2-(het)aryl-substituted condensed heterocyclic derivatives as pest control agentsThe invention relates to novel compounds of formula (I), wherein R1, R2, R3, A1, X and n are defined as cited in the description, to the use thereof as acaricides and/or insecticides for controlling animal pests, and to methods and intermediate products for the production of the compounds.The compound of formula (i)whereina1represent nitrogen ,=n+-o-or=c-r4,r1represent (c1-c6)-alkyl, (c1-c6)-halogenated alkyl, (c1-c6)-cyanoalkyl, (c1-c6)-hydroxy alkyl, (c1- c6)-alkoxy-(c1-c6)-alkyl, (c1-c6)-halogenated alkoxy-(c1-c6)-alkyl, (c2-c6)-alkenyl, (c2-c6)-alkene oxygen base-(c1-c6)-alkyl, (c2-c6)-haloalkenyloxy-(c1-c6)-alkyl, (c2-c6)-halogenated alkenyl, (c2-c6)-cyano alkene base, (c2-c6)-alkynyl, (c2-c6)-alkynyloxy group-(c1-c6)-alkyl, (c2-c6)-halogenated alkynyloxy group-(c1-c6)-alkyl, (c2- c6)-halo alkynyl, (c2-c6)-cyano alkynyl, (c3-c8)-cycloalkyl, (c3-c8)-cycloalkyl-(c3-c8)-cycloalkyl, (c1- c6)-alkyl-(c3-c8)-cycloalkyl, halogenated-(c3-c8)-cycloalkyl, amino, (c1-c6)-alkyl amino, two-(c1-c6)-alkane base amino, (c3-c8)-cycloalkyl amino, (c1-c6)-alkyl-carbonyl-amino, (c1-c6)-alkylthio group-(c1-c6)-alkyl, (c1- c6)-halogenated alkylthio-(c1-c6)-alkyl, (c1-c6)-alkyl sulphinyl-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl is sub- sulfonyl-(c1-c6)-alkyl, (c1-c6)-alkyl sulphonyl-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl sulfonyl-(c1- c6)-alkyl, (c1-c6)-alkoxy-(c1-c6)-alkylthio group-(c1-c6)-alkyl, (c1-c6)-alkoxy-(c1-c6)-alkyl is sub- sulfonyl-(c1-c6)-alkyl, (c1-c6)-alkoxy-(c1-c6)-alkyl sulphonyl-(c1-c6)-alkyl, (c1-c6)-alkyl carbonyl-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl carbonyl-(c1-c6)-alkyl, (c1-c6)-alkoxy carbonyl-(c1-c6)- alkyl, (c1-c6)-halo alkoxy carbonyl-(c1-c6)-alkyl, (c1-c6)-alkyl sulfonyl-amino, amino-sulfonyl-(c1- c6)-alkyl, (c1-c6)-alkyl amino sulfonyl-(c1-c6)-alkyl, two-(c1-c6)-alkyl amino sulfonyl-(c1-c6)- alkyl,or it represents optionally monosubstituted or more by identical or different aryl, heteroaryl or heterocyclyl substituent in each case the following group of substitution：(c1-c6) alkyl, (c1-c6) alkoxy, (c2-c6) alkenyl, (c2-c6) alkynyl, (c3-c8) cycloalkyl, wherein aryl, heteroaryl or heterocycle are optionally monosubstituted or more by substituent group same as below or different in each case substitution：halogen, cyano, nitro, hydroxyl, amino, carboxyl, carbamoyl, amino-sulfonyl, (c1-c6) alkyl, (c3-c6) ring alkyl, (c1-c6) alkoxy, (c1-c6) halogenated alkyl, (c1-c6) halogenated alkoxy, (c1-c6) alkylthio group, (c1-c6) alkyl asia sulfonyl, (c1-c6) alkyl sulphonyl, (c1-c6) alkyl sulfonyl imido grpup, (c1-c6) alkyl sulfonyl imido grpup-(c1-c6) alkane base, (c1-c6) alkyl sulfonyl imido grpup-(c2-c6) alkyl-carbonyl, (c1-c6) alkyl sulfenyl imine base, (c1-c6) alkyl asia sulphur imide-(c1-c6) alkyl, (c1-c6) alkyl sulfenyl imine base-(c2-c6) alkyl-carbonyl, (c1-c6) alkoxy carbonyl, (c1-c6) alkyl-carbonyl, (c3-c6) trialkylsilkl or benzyl orr1represent aryl, heteroaryl or heterocycle, each in these groups is optionally by identical or different selected from following substituent group is monosubstituted or polysubstituted：halogen, cyano, nitro, hydroxyl, amino, carboxyl, carbamoyl, (c1-c6)-alkyl, (c3-c8)-cycloalkyl, (c1-c6)-alkoxy, (c1-c6)-halogenated alkyl, (c1-c6)-halogenated alkoxy, (c1-c6)-alkane sulphur base, (c1-c6)-alkyl sulphinyl, (c1-c6)-alkyl sulphonyl, (c1-c6)-alkyl sulfonyl imido grpup, (c1-c6)-alkyl sulphur imide-(c1-c6)-alkyl, (c1-c6)-alkyl sulfonyl imido grpup-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkyl sulfenyl imido grpup, (c1-c6)-alkyl sulfenyl imine base-(c1-c6)-alkyl, (c1-c6)-alkyl sulfenyl imine base-(c2-c6)-alkane base carbonyl, (c1-c6)-alkoxy carbonyl, (c1-c6)-alkyl-carbonyl, (c3-c6)-trialkylsilkl, (=o) are (only miscellaneous in the case of ring group) and (=o)2(only in the case of heterocycle),r2it represents optionally by identical or different substituent group is monosubstituted or polysubstituted saturated heterocyclic, fractional saturation heterocycle or miscellaneous aromatic ring, wherein at least one carbon atom are substituted by hetero atom, wherein at least one carbonyl optionally may be present in each case base group and/or wherein possible substituent group are in each case：hydrogen, cyano, carboxyl, halogen, nitro, acetyl group, hydroxyl, amino, scn, three-(c1-c6) aikylsilyl groups, (c1-c6) alkyl, (c1-c6) halogenated alkyl, (c1-c6) cyanoalkyl, (c1- c6) hydroxy alkyl, hydroxycarbonyl group-(c1-c6)-alkoxy, (c1-c6) alkoxy carbonyl-(c1-c6) alkyl, (c1-c6) alkoxy- (c1-c6) alkyl, (c2-c6) alkenyl, (c2-c6) halogenated alkenyl, (c2-c6) cyano alkenyl, (c2-c6) alkynyl, (c2-c6) acetylenic halide base, (c2-c6) cyano alkynyl, (c3-c6) cycloalkyl, (c3-c6) cycloalkyl-(c3-c6) cycloalkyl, (c1-c4) alkyl-(c3-c6) cycloalkyl (c1-c6) alkoxy, (c1-c6) halogenated alkoxy, (c1-c6) cyano alkoxy, (c1-c6) alkoxy carbonyl-(c1- c6) alkoxy, (c1-c6) alkoxy-(c1-c6) alkoxy, (c1-c6) alkoximino ,-n=c (h)-o (c1-c6) alkane base ,-c (h)=n-o (c1-c6) alkyl, (c1-c6) halogenated alkyl-(c1-c6) alkoximino, (c1-c6) alkylthio group, (c1- c6) halogenated alkylthio, (c1-c6) alkoxy-(c1-c6) alkylthio group, (c1-c6) alkylthio group-(c1-c6) alkyl, (c1-c6) alkyl asia sulfonyl, (c1-c6) alkylsulfinyl, (c1-c6) alkoxy-(c1-c6) alkyl sulphinyl, (c1-c6) alkyl asia sulphur acyl group-(c1-c6) alkyl, (c1-c6) alkyl sulpho...
해충 방제제로서의 2-(헤트)아릴-치환된 융합 헤테로사이클 유도체본 발명은 화학식 (I)의 신규 화합물, 동물 해충을 방제하기 위한 살응애제 및/또는 살충제로서의 그의 용도, 및 그의 제조를 위한 방법 및 중간체에 관한 것이다[이미지] 상기 식에서, R1, R2, R3, A1, X 및 n은 각각 상기 정의된 바와 같다.화학식 (I)의 화합물:[이미지]상기 식에서, A1은 질소, =N+-O- 또는 =C-R4를 나타내고,R1은 (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-하이드록시알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C1-C6)-할로알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C3-C8)-사이클로알킬, (C3-C8)-사이클로알킬-(C3-C8)-사이클로알킬, (C1-C6)-알킬-(C3-C8)-사이클로알킬, 할로-(C3-C8)-사이클로알킬, 아미노, (C1-C6)-알킬아미노, 디-(C1-C6)-알킬아미노, (C3-C8)-사이클로알킬아미노, (C1-C6)-알킬카보닐아미노, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-할로알킬티오-(C1-C6)-알킬, (C1-C6)-알킬설피닐-(C1-C6)-알킬, (C1-C6)-할로알킬설피닐-(C1-C6)-알킬, (C1-C6)-알킬설포닐-(C1-C6)-알킬, (C1-C6)-할로알킬설포닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬설피닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬설포닐-(C1-C6)-알킬, (C1-C6)-알킬카보닐-(C1-C6)-알킬, (C1-C6)-할로알킬카보닐-(C1-C6)-알킬, (C1-C6)-알콕시카보닐-(C1-C6)-알킬, (C1-C6)-할로알콕시카보닐-(C1-C6)-알킬, (C1-C6)-알킬설포닐아미노, 아미노설포닐-(C1-C6)-알킬, (C1-C6)-알킬아미노설포닐-(C1-C6)-알킬, 디-(C1-C6)-알킬아미노설포닐-(C1-C6)-알킬을 나타내거나,각 경우 동일하거나 상이한 아릴, 헤트아릴- 또는 헤테로사이클릴 치환체에 의해 임의로 일- 또는 다치환된 다음 그룹들을 나타내고: (C1-C6)알킬, (C1-C6)알콕시, (C2-C6)알케닐, (C2-C6)알키닐, (C3-C8)사이클로알킬 (여기서 아릴, 헤트아릴 또는 헤테로사이클릴은 각 경우 할로겐, 시아노, 니트로, 하이드록시, 아미노, 카복시, 카바모일, 아미노설포닐, (C1-C6)알킬, (C3-C6)사이클로알킬, (C1-C6)알콕시, (C1-C6)할로알킬, (C1-C6)할로알콕시, (C1-C6)알킬티오, (C1-C6)알킬설피닐, (C1-C6)알킬설포닐, (C1-C6)알킬설프이미노, (C1-C6)알킬설프이미노-(C1-C6)알킬, (C1-C6)알킬설프이미노-(C2-C6)알킬카보닐, (C1-C6)알킬설폭스이미노, (C1-C6)알킬설폭스이미노-(C1-C6)알킬, (C1-C6)알킬설폭스이미노-(C2-C6)알킬카보닐, (C1-C6)알콕시카보닐, (C1-C6)알킬카보닐, (C3-C6)트리알킬실릴 또는 벤질로 구성된 그룹 중에서 선택된 동일하거나 상이한 치환체에 의해 임의로 일- 또는 다치환될 수 있음), 또는R1은 각각 할로겐, 시아노, 니트로, 하이드록시, 아미노, 카복시, 카바모일, (C1-C6)-알킬, (C3-C8)-사이클로알킬, (C1-C6)-알콕시, (C1-C6)-할로알킬, (C1-C6)-할로알콕시, (C1-C6)-알킬티오, (C1-C6)-알킬설피닐, (C1-C6)-알킬설포닐, (C1-C6)-알킬설프이미노, (C1-C6)-알킬설프이미노-(C1-C6)-알킬, (C1-C6)-알킬설프이미노-(C2-C6)-알킬카보닐, (C1-C6)-알킬설폭스이미노, (C1-C6)-알킬설폭스이미노-(C1-C6)-알킬, (C1-C6)-알킬설폭스이미노-(C2-C6)-알킬카보닐, (C1-C6)-알콕시카보닐, (C1-C6)-알킬카보닐, (C3-C6)-트리알킬실릴, (=O) (헤테로사이클릴의 경우에만) 및 (=O)2 (헤테로사이클릴의 경우에만)로 구성된 그룹 중에서 선택된 동일하거나 상이한 치환체에 의해 임의로 일- 또는 다치환된 아릴, 헤트아릴 또는 헤테로사이클릴을 나타내고,R2는 동일하거나 상이한 치환체에 의해 임의로 일- 또는 다치환된 포화, 헤테로사이클릭, 부분 포화 헤테로사이클릭 또는 헤테로방향족 환을 나타내고, 여기서 적어도 하나의 탄소 원자는 헤테로원자에 의해 대체되고, 각 경우 임의로 적어도 하나의 카보닐 그룹이 존재할 수 있고/있거나, 가능한 치환체들은 각 경우 다음과 같고: 수소, 시아노, 카복실, 할로겐, 니트로, 아세틸, 하이드록시, 아미노, SCN, 트리-(C1-C6)알킬실릴, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)하이드록시알킬, 하이드록시카보닐-(C1-C6)-알콕시, (C1-C6)알콕시카보닐-(C1-C6)알킬, (C1-C6)알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐, (C2-C6)시아노알키닐, (C3-C6)사이클로알킬, (C3-C6)사이클로알킬-(C3-C6)사이클로알킬, (C1-C4)알킬-(C3-C6)사이클로알킬 (C1-C6)알콕시, (C1-C6)할로알콕시, (C1-C6)시아노알콕시, (C1-C6)알콕시카보닐-(C1-C6)알콕시, (C1-C6)알콕시-(C1-C6)알콕시, (C1-C6)알콕시이미노, -N=C(H)-O(C1-C6)알킬, -C(H)=N-O(C1-C6)알킬, (C1-C6)할로알킬-(C1-C6)알콕시이미노, (C1-C6)알킬티오, (C1-C6)할로알킬티오, (C1-C6)알콕시-(C1-C6)알킬티오, (C1-C6)알킬티오-(C1-C6)알킬, (C1-C6)알킬설피닐, (C1-C6)할로알킬설피닐, (C1-C6)알콕시-(C1-C6)알킬설피닐, (C1-C6)알킬설피닐-(C1-C6)알킬, (C1-C6)알킬설포닐, (C1-C6)할로알킬설포닐, (C1-C6)알콕시-(C1-C6)알킬설포닐, (C1-C6)알킬설포닐-(C1-C6)알킬, (C1-C6)알킬설포닐옥시, (C1-C6)알킬카보닐, (C1-C6)할로알킬카보닐, (C1-C6)알킬카보닐옥시, (C1-C6)알콕시카보닐, (C1-C6)할로알콕시카보닐, 아미노카보닐, (C1-C6)알킬아미노카보닐, 디-(C1-C6)알킬아미노카보닐, (C2-C6)알케닐아미노카보닐, 디-(C2-C6)-알케닐아미노카보닐, (C3-C8)사이클로알킬아미노카보닐, (C1-C6)알킬설포닐아미노, (C1-C6)알킬아미노, 디-(C1-C6)알킬아미노, 아미노설포닐, (C1-C6)알킬아미노설포닐, 디-(C1-C6)알킬아미노설포닐, (C1-C6)알킬설폭스이미노, 아미노티오카보닐, (C1-C6)알킬아미노티오카보닐, 디-(C1-C6)알킬아미노티오카보닐, (C3-C8)사이클로알킬아미노, (C1-C6)알킬카보닐아미노, R2는 또한 -C(=O)-R8 (G1), -C(=S)-R8 (G2), -C(=O)-NR11R12(G3), -C(=S)-NR11R12 (G4), -S(O)m-R13 (G5), -S=O(=NH)-R13 (G6), -S=O(=N-CN)-R13 (G7), -S(=N-CN)-R13 (G8), -S(O)2-NR11R12 (G9), -NR11R12 (G10), -NR11-NR11R12 (G11), -NR11-C(=O)-R8 (G12), -NR11-C(=S)-R8 (G13), -NR11-S(O)2-R13 (G14), -N(R11)-O-R13 (G15), -N=S(=O)p-R14R15 (G16), -O-R13 (G17), -CR11=N-OR13 (G18) 또는 -CR11=CR8R12G(19)로부터 선택된 그룹을 나타내고, 여기서 R2가 G5, G6, G7, G8, G9를 나타내면, n은 2를 나타내고,R3은 수소,시아노, 할로겐, 니트로, 아세틸, 하이드록시, 아미노, SCN, 트리(C1-C6)알킬실릴, (C3-C8)사이클로알킬, (C3-C8)사이클로알킬-(C3-C8)사이클로알킬, (C1-C6)알킬-(C3-C8)사이클로알킬, 할로(C3-C8)사이클로알킬, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)하이드록시알킬, 하이드록시카보닐-(C1-C6)-알콕시, (C1-C6)알콕시카보닐-(C1-C6)알킬, (C1-C6)알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐, (C2-C6)시아노알키닐, (C1-C6)알콕시, (C1-C6)할로알콕시, (C1-C6)시아노알콕시, (C1-C6)알콕시카보닐-(C1-C6)알콕시, (C1-C6)알콕시-(C1-C6)알콕시, (C1-C6)알킬하이드록시이미노, (C1-C6)알콕시이미노, (C1-C6)알킬-(C1-C6)알콕시이미노, (C1-C6)할로알킬-(C1-C6)알콕시이미노, (C1-C6)알킬티오, (C1-C6)할로알킬티오, (C1-C6)알콕시-(C1-C6)알킬티오, (C1-C6)알킬티오-(C1-C6)알킬, (C1-C6)알킬설피닐, (C1-C6)할로알킬설피닐, (C1-C6)알콕시-(C1-C6)알킬설피닐, (C1-C6)알킬설피닐-(C1-C6)알킬, (C1-C6)알킬설포닐, (C1-C6)할로알킬설포닐, (C1-C6)알콕시-(C1-C6)알킬설포닐, (C1-C6)알킬설포닐-(C1-C6)알킬, (C1-C6)알킬설포닐옥시, (C1-C6)알킬카보닐, (C1-C6)알킬티오카보닐, (C1-C6)할로알킬카보닐, (C1-C6)알킬카보닐옥시, (C1-C6)알콕시카보닐, (C1-C6)할로알콕시카보닐, 아미노카보닐, (C1-C6)알킬아미노카보닐, (C1-C6)알킬아미노티오카보닐, 디-(C1-C6)알킬아미노카보닐, 디-(C1-C6)알킬아미노티오카보닐, (C2-C6)알케닐아미노카보닐, 디-(C2-C6)-알케닐아미노카보닐, (C3-C8)사이클로알킬아미노카보닐, (C1-C6)알킬설포닐아미노, (C1-C6)알킬아미노, 디-(C1-C6)알킬아미노, 아미노설포닐, (C1-C6)알킬아미노설포닐, 디-(C1-C6)알킬아미노설포닐, (C1-C6)알킬설폭스이미노, 아미노티오카보닐, (C1-C6)알킬아미노티오카보닐, 디-(C1-C6)알킬아미노티오카보닐, (C3-C8...