-(2',4',5'-트리플루오로바이페닐-2-일)-1-메틸-3-디플루오로메틸-1H-피라졸-4-카르복스아미드, N-(3',4',5'-트리플루오로바이페닐-2-일)-3-클로로플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-[2-(1,1,2,3,3,3-헥사플루오로프로폭시)페닐]-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-[2-(1,1,2,3,3,3-헥사플루오로프로폭시)-페닐]-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-[2-(2-클로로-1,1,2-트리플루오로에톡시)페닐]-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-[2-(2-클로르-1,1,2-트리플루오로에톡시)페닐]-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-[2-(1,1,2,2-테트라플루오로에톡시)페닐]-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-[2-(1,1,2,2-테트라플루오로에톡시)페닐]-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드, N-(4'-(트리플루오로메틸티오)바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(4'-(트리플루오로메틸티오)바이페닐-2-일)-1-메틸-3-트리플루오로메틸-1H-피라졸-4-카르복스아미드로 이루어진 군으로부터 선택되는 카르복스아미드;II.D 아시벤졸라르-S-메틸, 아닐라진, 알디모르프, 블라스티시딘-S, 부피리메이트, 캅타폴, 캅탄, 키노메티오네이트, 시프로디닐, 다조메트, 데바카르브, 디클로메진, 디펜조쿠아트, 디펜조쿠아트-메틸술페이트, 디플루메토림, 도데모르프, 도데모르프-아세테이트, 파목사돈, 페나미돈, 페나리몰, 페림존, 펜피클로닐, 펜프로피딘, 펜프로피모르프, 플루디옥소닐, 플루아지남, 플루오로이미드, [이미지], 폴페트, 페녹사닐, 이프로디온, 메파니피림, 니트라피린, 누아리몰, 옥틸리논, 옥솔린산, 피페랄린, 프로베나졸...