MOLECULES HAVING CERTAIN PESTICIDAL UTILITIES, INTERMEDIATES, COMPOSITIONS, AND PROCESSES, RELATED THERETOThis disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the following formula ("Formula One").A molecule having the following formulawherein :(A) R1, R2, R3, R4, R5, R6, R7, R9, and R10 are each independently selected from the group consisting of H, F, CI, Br, I, CN, N02, OH, (Ci-C4)alkyl, (C2-C4)alkenyl, (Ci-C4)haloalkyl, (Ci-C4)alkoxy, (Ci-C4)haloalkoxy, and (C3-C6)cycloalkyl,wherein each alkyi, alkenyl, haloalkyi, alkoxy, haloalkoxy, cycloalkyi, are optionally substituted with one or more substituents independently selected from the group consisting of H, F, CI, Br, I, CN, N02, OH, (Ci-C4)alkyl, (C2-C4)alkenyl, (Ci- C4)haloalkyl, (Ci-C4)alkoxy, (Ci-C4)haloalkoxy, and (C3-C6)cycloalkyl;(B) R8 is H ;(C) L is selected from the group consisting of(1) a bond connecting nitrogen to carbon in the ring, and (2) a (Ci)alkyl or a (C3-C4)alkyl wherein said alkyi is optionally substituted with one or more substituents independently selected from the group consisting of F, CI, CN, OH, and oxo;(D) R11 and R12 are each independently selected from the group consisting of H, (Ci-C4)alkyl, (C2-C4)alkenyl, (C2-C4)alkenyloxy, (C2-C4)alkynyl, (C2-C4)alkynyloxy, (Ci-C4)haloalkyl, (Ci-C4)alkoxy, (Ci-C4)haloalkoxy, (C3-C6)cycloalkyl, (C3-C6)cycloalkoxy, (C3-C6)cycloalkenyl, (C3-C6)cycloalkenyloxy, ((Ci-C4)alkyl)((C3-C6)cycloalkyl), C(0)((Ci- C4)alkyl), ((Ci-C4)alkyl)C(0)((Ci-C4)alkyl), ((Ci-C4)alkyl)C(0)0((Ci-C4)alkyl), and C(S)NH2,wherein each alkyi, alkenyl, alkenyloxy, alkynyl, alkynyloxy, haloalkyi, alkoxy, haloalkoxy, cycloalkyi, cycloalkoxy, cydoalkenyl, and cydoalkenyloxy, are optionally substituted with one or more substituents independently selected from the group consisting of H, F, CI, Br, I, CN, N02, OH, and oxo;(E) Xi is selected from the group consisting of N and CR13, wherein R13 is selected from the group consisting of H, F, CI, Br, I, CN, N02, OH, (Ci-C4)alkyl, (C2- C4)alkenyl, (C2-C4)alkenyloxy, (C2-C4)alkynyl, (C2-C4)alkynyloxy, (Ci-C4)haloalkyl, (Ci- C4)alkoxy, (Ci-C4)haloalkoxy, (C3-C6)cycloalkyl, (C3-C6)cycloalkoxy, (C3-C6)cycloalkenyl, and (C3-C6)cycloalkenyloxy, wherein each alkyl, alkenyl, alkenyloxy, alkynyl, alkynyloxy, haloalkyl, alkoxy, haloalkoxy, cycloalkyl, cycloalkoxy, cycloalkenyl, or cycloalkenyloxy, are optionally substituted with one or more substituents independently selected from the group consisting of H, F, CI, Br, I, CN, N02, OH, and oxo;(F) X2 is selected from the group consisting of N and CR16, wherein R16 is selected from the group consisting of (H), H, F, CI, Br, I, CN, N02, OH, (Ci-C4)alkyl, (C2- C4)alkenyl, (C2-C4)alkenyloxy, (C2-C4)alkynyl, (C2-C4)alkynyloxy, (Ci-C4)haloalkyl, (Ci- C4)alkoxy, (Ci-C4)haloalkoxy, (C3-C6)cycloalkyl, (C3-C6)cycloalkoxy, (C3-C6)cycloalkenyl, phenyl, and (C3-C6)cycloalkenyloxy,wherein each alkyl, alkenyl, alkenyloxy, alkynyl, alkynyloxy, haloalkyl, alkoxy, haloalkoxy, cycloalkyl, cycloalkoxy, cycloalkenyl, phenyl, and cycloalkenyloxy, are optionally substituted with one or more substituents independently selected from the group consisting of H, F, CI, Br, I, CN, N02, OH, and oxo;(G) R14 and R15 are each independently selected from the group consisting of (H), H, F, CI, Br, I, CN, N02, OH, (Q-CJalkyl, (Q-CJhaloalkyl, ( -GJalkoxy, (C C4)haloalkoxy, C(0)0((Ci-C4)alkyl), S((Ci-C4)alkyl), N((Ci-C4)alkyl)2, and phenyl,wherein each alkyl, alkenyl, haloalkyl, alkoxy, haloalkoxy, and phenyl, are optionally substituted with one or more substituents independently selected from the group consisting of H, F, CI, Br, I, CN, N02, OH, and oxo;(H) R15 and R16 may together be a 4-membered saturated or unsaturated, hydrocarbyl link,wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from the group consisting of H, F, CI, Br, I, CN N02, OH, (Ci-C4)alkyl, (Ci-C4)haloalkyl, and (Ci-C4)alkoxy;(I) R17 is selected from the group consisting of H, F, CI, Br, I, CN, N02, OH, (Ci-C8)alkyl, (C2-C8)alkenyl, (C2-C4)alkynyl, (C3-C6)cycloalkyl, (Ci-C4)alkoxy, (Ci- C4)haloalkyl, (Ci-C4)haloalkoxy, (Ci-C8)alkylphenyl, phenyl, and heterocyclyl,wherein each alkyl, alkenyl, alkynyl, cycloalkyl, alkoxy, haloalkyl, haloalkoxy, phenyl, and heterocyclyl, are optionally substituted with one or more substituents independently selected from the group consisting of H, F, CI, Br, I, CN, N02, OH, (Ci- C8)alkyl, (C3-C6)cycloalkyl, and S((Ci-C4)alkyl); and(J) Q is selected from the group consisting of O and S.
특정 살충 유용성을 갖는 분자, 그와 관련된 중간체, 조성물 및 방법본 개시내용은 선형동물문, 절지동물문 및/또는 연체동물문의 해충에 대해 살충 유용성을 갖는 분자, 이러한 분자를 제조하는 방법, 및 이러한 방법에 사용되는 중간체, 이러한 분자를 함유하는 조성물, 및 이러한 해충에 대해 이러한 분자를 사용하는 방법의 분야에 관한 것이다. 이들 분자는, 예를 들어 살선충제, 살진드기제, 살곤충제, 살응애제 및/또는 살연체동물제로서 사용될 수 있다. 본 문헌은 하기 화학식 ("화학식 1")을 갖는 분자를 개시한다.하기 화학식을 갖는 분자.여기서, (A) R1, R2, R3, R4, R5, R6, R7, R9, 및 R10은 각각 독립적으로 H, F, Cl, Br, I, CN, NO2, OH, (C1-C4)알킬, (C2-C4)알케닐, (C1-C4)할로알킬, (C1-C4)알콕시, (C1-C4)할로알콕시, 및 (C3-C6)시클로알킬로 이루어진 군으로부터 선택되고,여기서 각각의 알킬, 알케닐, 할로알킬, 알콕시, 할로알콕시, 시클로알킬은 H, F, Cl, Br, I, CN, NO2, OH, (C1-C4)알킬, (C2-C4)알케닐, (C1-C4)할로알킬, (C1-C4)알콕시, (C1-C4)할로알콕시, 및 (C3-C6)시클로알킬로 이루어진 군으로부터 독립적으로 선택된 1개 이상의 치환기로 임의로 치환되고; (B) R8은 H이고; (C) L은 (1) 질소를 고리 내의 탄소에 연결하는 결합, 및 (2) 알킬이 F, Cl, CN, OH, 및 옥소로 이루어진 군으로부터 독립적으로 선택된 1개 이상의 치환기로 임의로 치환된 것인 (C1)알킬 또는 (C3-C4)알킬로 이루어진 군으로부터 선택되고;(D) R11 및 R12는 각각 독립적으로 H, (C1-C4)알킬, (C2-C4)알케닐, (C2-C4)알케닐옥시, (C2-C4)알키닐, (C2-C4)알키닐옥시, (C1-C4)할로알킬, (C1-C4)알콕시, (C1-C4)할로알콕시, (C3-C6)시클로알킬, (C3-C6)시클로알콕시, (C3-C6)시클로알케닐, (C3-C6)시클로알케닐옥시, ((C1-C4)알킬)((C3-C6)시클로알킬), C(O)((C1-C4)알킬), ((C1-C4)알킬)C(O)((C1-C4)알킬), ((C1-C4)알킬)C(O)O((C1-C4)알킬), 및 C(S)NH2로 이루어진 군으로부터 선택되고,여기서 각각의 알킬, 알케닐, 알케닐옥시, 알키닐, 알키닐옥시, 할로알킬, 알콕시, 할로알콕시, 시클로알킬, 시클로알콕시, 시클로알케닐, 및 시클로알케닐옥시는 H, F, Cl, Br, I, CN, NO2, OH, 및 옥소로 이루어진 군으로부터 독립적으로 선택된 1개 이상의 치환기로 임의로 치환되고; (E) X1은 N 및 CR13으로 이루어진 군으로부터 선택되고, 여기서 R13은 H, F, Cl, Br, I, CN, NO2, OH, (C1-C4)알킬, (C2-C4)알케닐, (C2-C4)알케닐옥시, (C2-C4)알키닐, (C2-C4)알키닐옥시, (C1-C4)할로알킬, (C1-C4)알콕시, (C1-C4)할로알콕시, (C3-C6)시클로알킬, (C3-C6)시클로알콕시, (C3-C6)시클로알케닐, 및 (C3-C6)시클로알케닐옥시로 이루어진 군으로부터 선택되고,여기서 각각의 알킬, 알케닐, 알케닐옥시, 알키닐, 알키닐옥시, 할로알킬, 알콕시, 할로알콕시, 시클로알킬, 시클로알콕시, 시클로알케닐, 또는 시클로알케닐옥시는 H, F, Cl, Br, I, CN, NO2, OH, 및 옥소로 이루어진 군으로부터 독립적으로 선택된 1개 이상의 치환기로 임의로 치환되고; (F) X2는 N 및 CR16으로 이루어진 군으로부터 선택되고, 여기서 R16은 (H), H, F, Cl, Br, I, CN, NO2, OH, (C1-C4)알킬, (C2-C4)알케닐, (C2-C4)알케닐옥시, (C2-C4)알키닐, (C2-C4)알키닐옥시, (C1-C4)할로알킬, (C1-C4)알콕시, (C1-C4)할로알콕시, (C3-C6)시클로알킬, (C3-C6)시클로알콕시, (C3-C6)시클로알케닐, 페닐, 및 (C3-C6)시클로알케닐옥시로 이루어진 군으로부터 선택되고,여기서 각각의 알킬, 알케닐, 알케닐옥시, 알키닐, 알키닐옥시, 할로알킬, 알콕시, 할로알콕시, 시클로알킬, 시클로알콕시, 시클로알케닐, 페닐, 및 시클로알케닐옥시는 H, F, Cl, Br, I, CN, NO2, OH, 및 옥소로 이루어진 군으로부터 독립적으로 선택된 1개 이상의 치환기로 임의로 치환되고; (G) R14 및 R15는 각각 독립적으로 (H), H, F, Cl, Br, I, CN, NO2, OH, (C1-C4)알킬, (C1-C4)할로알킬, (C1-C4)알콕시, (C1-C4)할로알콕시, C(O)O((C1-C4)알킬), S((C1-C4)알킬), N((C1-C4)알킬)2, 및 페닐로 이루어진 군으로부터 선택되고,여기서 각각의 알킬, 알케닐, 할로알킬, 알콕시, 할로알콕시, 및 페닐은 H, F, Cl, Br, I, CN, NO2, OH, 및 옥소로 이루어진 군으로부터 독립적으로 선택된 1개 이상의 치환기로 임의로 치환되고; (H) R15 및 R16은 함께 4-원 포화 또는 불포화, 히드로카르빌 연결일 수 있고,여기서 상기 히드로카르빌 연결은 H, F, Cl, Br, I, CN NO2, OH, (C1-C4)알킬, (C1-C4)할로알킬, 및 (C1-C4)알콕시로 이루어진 군으로부터 독립적으로 선택된 1개 이상의 치환기로 임의로 치환될 수 있고; (I) R17은 H, F, Cl, Br, I, CN, NO2, OH, (C1-C8)알킬, (C2-C8)알케닐, (C2-C4)알키닐, (C3-C6)시클로알킬, (C1-C4)알콕시, (C1-C4)할로알킬, (C1-C4)할로알콕시, (C1-C8)알킬페닐, 페닐, 및 헤테로시클릴로 이루어진 군으로부터 선택되고,여기서 각각의 알킬, 알케닐, 알키닐, 시클로알킬, 알콕시, 할로알킬, 할로알콕시, 페닐, 및 헤테로시클릴은 H, F, Cl, Br, I, CN, NO2, OH, (C1-C8)알킬, (C3-C6)시클로알킬, 및 S((C1-C4)알킬)로 이루어진 군으로부터 독립적으로 선택된 1개 이상의 치환기로 임의로 치환되고; (J) Q는 O 및 S로 이루어진 군으로부터 선택된다.