Condensed bicyclic heterocycle derivatives as pest control agentsThe invention relates to novel compounds of formula (I), wherein Aa, Ab, Ac, Ad, R1, Q and n have the meanings indicated in the description, the use thereof as acaricides and/or insecticides for controlling animal pests, and methods and intermediate products for the production thereof.The compound of formula (i)whereinaaindicate nitrogen or=c (r7)-,abexpression=n- ,-s (o)m-、-o-、-n(r15)-,=c (r2- c)-, (=o)-or-c (r9)(r10)-,acexpression=n- ,-s (o)m,-o- ,=c (r3- c)-, (=o)-or-c (r11)(r12)-,adexpression=n- ,-s (o)m-、-o-、-n(r15)-,=c (r8- c)-, (=o)-or-c (r13)(r14)-,wherein substituent ab、acand adin only one can indicate oxygen ,-s (o)mor-c (=o)-,r1indicate (c1-c6)-alkyl, (c1-c6)-halogenated alkyl, (c1-c6)-cyanoalkyl, (c1-c6)-hydroxy alkyl, (c1- c6)-alkoxy-(c1-c6)-alkyl, (c1-c6)-halogenated alkoxy-(c1-c6)-alkyl, (c2-c6)-alkenyl, (c2-c6)-alkene oxygen base-(c1-c6)-alkyl, (c2-c6)-haloalkenyloxy-(c1-c6)-alkyl, (c2-c6)-halogenated alkenyl, (c2-c6)-cyano alkene base, (c2-c6)-alkynyl, (c2-c6)-alkynyloxy group-(c1-c6)-alkyl, (c2-c6)-halogenated alkynyloxy group-(c1-c6)-alkyl, (c2- c6)-halo alkynyl, (c2-c6)-cyano alkynyl, (c3-c8)-naphthenic base, (c3-c8)-naphthenic base-(c3-c8)-naphthenic base, (c1- c6)-alkyl-(c3-c8)-naphthenic base, halogenated-(c3-c8)-naphthenic base, amino, (c1-c6)-alkyl amino, two-(c1-c6)-alkane base-amino, (c3-c8)-cycloalkyl amino, (c1-c6)-alkyl-carbonyl-amino, (c1-c6)-alkylthio group-(c1-c6)-alkyl, (c1- c6)-halogenated alkylthio-(c1-c6)-alkyl, (c1-c6)-alkyl sulphinyl-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl is sub- sulfonyl-(c1-c6)-alkyl, (c1-c6)-alkyl sulphonyl-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl sulfonyl-(c1- c6)-alkyl, (c1-c6)-alkoxy-(c1-c6)-alkylthio group-(c1-c6)-alkyl, (c1-c6)-alkoxy-(c1-c6)-alkyl is sub- sulfonyl-(c1-c6)-alkyl, (c1-c6)-alkoxy-(c1-c6)-alkyl sulphonyl-(c1-c6)-alkyl, (c1-c6)-alkyl carbonyl-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl carbonyl-(c1-c6)-alkyl, (c1-c6)-alkoxy carbonyl-(c1-c6)- alkyl, (c1-c6)-halo alkoxy carbonyl-(c1-c6)-alkyl, (c1-c6)-alkyl sulfonyl-amino, amino-sulfonyl-(c1- c6)-alkyl, (c1-c6)-alkyl amino sulfonyl-(c1-c6)-alkyl, two-(c1-c6)-alkyl amino sulfonyl-(c1-c6)- alkyl,or indicate (c1-c6)-alkyl, (c1-c6)-alkoxy, (c2-c6)-alkenyl, (c2-c6)-alkynyl, (c3-c8)-naphthenic base, it is respectively optionally monosubstituted or polysubstituted by identical or different aryl, heteroaryl or heterocyclyl substituent, wherein aryl, heteroaryl base or heterocycle can be respectively optionally monosubstituted or polysubstituted by identical or different following substituent group: halogen, cyano, nitro, hydroxyl, amino, carboxyl, carbamoyl, amino-sulfonyl, (c1-c6)-alkyl, (c3-c6)-naphthenic base, (c1-c6)-alcoxyl base, (c1-c6)-halogenated alkyl, (c1-c6)-halogenated alkoxy, (c1-c6)-alkylthio group, (c1-c6)-alkyl sulphinyl, (c1- c6)-alkyl sulphonyl, (c1-c6)-alkyl sulfonyl imino group, (c1-c6)-alkyl sulfonyl imino group-(c1-c6)-alkyl, (c1- c6)-alkyl sulfonyl imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkyl sulfenyl imino group, (c1-c6)-alkyl sulfenyl imino group-(c1-c6)-alkyl, (c1-c6)-alkyl sulfenyl imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkoxy carbonyl base, (c1-c6)-alkyl-carbonyl, (c3-c6)-trialkylsilkl or benzyl, orr1indicate aryl, heteroaryl or heterocycle, it is respectively optionally monosubstituted by identical or different following substituent group or take more generation: halogen, cyano, nitro, hydroxyl, amino, carboxyl, carbamoyl, (c1-c6)-alkyl, (c3-c8)-naphthenic base, (c1- c6)-alkoxy, (c1-c6)-halogenated alkyl, (c1-c6)-halogenated alkoxy, (c1-c6)-alkylthio group, (c1-c6)-alkyl sulfenyl base, (c1-c6)-alkyl sulphonyl, (c1-c6)-alkyl sulfonyl imino group, (c1-c6)-alkyl sulfonyl imino group-(c1-c6)-alkane base, (c1-c6)-alkyl sulfonyl imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkyl sulfenyl imino group, (c1-c6)-alkyl sulfenyl imino group-(c1-c6)-alkyl, (c1-c6)-alkyl sulfenyl imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alcoxyl base carbonyl, (c1-c6)-alkyl-carbonyl, (c3-c6)-trialkylsilkl, (=o) (only in the case where heterocycle) or (= o)2(only in the case where heterocycle),r2、r3、r8hydrogen, cyano, halogen, nitro, acetyl group, hydroxyl, amino, scn, three-(c are indicated independently of one another1-c6)-alkane base silicyl, (c3-c8)-naphthenic base, (c3-c8)-naphthenic base-(c3-c8)-naphthenic base, (c1-c6)-alkyl-(c3-c8)-ring alkyl, halogenated-(c3-c8)-naphthenic base, (c1-c6)-alkyl, (c1-c6)-halogenated alkyl, (c1-c6)-cyanoalkyl, (c1-c6)- hydroxy alkyl, hydroxycarbonyl group-(c1-c6)-alkoxy, (c1-c6)-alkoxy carbonyl-(c1-c6)-alkyl, (c1-c6)-alkoxy- (c1-c6)-alkyl, (c2-c6)-alkenyl, (c2-c6)-halogenated alkenyl, (c2-c6)-cyano alkenyl, (c2-c6)-alkynyl, (c2-c6)- halo alkynyl, (c2-c6)-cyano alkynyl, (c1-c6)-alkoxy, (c1-c6)-halogenated alkoxy, (c1-c6)-cyano alkoxy, (c1-c6)-alkoxy carbonyl-(c1-c6)-alkoxy, (c1-c6)-alkoxy-(c1-c6)-alkoxy, (c1-c6)-alkyl hydroxy imino group, (c1-c6)-alkoximino, (c1-c6)-alkyl-(c1-c6)-alkoximino, (c1-c6)-halogenated alkyl- (c1-c6)-alkoximino, (c1-c6)-alkylthio group, (c1-c6)-halogenated alkylthio, (c1-c6)-alkoxy-(c1-c6)-alkane sulfenyl, (c1-c6)-alkylthio group-(c1-c6)-alkyl, (c1-c6)-alkyl sulphinyl, (c1-c6)-alkylsulfinyl, (c1-c6)-alkoxy-(c1-c6)-alkyl sulphinyl, (c1-c6)-alkyl sulphinyl-(c1-c6)-alkyl, (c1-c6)-alkane base sulfonyl, ...
해충 방제제로서의 축합 바이시클릭 헤테로사이클 유도체본 발명은 신규한 하기 화학식 (I) 의 화합물:[이미지] [식 중, Aa, Ab, Ac, Ad, R1, Q 및 n 은 상기 주어진 의미를 가짐], 동물 해충을 방제하기 위한 살비제 및/또는 살곤충제로서의 이의 용도, 및 이의 제조를 위한 방법 및 중간 생성물에 관한 것이다.하기 화학식 (I) 의 화합물:[이미지][식 중:Aa 는 질소 또는 =C(R7)- 를 나타내고,Ab 는 =N-, -S(O)m-, -O-, -N(R15)-, =C(R2)-, -C(=O)- 또는 -C(R9)(R10)- 를 나타내고,Ac 는 =N-, -S(O)m-, -O-, =C(R3)-, -C(=O)- 또는 -C(R11)(R12)- 를 나타내고,Ad 는 =N-, -S(O)m-, -O-, -N(R15)-, =C(R8)-, -C(=O)- 또는 -C(R13)(R14)- 를 나타내고,여기서, 치환기 Ab, Ac 및 Ad 중 오로지 하나가 산소, -S(O)m- 또는 -C(=O)- 를 나타낼 수 있고,R1 은 (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-히드록시알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C1-C6)-할로알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C3-C8)-시클로알킬, (C3-C8)-시클로알킬-(C3-C8)-시클로알킬, (C1-C6)-알킬-(C3-C8)-시클로알킬, 할로-(C3-C8)-시클로알킬, 아미노, (C1-C6)-알킬아미노, 디-(C1-C6)-알킬-아미노, (C3-C8)-시클로알킬아미노, (C1-C6)-알킬카르보닐아미노, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-할로알킬티오-(C1-C6)-알킬, (C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-할로알킬술피닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-할로알킬술포닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-알킬카르보닐-(C1-C6)-알킬, (C1-C6)-할로알킬카르보닐-(C1-C6)-알킬, (C1-C6)-알콕시카르보닐-(C1-C6)-알킬, (C1-C6)-할로알콕시카르보닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐아미노, 아미노술포닐-(C1-C6)-알킬, (C1-C6)-알킬아미노술포닐-(C1-C6)-알킬, 디-(C1-C6)-알킬-아미노술포닐-(C1-C6)-알킬을 나타내거나, (C1-C6)-알킬, (C1-C6)-알콕시, (C2-C6)-알케닐, (C2-C6)-알키닐, (C3-C8)-시클로알킬 (이들 각각은 임의로는 동일 또는 상이한 아릴, 헤타릴 또는 헤테로시클릴 치환기에 의해 1치환 또는 다치환되고, 여기서 아릴, 헤타릴 또는 헤테로시클릴은 각각 임의로는 동일 또는 상이한 할로겐, 시아노, 니트로, 히드록시, 아미노, 카르복시, 카르바모일, 아미노술포닐, (C1-C6)-알킬, (C3-C6)-시클로알킬, (C1-C6)-알콕시, (C1-C6)-할로알킬, (C1-C6)-할로알콕시, (C1-C6)-알킬티오, (C1-C6)-알킬술피닐, (C1-C6)-알킬술포닐, (C1-C6)-알킬술피미노, (C1-C6)-알킬술피미노-(C1-C6)-알킬, (C1-C6)-알킬술피미노-(C2-C6)-알킬카르보닐, (C1-C6)-알킬술폭시미노, (C1-C6)-알킬술폭시미노-(C1-C6)-알킬, (C1-C6)-알킬술폭시미노-(C2-C6)-알킬카르보닐, (C1-C6)-알콕시카르보닐, (C1-C6)-알킬카르보닐, (C3-C6)-트리알킬실릴 또는 벤질 치환기에 의해 1치환 또는 다치환될 수 있음) 을 나타내고, 또는R1 은 아릴, 헤타릴 또는 헤테로시클릴 (이들 각각은 임의로는 동일 또는 상이한 할로겐, 시아노, 니트로, 히드록시, 아미노, 카르복시, 카르바모일, (C1-C6)-알킬, (C3-C8)-시클로알킬, (C1-C6)-알콕시, (C1-C6)-할로알킬, (C1-C6)-할로알콕시, (C1-C6)-알킬티오, (C1-C6)-알킬술피닐, (C1-C6)-알킬술포닐, (C1-C6)-알킬술피미노, (C1-C6)-알킬술피미노-(C1-C6)-알킬, (C1-C6)-알킬술피미노-(C2-C6)-알킬카르보닐, (C1-C6)-알킬술폭시미노, (C1-C6)-알킬술폭시미노-(C1-C6)-알킬, (C1-C6)-알킬술폭시미노-(C2-C6)-알킬카르보닐, (C1-C6)-알콕시카르보닐, (C1-C6)-알킬카르보닐, (C3-C6)-트리알킬실릴, (=O) (오로지 헤테로시클릴의 경우) 또는 (=O)2 (오로지 헤테로시클릴의 경우) 치환기에 의해 1치환 또는 다치환됨) 을 나타내고,R2, R3, R8 은 서로 독립적으로 수소, 시아노, 할로겐, 니트로, 아세틸, 히드록시, 아미노, SCN, 트리-(C1-C6)-알킬실릴, (C3-C8)-시클로알킬, (C3-C8)-시클로알킬-(C3-C8)-시클로알킬, (C1-C6)-알킬-(C3-C8)-시클로알킬, 할로-(C3-C8)-시클로알킬, (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-히드록시알킬, 히드록시카르보닐-(C1-C6)-알콕시, (C1-C6)-알콕시카르보닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C1-C6)-알콕시, (C1-C6)-할로알콕시, (C1-C6)-시아노알콕시, (C1-C6)-알콕시카르보닐-(C1-C6)-알콕시, (C1-C6)-알콕시-(C1-C6)-알콕시, (C1-C6)-알킬히드록시이미노, (C1-C6)-알콕시이미노, (C1-C6)-알킬-(C1-C6)-알콕시이미노, (C1-C6)-할로알킬-(C1-C6)-알콕시이미노, (C1-C6)-알킬티오, (C1-C6)-할로알킬티오, (C1-C6)-알콕시-(C1-C6)-알킬티오, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알킬술피닐, (C1-C6)-할로알킬술피닐, (C1-C6)-알콕시-(C1-C6)-알킬술피닐, (C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐, (C1-C6)-할로알킬술포닐, (C1-C6)-알콕시-(C1-C6)-알킬술포닐, (C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐옥시, (C1-C6)-알킬카르보닐, (C1-C6)-알킬티오카르보닐, (C1-C6)-할로알킬카르보닐, (C1-C6)-알킬카르보닐옥시, (C1-C6)-알콕시카르보닐, (C1-C6)-할로알콕시카르보닐, 아미노카르보닐, (C1-C6)-알킬아미노카르보닐, (C1-C6)-알킬아미노티오카르보닐, 디-(C1-C6)-알킬아미노카르보닐, 디-(C1-C6)-알킬아미노티오카르보닐, (C2-C6)-알케닐아미노카르보닐, 디-(C2-C6)-알케닐아미노카르보닐, (C3-C8)-시클로알킬아미노카르보닐, (C1-C6)-알킬술포닐아미노, (C1-C6)-알킬아미노, 디-(C1-C6)-알킬아미노, 아미노술포닐, (C1-C6)-알킬아미노술포닐, 디-(C1-C6)-알킬아미노술포닐, (C1-C6)-알킬술폭시미노, 아미노티오카르보닐, (C1-C6)-알킬아미노티오카르보닐, 디-(C1-C6)-알킬아미노티오카르보닐, (C3-C8)-시클로알킬아미노 또는 NHCO-(C1-C6)-알킬 ((C1-C6)-알킬카르보닐아미노) 를 나타내고,R7 은 수소, 시아노, 할로겐, 아세틸, 히드록시, 아미노, (C3-C8)-시클로알킬, 할로-(C3-C8)-시클로알킬, (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C2-C6)-알케닐, (C2-C6)-할로알케닐, (C2-C6)-알키닐, (C2-C6)-할로알키닐, (C1-C6)-알콕시, (C1-C6)-할로알콕시, (C1-C6)-알킬티오, (C1-C6)-할로알킬티오, (C1-C6)-알킬술피닐, (C1-C6)-할로알킬술피닐, (C1-C6)-알킬술포닐 또는 (C1-C6)-할로알킬술포닐을 나타내고,R9, R10, R11, R12, R13, R14 는 서로 독립적으로 수소, 할로겐, (C1-C6)-알킬 또는 (C1-C6)-할로알킬을 나타내고,R15 는 수소, 아세틸, (C1-C4)-알킬, (C1-C4)-히드록시알킬, (C1-C4)-할로알킬, (C1-C4)-시아노알킬, (C1-C4)-알콕시-(C1-C4)-알킬, (C1-C4)-할로알콕시-(C1-C4)-알킬, (C2-C4)-알케닐, (C2-C4)-알케닐옥시-(C1-C4)-알킬, (C2-C4)-할로알케닐옥시-(C1-C4)-알킬, (C2-C4)-할로알케닐, (C2-C4)-시아노알케닐, (C2-C4)-알키닐, (C2-C4)-알키닐옥시-(C1-C4)-알킬, (C2-C4)-할로알키닐옥시-(C1-C4)-알킬, (C2-C4)-할로알키닐, (C2-C4)-시아노알키닐, (C3-C6)-시클로알킬, (C1-C4)-알킬-(C3-C6)-시클로알킬, 할로-(C3-C6)-시클로알킬, (C1-C4)-알킬티오-(C1-C4)-알킬, (C1-C4)-할로알킬티오-(C1-C4)-알킬, (C1-C4)-알킬술피닐-(C1-C4)-알킬, (C1-C4)-할로알킬술피닐-(C1-C4)-알킬, (C1-C4)-알킬술포닐-(C1-C4)-알킬, (C1-C4)-알킬카르보닐-(C1-C4)-알킬, (C1-C4)-할로알킬카르보닐-(C1-C4)-알킬을 나타내거나, (C1-C4)-알킬, (C2-C4)-알케닐, (C2-C4)-알키닐 (이들 각각은 임의로는 동일 또는 상이한 아릴 또는 헤테로시클릴 치환기에 의해 1치환 또는 2치환되고, 여기서 아릴 또는 헤테로시클릴은 각각의 경우에 임의로는 동일 또는 상이한 할로겐, 시아노, (C1-C4)-알킬, (C3-C4)-시클로알킬, (C1-C4)-알콕시, (C1-C4)-할로알킬, (C1-C4)-할로알콕시, (C1-C4)-알킬티오, (C1-C4)-알킬술피닐 또는 (C1-C4)-알킬술포닐 치환기에 의해 1치환 또는 2치환될 수 있음) 을 나타내고, 또는R15 는 아릴 또는 헤테로시클릴 (이들 각각은 임의로는 동일 또는 상이한 할로겐, 시아노, (C1-C4)-알킬, (C3-C6)-시클로알킬, (C...