Phenylthio acetic acid derivatives, process and intermediate products for their production and agents containing themPhenylthio acetic acid derivatives of formula (I) in which the components and index have the following meanings: R is hydrogen and alkyl; R is cyano, nitro, trifluoro methyl, halogen, alkyl and alkoxy; m is 0, 1 or 2, in which the radicals R may be different if m is 2; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, halogen alkyl, alkoxy, halogen alkoxy, alkylthio, alkylamino or dialkylamino; R is hydrogen, cyano, nitro, hydroxy, amino, halogen, possibly substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, possibly substituted cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino, N-hetaryl-N-alkylamino; R is hydrogen, possibly substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkyl carbonyl, alkenyl carbonyl, alkinyl carbonyl or alkyl sulphonyl, possibly substituted aryl, aryl carbonyl, aryl sulphonyl, hetaryl, hetaryl carbonyl or hetaryl sulphonyl. The invention also concern their salts, the process and intermediate products for their production and their use.Phenylacetic acid derivatives and the salt thereof represented of formula i wherein substituting group and symbol definition are as follows:r 1be hydrogen or c 1-c 4-alkyl; r 2be cyano group, nitro, trifluoromethyl, halogen, c 1-c 4-alkyl or c 1-c 4-alkoxyl group; m is 0,1 or 2, if m is 2, and r 2can be different groups; r 3be hydrogen, cyano group, nitro, hydroxyl, amino, halogen, c 1-c 4-alkyl, c 1-c 4-haloalkyl, c 1-c 4-alkoxyl group, c 1-c 4-halogen for alkoxyl group, c 1-c 4-alkylthio, c 1-c 4-alkylamino or two- c 1-c 4-alkylamino; r 4be hydrogen, cyano group, nitro, hydroxyl, amino, halogen, c 1-c 6-alkyl, c 1-c 6-alkoxyl group, c 1-c 6-alkylthio, c 1-c 6-alkane ammonia base, two-c 1-c 6-alkylamino, c 2-c 6-alkenyl, c 2-c 6-alkenyloxy, c 2-c 6-alkenyl thio, c 2-c 6-chain enamino, n-c 2-c 6-alkenyl-n-c 1-c 6-alkyl ammonia base, c 2-c 6-alkynyl group, c 2-c 6-chain oxy-acetylene, c 2-c 6-sulfur-based chain acetylene, c 2-c 6-alkyne amino, n-c 2-c 6-alkyne base-n-c 1-c 6-alkylamino, the hydrocarbyl portion in these groups can by halo partially or completely or have one to three following groups: cyano group, nitrebase, hydroxyl, sulfydryl, amino, carboxyl, aminocarbonyl, ammonia thiocarbonyl, halogenelement, c 1-c 6-alkyl amino-carbonyl, two-c 1-c 6-alkyl amino carbonyl base, c 1-c 6-alkylamino thiocarbonyl, two-c 1-c 6-thio-alkyl amino-carbonyl, c 1-c 6-alkyl sulphonyl, c 1-c 6alkyl sulphinyl, c 1-c 6-alkoxyl group, c 1-c 6-halogenated alkoxy, c 1-c 6-carbalkoxy, c 1-c 6-alkylthio, c 1-c 6-alkylamino, two-c 1-c 6-alkylamino, c 2-c 6alkenyloxy, c 3-c 6-cycloalkyl, c 3-c 6-cycloalkyloxy, heterocyclic radical, heterocyclic oxy group, aryl, aryloxy, aryl-c 1-c 4-alkoxyl group, arylthio, aryl-c 1-c 4-alkylthio, heteroaryl, heteroaryloxy, heteroaryl-c 1-c 4-alkoxyl group, heteroarylthio, heteroaryl-c 1-c 4-alkylthio, these cyclic group cyclic groups part can and/or have one to three following groups by halo partially or completely again: cyano group, nitro, hydroxyl, sulfydryl, amino, carboxyl, aminocarbonyl, ammonia thiocarbonyl, c 1-c 6alkyl, c 1-c 6-haloalkyl, c 1-c 6-alkyl sulphonyl, c 1-c 6-alkyl sulphinyl, c 3-c 6-cycloalkyl, c 1-c 6-alkoxyl group, c 1-c 6-halogenated alkoxy, c 1-c 6-carbalkoxy, c 1-c 6-alkylthio, c 1-c 6-alkylamino, two-c 1-c 6-alkylamino, c 1-c 6-alkyl amino-carbonyl, two-c 1-c 6-alkyl amino-carbonyl, c 1-c 6-alkylamino thiocarbonyl, two-c 1-c 6-thio-alkyl amino-carbonyl, c 2-c 6-alkenyl, c 2-c 6-alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy, heteroarylthio, and c (=nor 6)-an-r 7c 3-c 6-cycloalkyl, c 3-c 6-cycloalkyloxy, c 3-c 6-cycloalkylthio, c 3-c 6-naphthene amino, n-c 3-c 6-cycloalkyl-n-c 1-c 6-alkylamino, c 3-c 6-cycloalkenyl group, c 3-c 6-cyclenes oxygen base, c 3-c 6-cyclenes sulfenyl, c 3-c 6-cyclenes amino, n-c 3-c 6-cycloalkenyl group-n-c 1-c 6-alkylamino, heterocyclic radical, heterocyclic oxy group, heterocycle sulfenyl, heterocyclic amino group, n-heterocyclic radical-n-c 1-c 6-alkylamino, aryl, aryloxy, arylthio, virtue is amino, n-aryl-n-c 1-c 6-alkylamino, heteroaryl, heteroaryloxy, heteroarylthio, assorted virtue is amino, n-heteroaryl-n-c 1- c 6-alkylamino, cyclic group can or have by halo partially or completely three following groups: cyano group, nitro, hydroxyl, sulfydryl, amino, carboxyl,aminocarbonyl, ammonia thiocarbonyl, halogen, c 1-c 6-alkyl, c 1-c 6-haloalkyl, c 1-c 6-alkyl sulphonyl, c 1-c 6-alkyl asia alkylsulfonyl, c 3-c 6-cycloalkyl, c 1-c 6-alkoxyl group, c 1- c 6-halogenated alkoxy, c 1-c 6-carbalkoxy, c 1-c 6-alkane sulphur base, c 1-c 6-alkylamino, two-c 1-c 6-alkylamino, c 1-c 6-alkyl amino-carbonyl, two-c 1-c 6-alkyl amino-carbonyl, c 1-c 6-alkylamino thiocarbonyl, two-c 1-c 6-alkylamino sulfo- carbonyl, c 2-c 6-alkenyl, c 2-c 6-alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, heteroaryl and heteroaryloxy; r 5be hydrogen, c 1-c 10-alkyl, c 3-c 6-cycloalkyl, c 2-c 10-alkene base, c 2-c 10-alkynyl group, c 1-c 10-alkyl carbonyl, c 2-c 10-alkene carbonyl, c 3-c 10-alkyne carbonyl or c 1-c 10-alkyl sulphur acyl group, these groups can by halo partially or completely or have one to three followinggroup: cyano group, nitro, hydroxyl, sulfydryl, amino, carboxyl, aminocarbonyl,amino thiocarbonyl, halogen, c 1-c 6-alkyl, c 1-c 6-halo alkyl, c 1-c 6-alkyl sulphonyl, c 1-c 6-alkyl sulfenyl base, c 1-c 6-alkoxyl group, c 1-c 6-halogenated alkoxy, c 1- c 6-carbalkoxy, c 1-c 6-alkylthio, c 1-c 6-alkylamino, two-c 1-c 6-alkylamino, c 1-c 6-alkyl amino-carbonyl, two- c 1-c 6-alkyl amino-carbonyl, c 1-c 6-alkylamino thiocarbonyl, two-c 1-c 6-thio-alkyl amino-carbonyl, c 2-c 6-alkenyl, c 2-c 6-alkenyloxy, c 3-c 6-cycloalkyl, c 3-c 6-ring alkoxyl group, heterocyclic radical, heterocyclic oxy group, benzyl, benzyloxy, aryl, fragrant oxygenbase, arylthio, heteroaryl, heteroaryloxy and heteroarylthio, these cyclic groupgroup can or have one to three following groups by halo partially or completely again: cyanogenbase, nitro, hydro...
페닐티오 아세트산 유도체, 이의 제조 방법 및 이에 대한 중간체, 및 이들을 함유하는 조성물(Phenylthio Acetic Acid Derivatives, Process and Intermediate Products for Their Production and Agents Containing Them)화학식(Ⅰ)의 페닐아세트산 유도체 및 이의 염, 이의 제조 방법 및 이의 제조용 중간체, 및 이들의 용도에 관한 것이다.상기 식에서, R1은 수소 또는 알킬이고; R2는 시아노, 니트로, 트리플루오로메틸, 할로겐, 알킬 또는 알콕시이고; m은 0, 1또는 2인데, m이 2인 경우 R2 라디칼은 상이할 수 있고; R3은 수소, 시아노, 니트로, 히드록실, 아미노, 할로겐, 알킬, 할로알킬, 알콕시, 할로알콕시, 알킬티오, 알킬아미노 또는 디알킬아미노이고; R4는 수소, 시아노, 니트로, 히드록실, 아미노, 할로겐, 비치환되거나 치환된 알킬, 알콕시, 알킬티오, 알킬아미노, 디알킬아미노, 알케닐, 알케닐옥시, 알케닐티오, 알케닐아미노, N-알케닐-N-알킬아미노, 시클로알케닐, 시클로알케닐옥시, 시클로알케닐티오, 시클로알케닐아미노, N-시클로알케닐-N-알킬아미노, 헤테로시클릴, 헤테로시클릴옥시, 헤테로시클릴티오, 헤테로시클릴아미노, N-헤테로시크릴-N-알킬아미노, 아릴, 아릴옥시, 아릴티오, 아릴아미노, N-아릴-N-알킬아미노, 헤타릴, 헤타릴옥시, 헤타릴티오, 헤타릴아미노, N-헤타릴-N-알킬아미노이고; R5는 수소, 비치환되거나 치환된 알킬, 시클로알킬, 알케닐, 알키닐, 알킬카르보닐, 알케닐카르보닐, 알키닐카르보닐 또는 알킬술포닐, 비치환되거나 치환된 아릴, 아릴카르보닐, 아릴술포닐, 헤타릴, 헤타릴카르보닐 또는 헤타릴술포닐이다.화학식(Ⅰ)의 페닐아세트산 유도체 및 이의 염. [이미지] 상기 식에서 R1은 수소 또는 C1-C4-알킬이고 ; R2는 시아노, 니트로, 트리플루오로메틸, 할로겐, C1-C2알킬 또는 C1-C4-알콕시이고; m은 0,1 또는 2인데, m이 2인경우 R2 라디칼은 상이할 수 있고; R3은 수소, 시아노, 니트로, 히드록실, 아미노, 할로겐, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시, C1-C4-알킬티오, C1-C4-알킬아미노 또는 디-C1-C4알킬아미노이고; R4는 수소, 시아노, 니트로 이드록실, 아미노, 할로겐, C1-C6-알킬, C1-C6-알콕시, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C6-알킬아미노, C2-C6-알케닐, C2-C 6-알케닐옥시, C2-C6-알케닐티오, C2-C6-알케닐아미노, N-C2-C6-알케닐-N-C1-C6-알킬아미노, C1-C6-알키닐, C2-C6-알키닐옥시, C2-C6-알키닐티오, C2-C6-알키닐아미노, N-C2-C 6-알키닐-N-C1-C6-알키닐아미노 〔이들 기의 탄화수소 라디칼은 부분적으로 또는 완전히 할로겐화될 수 있거나 다음 라디칼, 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, 할로겐, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C1-C6-알킬술포닐, C1-C6-알킬술폭실, C1-C6-알콕시, C1-C6-할록알콕시, C1-C6-알콕시카르보닐, C1-C6알킬티오, C1-C6알킬아미노, 디-C1-C6-알킬아미노, C2-C6-알케닐옥시, C3-C6시클로알킬, C3-C6-시클로알콕시, 헤테로시클릴, 헤테로시클릴옥시, 아릴, 아릴옥시, 아릴-C1-C4-알콕시, 아릴티오, 아릴-C1-C4-알킬티오, 헤타릴, 헤타릴옥시, 헤타릴-C1-C4-알콕시, 헤타릴티오, 헤타릴-C1-C4-알킬티오 중 1개 내지 3개를 포함할 수 있으며, 여기서 상기 시클릭라디칼도 마찬가지로 부분적으로 또는 완전히 할로겐화될 수 있고(있거나) 다음기, 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, C1-C6-알킬, C1-C6-할로알킬, C1-C6-알킬술포닐, C1-C6-알킬술포닐, C3-C6-시클로알킬, C1-C6-알콕시, C1-C6-할로알콕시, C1-C6-알콕시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C 6-알킬아미노, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C2-C6-알케닐, C2-C6-알케닐옥시, 벤질, 벤질옥시, 아릴, 아릴옥시, 아릴티오, 헤타릴, 헤타릴옥시, 헤타릴티오 및 C(=NOR6)-An-R7 중 1개 내지 3개를 포함할 수 있음〕;C3-C6-시클로알킬, C3-C6-시클로알콕시, C3-C6-시클로알킬티오, C3-C6-시클로알킬아미노, N-C3-C6-시클로알킬-N-C1-C6-알킬아미노, C3-C6-시클로알케닐, C3-C6-시클로알케닐옥시, C3-C6-시클로알케닐티오, C3-C6-시클로알케닐아미노, N-C3-C6-시클로알케닐-N-C1-C6-알킬아미노, 헤테로시클릴, 헤테로시클릴옥시, 헤테로시클릴티오, 헤테로시클릴아미노, N-헤테로시클릴-N-C1-C6-알킬아미노〔여기서 시클릭 라디칼은 부분적으로 또는 오나전히 할로겐화될 수 있거나 다음기, 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, 할로겐, C1-C6-알킬, C1-C6-할로알킬, C1-C 6-알킬술포닐, C1-C6-알킬술포닐, C3-C6-시클로알킬, C1-C6-알콕시, C1-C6-할로알콕시, C1-C6-알콕시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C2-C6-알케닐, C2-C6-알케닐옥시, 벤질, 벤질옥시, 아릴, 아릴옥시, 헤타릴 및 헤타릴옥시 중 1개 내지 3개를 포함할 수 있음]이고; R5는 수소, C1-C10-알킬, C3-C6-시클로알킬, C2-C10-알케닐, C2-C10-알키닐, C1-C10-알킬카르보닐, C2-C10-알케닐카르보닐, C3-C10-알키닐카르보닐 또는 C1-C10-알킬술포닐 〔이들 라디칼은 부분적으로 또는 완전히 할로겐화될 수 있거나 다음기, 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, 할로겐, C1-C6-알킬, C1-C6-할로알킬, C1-C6-알킬술포닐, C1-C6-알킬술폭실, C1-C6-알콕시, C1-C6-할로알콕시, C1-C6-알콕시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C 6-알킬아미노, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C2-C6-알케닐, C2-C6-알케닐옥시, C3-C6-시클로알킬, C3-C6-시클로알콕시, 헤테로시클릴, 헤테로시클릴옥시, 벤질, 벤질옥시, 아릴, 아릴옥시, 아릴티오, 헤타릴, 헤타릴옥시 및 헤타릴티오 중 1개 내지 3개를 포함할 수 있으며, 여기서, 시클릴기는 부분적으로 또는 완전히 할로겐화될 수 있거나 다음기, 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, 할로겐, C1-C6-알킬, C1-C6-할로알킬, C1-C 6-알킬술포닐, C1-C6-알킬술폭실, C3-C6-시클로알킬, C1-C6-알콕시, C1-C6-할로알콕시, C1-C6-알콕시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C6-알킬아미노, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C2-C6-알케닐, C2-C6-알케닐옥시, 벤질, 벤질옥시, 아릴, 아릴옥시, 아릴티오, 헤타릴, 헤타릴옥시, 헤타릴티오 또는 C(=NOR6)-An-R7 중 1개 내지 3개를 포함할 수 있음]; 아릴, 아릴카르보닐, 아릴술포닐, 헤타릴, 헤타릴카르보닐 또는 헤타릴술포닐 〔이들 라디칼은 부분적으로 또는 완전히 할로겐화될 수 있거나 다음기, 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, 할로겐, C1-C6-알킬, C1-C6-할로알킬, C1-C6-알킬카르보닐, C1-C6-알킬술포닐, C1-C6-알킬술폭실, C3-C6-시클로알킬, C1-C 6-알콕시, C4-C6-할로알콕시, C1-C6-알콕시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C6-알킬아미노, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C 6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C2-C6-알케닐, C2-C6-알케닐옥시, 벤질, 벤질옥시, 아릴, 아릴옥시, 헤타릴, 헤타릴옥시 또는 C(=NOR6)-An-R7 중 1개 내지 3개를 포함할 수 있음〕이고; 여기서 A는 산소, 황 또는 질소 여기서 질소는 수소 또는 C1-C6-알킬을 포함하며; n은 0또는 1이고; R6은 수소 또는 C1-C 6-알킬이고, R7은 수소 또는 C1-C6-알킬이다.