PYRAZOLO [1,5-A]PYRIDINE DERIVATIVES AND THEIR USE AS PESTICIDESThe invention relates to novel compounds of formula (I), in which Q, Aa, Ab, Ac, Ad, R1 and n are defined as in the description, to the use thereof as acaricides and/or insecticides for controlling animal pests, and to methods and intermediate products for the production thereof.The compound of formula (i)whereinaa is nitrogen or=c (r10)-,ab is nitrogen or=c (r11)-,ac is nitrogen or=c (r12)-,ad is nitrogen or=c (r13)-,wherein being no more than two in aa, ab, ac and ad can be nitrogen,r1for (c1-c6)-alkyl, (c1-c6)-halogenated alkyl, (c1-c6)-cyanoalkyl, (c1-c6)-hydroxy alkyl, (c1-c6)- alkoxy-(c1-c6)-alkyl, (c1-c6)-halogenated alkoxy-(c1-c6)-alkyl, (c2-c6)-alkenyl, (c2-c6)-alkenyloxy group- (c1-c6)-alkyl, (c2-c6)-haloalkenyloxy-(c1-c6)-alkyl, (c2-c6)-halogenated alkenyl, (c2-c6)-cyano alkenyl, (c2-c6)-alkynyl, (c2-c6)-alkynyloxy group-(c1-c6)-alkyl, (c2-c6)-halogenated alkynyloxy group-(c1-c6)-alkyl, (c2-c6)- halo alkynyl, (c2-c6)-cyano alkynyl, (c3-c8)-naphthenic base, (c3-c8)-naphthenic base-(c3-c8)-naphthenic base, (c1-c6)- alkyl-(c3-c8)-naphthenic base, halogenated-(c3-c8)-naphthenic base, amino, (c1-c6)-alkyl amino, two-(c1-c6)-alkyl-ammonia base, (c3-c8)-cycloalkyl amino, (c1-c6)-alkyl-carbonyl-amino, (c1-c6)-alkylthio group-(c1-c6)-alkyl, (c1-c6)- halogenated alkylthio-(c1-c6)-alkyl, (c1-c6)-alkyl sulphinyl-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl sulfenyl base-(c1-c6)-alkyl, (c1-c6)-alkyl sulphonyl-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl sulfonyl-(c1-c6)- alkyl, (c1-c6)-alkoxy-(c1-c6)-alkylthio group-(c1-c6)-alkyl, (c1-c6)-alkoxy-(c1-c6)-alkyl asia sulphur acyl group-(c1-c6)-alkyl, (c1-c6)-alkoxy-(c1-c6)-alkyl sulphonyl-(c1-c6)-alkyl, (c1-c6)-alkyl oxycarbonyl base-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl carbonyl-(c1-c6)-alkyl, (c1-c6)-alkoxy carbonyl-(c1-c6)-alkane base, (c1-c6)-halo alkoxy carbonyl-(c1-c6)-alkyl, (c1-c6)-alkyl sulfonyl-amino, amino-sulfonyl-(c1- c6)-alkyl, (c1-c6)-alkyl amino sulfonyl-(c1-c6)-alkyl, two-(c1-c6)-alkyl amino sulfonyl-(c1-c6)- alkyl,it or is optionally identical or differently monosubstituted or polysubstituted by aryl, heteroaryl or heterocycle in each case (c1-c6)-alkyl, (c1-c6)-alkoxy, (c2-c6)-alkenyl, (c2-c6)-alkynyl, (c3-c8)-naphthenic base, wherein aryl, miscellaneous aryl or heterocycle can be respectively optionally identical or differently monosubstituted or polysubstituted by following substituent group: halogen, cyano, nitre base, hydroxyl, amino, carboxyl, carbamoyl, amino-sulfonyl, (c1-c6)-alkyl, (c3-c6)-naphthenic base, (c1-c6)-alkane oxygroup, (c1-c6)-halogenated alkyl, (c1-c6)-halogenated alkoxy, (c1-c6)-alkylthio group, (c1-c6)-alkyl sulphinyl, (c1-c6)-alkyl sulphonyl, (c1-c6)-alkyl sulfenyl imino group, (c1-c6)-alkyl sulfenyl imino group-(c1-c6)-alkane base, (c1-c6)-alkyl sulfenyl imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkyl sulfonyl imino group, (c1-c6)-alkyl sulfonylimino-(c1-c6)-alkyl, (c1-c6)-alkyl sulfonyl imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkoxy carbonyl base, (c1-c6)-alkyl-carbonyl, (c3-c6)-trialkylsilkl or benzyl, orr1it is respectively optionally identical or differently monosubstituted by following substituent group or take for aryl, heteroaryl or heterocycle more generation: halogen, cyano, nitro, hydroxyl, amino, carboxyl, carbamoyl, (c1-c6)-alkyl, (c3-c8)-naphthenic base, (c1- c6)-alkoxy, (c1-c6)-halogenated alkyl, (c1-c6)-halogenated alkoxy, (c1-c6)-alkylthio group, (c1-c6)-alkyl sulfenyl base, (c1-c6)-alkyl sulphonyl, (c1-c6)-alkyl sulfenyl imino group, (c1-c6)-alkyl sulfenyl imino group-(c1-c6)- alkyl, (c1-c6)-alkyl sulfenyl imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkyl sulfonyl imino group, (c1-c6)-alkane base sulfonylimino-(c1-c6)-alkyl, (c1-c6)-alkyl sulfonyl imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkoxy carbonyl, (c1-c6)-alkyl-carbonyl, (c3-c6)-trialkylsilkl, (=o) (only in the case where heterocycle) or (=o)2 (only in the case where heterocycle),r10、r11、r12、r13it independently is hydrogen, cyano, halogen, nitro, acetyl group, hydroxyl, amino, scn, three-(c1-c6)-alkyl silicyl, (c3-c8)-naphthenic base, (c3-c8)-naphthenic base-(c3-c8)-naphthenic base, (c1-c6)-alkyl-(c3-c8)-cycloalkanes base, halogenated-(c3-c8)-naphthenic base, (c1-c6)-alkyl, (c1-c6)-halogenated alkyl, (c1-c6)-cyanoalkyl, (c1-c6)-hydroxyl base alkyl, hydroxycarbonyl group-(c1-c6)-alkoxy, (c1-c6)-alkoxy carbonyl-(c1-c6)-alkyl, (c1-c6)-alkoxy- (c1-c6)-alkyl, (c2-c6)-alkenyl, (c2-c6)-halogenated alkenyl, (c2-c6)-cyano alkenyl, (c2-c6)-alkynyl, (c2-c6)- halo alkynyl, (c2-c6)-cyano alkynyl, (c1-c6)-alkoxy, (c1-c6)-halogenated alkoxy, (c1-c6)-cyano alkoxy, (c1-c6)-alkoxy carbonyl-(c1-c6)-alkoxy, (c1-c6)-alkoxy-(c1-c6)-alkoxy, (c1-c6)-alkyl hydroxy imino group, (c1-c6)-alkoximino, (c1-c6)-alkyl-(c1-c6)-alkoximino, (c1-c6)-halogenated alkyl- (c1-c6)-alkoximino, (c1-c6)-alkylthio group, (c1-c6)-halogenated alkylthio, (c1-c6)-alkoxy-(c1-c6)-alkane sulfenyl, (c1-c6)-alkylthio group-(c1-c6)-alkyl, (c1-c6)-alkyl sulphinyl, (c1-c6)-alkylsulfinyl, (c1-c6)-alkoxy-(c1-c6)-alkyl sulphinyl, (c1-c6)-alkyl sulphinyl-(c1-c6)-alkyl, (c1-c6)-alkane base sulfonyl, (c1-c6)-halogenated alkyl sulfonyl, (c1-c6)-alkoxy-(c1-c6)-alkyl sulphonyl, (c1-c6)-alkyl sulphur acyl group-(c1-c6)-alkyl, (c1-c6)-alkyl sulphonyl oxygroup, (c1-c6)-alkyl-carbon...
농약으로서의 피라졸로[1,5-a]피리딘 유도체본 발명은 화학식 (I)의 신규 화합물, 동물 해충을 방제하기 위한 살응애제 및/또는 살충제로서의 그의 용도, 및 그의 제조를 위한 방법 및 중간체에 관한 것이다[이미지] 상기 식에서, Q, Aa, Ab, Ac, Ad, R1 및 n은 각각 상기 정의된 바와 같다.화학식 (I)의 화합물:[이미지]상기 식에서,Aa는 질소 또는 =C(R10)-이고,Ab는 질소 또는 =C(R11)-이고,Ac는 질소 또는 =C(R12)-이고,Ad는 질소 또는 =C(R13)-이고,Aa, Ab, Ac 및 Ad의 2개 이하가 질소일 수 있고,R1은 (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-하이드록시알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C1-C6)-할로알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C3-C8)-사이클로알킬, (C3-C8)-사이클로알킬-(C3-C8)-사이클로알킬, (C1-C6)-알킬-(C3-C8)-사이클로알킬, 할로-(C3-C8)-사이클로알킬, 아미노, (C1-C6)-알킬아미노, 디-(C1-C6)-알킬-아미노, (C3-C8)-사이클로알킬아미노, (C1-C6)-알킬카보닐아미노, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-할로알킬티오-(C1-C6)-알킬, (C1-C6)-알킬설피닐-(C1-C6)-알킬, (C1-C6)-할로알킬설피닐-(C1-C6)-알킬, (C1-C6)-알킬설포닐-(C1-C6)-알킬, (C1-C6)-할로알킬설포닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬설피닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬설포닐-(C1-C6)-알킬, (C1-C6)-알킬카보닐-(C1-C6)-알킬, (C1-C6)-할로알킬카보닐-(C1-C6)-알킬, (C1-C6)-알콕시카보닐-(C1-C6)-알킬, (C1-C6)-할로알콕시카보닐-(C1-C6)-알킬, (C1-C6)-알킬설포닐아미노, 아미노설포닐-(C1-C6)-알킬, (C1-C6)-알킬아미노설포닐-(C1-C6)-알킬, 디-(C1-C6)-알킬아미노설포닐-(C1-C6)-알킬이거나,각 경우 동일하거나 상이하게 임의로 일- 또는 다-아릴-, -헤트아릴- 또는 -헤테로사이클릴-치환된 (C1-C6)-알킬, (C1-C6)-알콕시, (C2-C6)-알케닐, (C2-C6)-알키닐, (C3-C8)-사이클로알킬이고, 여기서 아릴, 헤트아릴 또는 헤테로사이클릴은 각각 할로겐, 시아노, 니트로, 하이드록실, 아미노, 카복실, 카바모일, 아미노설포닐, (C1-C6)-알킬, (C3-C6)-사이클로알킬, (C1-C6)-알콕시, (C1-C6)-할로알킬, (C1-C6)-할로알콕시, (C1-C6)-알킬티오, (C1-C6)-알킬설피닐, (C1-C6)-알킬설포닐, (C1-C6)-알킬설프이미노, (C1-C6)-알킬설프이미노-(C1-C6)-알킬, (C1-C6)-알킬설프이미노-(C2-C6)-알킬카보닐, (C1-C6)-알킬설폭스이미노, (C1-C6)-알킬설폭스이미노-(C1-C6)-알킬, (C1-C6)-알킬설폭스이미노-(C2-C6)-알킬카보닐, (C1-C6)-알콕시카보닐, (C1-C6)-알킬카보닐, (C3-C6)-트리알킬실릴 또는 벤질에 의해 동일하거나 상이하게 임의로 일- 또는 다치환될 수 있거나, 또는R1은 각각 할로겐, 시아노, 니트로, 하이드록실, 아미노, 카복실, 카바모일, (C1-C6)-알킬, (C3-C8)-사이클로알킬, (C1-C6)-알콕시, (C1-C6)-할로알킬, (C1-C6)-할로알콕시, (C1-C6)-알킬티오, (C1-C6)-알킬설피닐, (C1-C6)-알킬설포닐, (C1-C6)-알킬설프이미노, (C1-C6)-알킬설프이미노-(C1-C6)-알킬, (C1-C6)-알킬설프이미노-(C2-C6)-알킬카보닐, (C1-C6)-알킬설폭스이미노, (C1-C6)-알킬설폭스이미노-(C1-C6)-알킬, (C1-C6)-알킬설폭스이미노-(C2-C6)-알킬카보닐, (C1-C6)-알콕시카보닐, (C1-C6)-알킬카보닐, (C3-C6)-트리알킬실릴, (=O) (헤테로사이클릴의 경우에만) 및 (=O)2 (헤테로사이클릴의 경우에만)에 의해 동일하거나 상이하게 임의로 일- 또는 다치환된 아릴, 헤트아릴 또는 헤테로사이클릴이고, R10, R11, R12, R13은 독립적으로 수소, 시아노, 할로겐, 니트로, 아세틸, 하이드록실, 아미노, SCN, 트리-(C1-C6)-알킬실릴, (C3-C8)-사이클로알킬, (C3-C8)-사이클로알킬-(C3-C8)-사이클로알킬, (C1-C6)-알킬-(C3-C8)-사이클로알킬, 할로-(C3-C8)-사이클로알킬, (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-하이드록시알킬, 하이드록시카보닐-(C1-C6)-알콕시, (C1-C6)-알콕시카보닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C1-C6)-알콕시, (C1-C6)-할로알콕시, (C1-C6)-시아노알콕시, (C1-C6)-알콕시카보닐-(C1-C6)-알콕시, (C1-C6)-알콕시-(C1-C6)-알콕시, (C1-C6)-알킬하이드록시이미노, (C1-C6)-알콕시이미노, (C1-C6)-알킬-(C1-C6)-알콕시이미노, (C1-C6)-할로알킬-(C1-C6)-알콕시이미노, (C1-C6)-알킬티오, (C1-C6)-할로알킬티오, (C1-C6)-알콕시-(C1-C6)-알킬티오, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알킬설피닐, (C1-C6)-할로알킬설피닐, (C1-C6)-알콕시-(C1-C6)-알킬설피닐, (C1-C6)-알킬설피닐-(C1-C6)-알킬, (C1-C6)-알킬설포닐, (C1-C6)-할로알킬설포닐, (C1-C6)-알콕시-(C1-C6)-알킬설포닐, (C1-C6)-알킬설포닐-(C1-C6)-알킬, (C1-C6)-알킬설포닐옥시, (C1-C6)-알킬카보닐, (C1-C6)-알킬티오카보닐, (C1-C6)-할로알킬카보닐, (C1-C6)-알킬카보닐옥시, (C1-C6)-알콕시카보닐, (C1-C6)-할로알콕시카보닐, 아미노카보닐, (C1-C6)-알킬아미노카보닐, (C1-C6)-알킬아미노티오카보닐, 디-(C1-C6)-알킬아미노카보닐, 디-(C1-C6)-알킬아미노티오카보닐, (C2-C6)-알케닐아미노카보닐, 디-(C2-C6)-알케닐아미노카보닐, (C3-C8)-사이클로알킬아미노카보닐, (C1-C6)-알킬설포닐아미노, (C1-C6)-알킬아미노, 디-(C1-C6)-알킬아미노, 아미노설포닐, (C1-C6)-알킬아미노설포닐, 디-(C1-C6)-알킬아미노설포닐, (C1-C6)-알킬설폭스이미노, 아미노티오카보닐, (C1-C6)-알킬아미노티오카보닐, 디-(C1-C6)-알킬아미노티오카보닐, (C3-C8)-사이클로알킬아미노, NHCO-(C1-C6)-알킬 ((C1-C6)-알킬카보닐아미노)이거나, 각 경우 동일하거나 상이하게 임의로 일 또는 다치환된 아릴 또는 헤트아릴이고, 여기서 (헤트아릴의 경우) 적어도 하나의 카보닐 그룹이 임의로 존재할 수 있고/있거나, 가능한 치환체는 각 경우 다음과 같고: 시아노, 카복실, 할로겐, 니트로, 아세틸, 하이드록실, 아미노, SCN, 트리-(C1-C6)알킬실릴, (C3-C8)사이클로알킬, (C3-C8)사이클로알킬-(C3-C8)사이클로알킬, (C1-C6)알킬-(C3-C8)사이클로알킬, 할로(C3-C8)사이클로알킬, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)하이드록시알킬, 하이드록시카보닐-(C1-C6)-알콕시, (C1-C6)알콕시카보닐-(C1-C6)알킬, (C1-C6)알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐, (C2-C6)시아노알키닐, (C1-C6)알콕시, (C1-C6)할로알콕시, (C1-C6)시아노알콕시, (C1-C6)알콕시카보닐-(C1-C6)알콕시, (C1-C6)알콕시-(C1-C6)알콕시, (C1-C6)알킬하이드록시이미노, (C1-C6)알콕시이미노, (C1-C6)알킬-(C1-C6)알콕시이미노, (C1-C6)할로알킬-(C1-C6)알콕시이미노, (C1-C6)알킬티오, (C1-C6)할로알킬티오, (C1-C6)알콕시-(C1-C6)알킬티오, (C1-C6)알킬티오-(C1-C6)알킬, (C1-C6)알킬설피닐, (C1-C6)할로알킬설피닐, (C1-C6)알콕시-(C1-C6)알킬설피닐, (C1-C6)알킬설피닐-(C1-C6)알킬, (C1-C6)알킬설포닐, (C1-C6)할로알킬설포닐, (C1-C6)알콕시-(C1-C6)알킬설포닐, (C1-C6)알킬설포닐-(C1-C6)알킬, (C1-C6)알킬설포닐옥시, (C1-C6)알킬카보닐, (C1-C6)할로알킬카보닐, (C1-C6)알킬카보닐옥시, (C1-C6)알콕시카보닐, (C1-C6)할로알콕시카보닐, 아미노카보닐, (C1-C6)알킬아미노카보닐, 디-(C1-C6)알킬아미노카보닐, (C2-C6)알케닐아미노카보닐, 디-(C2-C6)-알케닐아미노카보닐, (C3-C8)사이클로알킬아미노카보닐, (C1-C6)알킬설포닐아미노, (C1-C6)알킬아미노, 디-(C1-C6)알킬아미노, 아미노설포닐, (C1-C6)알킬아미노설포닐, 디-(C1-C6)알킬아미노설포닐, (C1-C6)알킬설폭스이미노, 아미노티오카보닐, (C1-C6)알킬아미노티오카보닐, 디-(C1-C6)알킬아미노티오카보닐, (C3-C8)사이클로알킬아미노, (C1-C6)알킬카보닐아미노,R10, R11, R12, R13 라디칼의 1 또는 2개만이 수소 이외의 치환체이고,Q는 부분 포화 또는 포화 헤테로사이클릭 또는 헤테로방향족 8-, 9-, 10-, 11- 또는 12-원 융합 비사이클릭 또는 트리사이클릭 환 시스템이고, 여기서 적어도 하나의 카보닐 그룹이 임의로 존재할 수 있고/있거나, 환 시스템은 동일하거나 상이하게 임의로 일- 또는 다치환되고, 여기서 치환체는 시아노, 할로겐, 니트로, 아세틸, 하이드록실, 아미노, SCN, 트리-(C1-C6)-알킬실릴, (C3-C8)-사이클로알킬, (C3-C8)...