Pesticidal compositions and processes related theretoThis document discloses molecules having the following formula (I) and processes associated therewith.Composition, the molecule of its contained i:wherein:a () r1 is selected from(1) h, f, cl, br, i, cn, no 2, (c 1-c 8) alkyl, halo (c 1-c 8) alkyl, (c 1-c 8) alkoxyl, halo (c 1-c 8) alkoxyl, s (c 1-c 8) alkyl, s (halo (c 1-c 8) alkyl), s (o) (c 1-c 8) alkyl, s (o) (halo (c 1-c 8) alkyl), s (o) 2(c 1-c 8) alkyl, s (o) 2(halo (c 1-c 8) alkyl), n (r14) (r15), (2) (the c replaced 1-c 8) alkyl, (the c of wherein said replacement 1-c 8) alkyl has and be one or morely selected from following substituting group: cn and no 2, (3) halo (c replaced 1-c 8) alkyl, the halo (c of wherein said replacement 1-c 8) alkyl has and be one or morely selected from following substituting group: cn and no 2, (4) (the c replaced 1-c 8) alkoxyl, (the c of wherein said replacement 1-c 8) alkoxyl has and be one or morely selected from following substituting group: cn and no 2, and (5) halo (c replaced 1-c 8) alkoxyl, the halo (c of wherein said replacement 1-c 8) alkoxyl has and be one or morely selected from following substituting group: cn and no 2; b () r2 is selected from(1) h, f, cl, br, i, cn, no 2, (c 1-c 8) alkyl, halo (c 1-c 8) alkyl, (c 1-c 8) alkoxyl, halo (c 1-c 8) alkoxyl, s (c 1-c 8) alkyl, s (halo (c 1-c 8) alkyl), s (o) (c 1-c 8) alkyl, s (o) (halo (c 1-c 8) alkyl), s (o) 2(c 1-c 8) alkyl, s (o) 2(halo (c 1-c 8) alkyl), n (r14) (r15), (2) (the c replaced 1-c 8) alkyl, (the c of wherein said replacement 1-c 8) alkyl has and be one or morely selected from following substituting group: cn and no 2, (3) halo (c replaced 1-c 8) alkyl, the halo (c of wherein said replacement 1-c 8) alkyl has and be one or morely selected from following substituting group: cn and no 2, (4) (the c replaced 1-c 8) alkoxyl, (the c of wherein said replacement 1-c 8) alkoxyl has and be one or morely selected from following substituting group: cn and no 2, and (5) halo (c replaced 1-c 8) alkoxyl, the halo (c of wherein said replacement 1-c 8) alkoxyl has and be one or morely selected from following substituting group: cn and no 2; c () r3 is selected from(1) h, f, cl, br, i, cn, no 2, (c 1-c 8) alkyl, halo (c 1-c 8) alkyl, (c 1-c 8) alkoxyl, halo (c 1-c 8) alkoxyl, s (c 1-c 8) alkyl, s (halo (c 1-c 8) alkyl), s (o) (c 1-c 8) alkyl, s (o) (halo (c 1-c 8) alkyl), s (o) 2(c 1-c 8) alkyl, s (o) 2(halo (c 1-c 8) alkyl), n (r14) (r15), (2) (the c replaced 1-c 8) alkyl, (the c of wherein said replacement 1-c 8) alkyl has and be one or morely selected from following substituting group: cn and no 2, (3) halo (c replaced 1-c 8) alkyl, the halo (c of wherein said replacement 1-c 8) alkyl has and be one or morely selected from following substituting group: cn and no 2, (4) (the c replaced 1-c 8) alkoxyl, (the c of wherein said replacement 1-c 8) alkoxyl has and be one or morely selected from following substituting group: cn and no 2, and (5) halo (c replaced 1-c 8) alkoxyl, the halo (c of wherein said replacement 1-c 8) alkoxyl has and be one or morely selected from following substituting group: cn and no 2; d () r4 is selected from(1) h, f, cl, br, i, cn, no 2, (c 1-c 8) alkyl, halo (c 1-c 8) alkyl, (c 1-c 8) alkoxyl, halo (c 1-c 8) alkoxyl, s (c 1-c 8) alkyl, s (halo (c 1-c 8) alkyl), s (o) (c 1-c 8) alkyl, s (o) (halo (c 1-c 8) alkyl), s (o) 2(c 1-c 8) alkyl, s (o) 2(halo (c 1-c 8) alkyl), n (r14) (r15), (2) (the c replaced 1-c 8) alkyl, (the c of wherein said replacement 1-c 8) alkyl has and be one or morely selected from following substituting group: cn and no 2, (3) halo (c replaced 1-c 8) alkyl, the halo (c of wherein said replacement 1-c 8) alkyl has and be one or morely selected from following substituting group: cn and no 2, (4) (the c replaced 1-c 8) alkoxyl, (the c of wherein said replacement 1-c 8) alkoxyl has and be one or morely selected from following substituting group: cn and no 2, and (5) halo (c replaced 1-c 8) alkoxyl, the halo (c of wherein said replacement 1-c 8) alkoxyl has and be one or morely selected from following substituting group: cn and no 2; e () r5 is selected from(1) h, f, cl, br, i, cn, no 2, (c 1-c 8) alkyl, halo (c 1-c 8) alkyl, (c 1-c 8) alkoxyl, halo (c 1-c 8) alkoxyl, s (c 1-c 8) alkyl, s (halo (c 1-c 8) alkyl), s (o) (c 1-c 8) alkyl, s (o) (halo (c 1-c 8) alkyl), s (o) 2(c 1-c 8) alkyl, s (o) 2(halo (c 1-c 8) alkyl), n (r14) (r15), (2) (the c replaced 1-c 8) alkyl, (the c of wherein said replacement 1-c 8) alkyl has and be one or morely selected from following substituting group: cn and no 2, (3) halo (c replaced 1-c 8) alkyl, the halo (c of wherein said replacement 1-c 8) alkyl has and be one or morely selected from following substituting group: cn and no 2, (4) (the c replaced 1-c 8) alkoxyl, (the c of wherein said replacement 1-c 8) alkoxyl has and be one or morely selected from following substituting group: cn and no 2, and (5) halo (c replaced 1-c 8) alkoxyl, the halo (c of wherein said replacement 1-c 8) alkoxyl has and be one or morely selected from following substituting group: cn and no 2; f () r6 is (c 1-c 8...
살충 조성물 및 그와 관련된 방법본원은 하기 화학식 1을 갖는 분자 및 그와 관련된 방법을 개시한다. <화학식 1>하기 화학식 1에 따른 분자를 포함하는 조성물.<화학식 1>[이미지]상기 식에서,(a) R1은(1) H, F, Cl, Br, I, CN, NO2, (C1-C8)알킬, 할로(C1-C8)알킬, (C1-C8)알콕시, 할로(C1-C8)알콕시, S(C1-C8)알킬, S(할로(C1-C8)알킬), S(O)(C1-C8)알킬, S(O)(할로(C1-C8)알킬), S(O)2(C1-C8)알킬, S(O)2(할로(C1-C8)알킬), N(R14)(R15),(2) 치환된 (C1-C8)알킬 (여기서 상기 치환된 (C1-C8)알킬은 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐),(3) 치환된 할로(C1-C8)알킬 (여기서 상기 치환된 할로(C1-C8)알킬은 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐),(4) 치환된 (C1-C8)알콕시 (여기서 상기 치환된 (C1-C8)알콕시는 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐), 및(5)치환된할로(C1-C8)알콕시 (여기서 상기 치환된 할로(C1-C8)알콕시는 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐)로부터 선택되고;(b) R2는(1) H, F, Cl, Br, I, CN, NO2, (C1-C8)알킬, 할로(C1-C8)알킬, (C1-C8)알콕시, 할로(C1-C8)알콕시, S(C1-C8)알킬, S(할로(C1-C8)알킬), S(O)(C1-C8)알킬, S(O)(할로(C1-C8)알킬), S(O)2(C1-C8)알킬, S(O)2(할로(C1-C8)알킬), N(R14)(R15),(2) 치환된 (C1-C8)알킬 (여기서 상기 치환된 (C1-C8)알킬은 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐),(3) 치환된 할로(C1-C8)알킬 (여기서 상기 치환된 할로(C1-C8)알킬은 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐),(4) 치환된 (C1-C8)알콕시 (여기서 상기 치환된 (C1-C8)알콕시는 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐), 및(5) 치환된 할로(C1-C8)알콕시 (여기서 상기 치환된 할로(C1-C8)알콕시는 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐)로부터 선택되고;(c) R3은(1) H, F, Cl, Br, I, CN, NO2, (C1-C8)알킬, 할로(C1-C8)알킬, (C1-C8)알콕시, 할로(C1-C8)알콕시, S(C1-C8)알킬, S(할로(C1-C8)알킬), S(O)(C1-C8)알킬, S(O)(할로(C1-C8)알킬), S(O)2(C1-C8)알킬, S(O)2(할로(C1-C8)알킬), N(R14)(R15),(2)치환된 (C1-C8)알킬 (여기서 상기 치환된 (C1-C8)알킬은 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐),(3) 치환된 할로(C1-C8)알킬 (여기서 상기 치환된 할로(C1-C8)알킬은 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐),(4) 치환된 (C1-C8)알콕시 (여기서 상기 치환된 (C1-C8)알콕시는 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐), 및(5) 치환된 할로(C1-C8)알콕시 (여기서 상기 치환된 할로(C1-C8)알콕시는 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐)로부터 선택되고;(d) R4는(1) H, F, Cl, Br, I, CN, NO2, (C1-C8)알킬, 할로(C1-C8)알킬, (C1-C8)알콕시, 할로(C1-C8)알콕시, S(C1-C8)알킬, S(할로(C1-C8)알킬), S(O)(C1-C8)알킬, S(O)(할로(C1-C8)알킬), S(O)2(C1-C8)알킬, S(O)2(할로(C1-C8)알킬), N(R14)(R15),(2) 치환된 (C1-C8)알킬 (여기서 상기 치환된 (C1-C8)알킬은 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐),(3) 치환된 할로(C1-C8)알킬 (여기서 상기 치환된 할로(C1-C8)알킬은 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐),(4) 치환된 (C1-C8)알콕시 (여기서 상기 치환된 (C1-C8)알콕시는 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐), 및(5) 치환된 할로(C1-C8)알콕시 (여기서 상기 치환된 할로(C1-C8)알콕시는 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐)로부터 선택되고; (e) R5는(1) H, F, Cl, Br, I, CN, NO2, (C1-C8)알킬, 할로(C1-C8)알킬, (C1-C8)알콕시, 할로(C1-C8)알콕시, S(C1-C8)알킬, S(할로(C1-C8)알킬), S(O)(C1-C8)알킬, S(O)(할로(C1-C8)알킬), S(O)2(C1-C8)알킬, S(O)2(할로(C1-C8)알킬), N(R14)(R15),(2) 치환된 (C1-C8)알킬 (여기서 상기 치환된 (C1-C8)알킬은 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐),(3) 치환된 할로(C1-C8)알킬 (여기서 상기 치환된 할로(C1-C8)알킬은 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐),(4) 치환된 (C1-C8)알콕시 (여기서 상기 치환된 (C1-C8)알콕시는 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐), 및(5) 치환된 할로(C1-C8)알콕시 (여기서 상기 치환된 할로(C1-C8)알콕시는 CN 및 NO2로부터 선택된 1개 이상의 치환기를 가짐)로부터 선택되고;(f) R6은 (C1-C8)할로알킬이고;(g) R7은 H, F, Cl, Br, I, OH, (C1-C8)알콕시, 및 할로(C1-C8)알콕시로부터 선택되고;(h) R8은 H, (C1-C8)알킬, 할로(C1-C8)알킬, OR14, 및 N(R14)(R15)로부터 선택되고;(i) R9는 H, F, Cl, Br, I, (C1-C8)알킬, 할로(C1-C8)알킬, (C1-C8)알콕시, 할로(C1-C8)알콕시, OR14, 및 N(R14)(R15)로부터 선택되고;(j) R10은(1) (u), H, F, Cl, Br, I, CN, NO2, (C1-C8)알킬, 할로(C1-C8)알킬, (C1-C8)알콕시, 할로(C1-C8)알콕시, 시클로(C3-C6)알킬, S(C1-C8)알킬, S(할로(C1-C8)알킬), S(O)(C1-C8)알킬, S(O)(할로(C1-C8)알킬), S(O)2(C1-C8)알킬, S(O)2(할로(C1-C8)알킬), NR14R15, C(=O)H, C(=O)N(R14)(R15), CN(R14)(R15)(=NOH), (C=O)O(C1-C8)알킬, (C=O)OH, 헤테로시클릴, (C2-C8)알케닐, 할로(C2-C8)알케닐, (C2-C8)알키닐,(2) 치환된 (C1-C8)알킬 (여기서 상기 치환된 (C1-C8)알킬은 OH, (C1-C8)알콕시, S(C1-C8)알킬, S(O)(C1-C8)알킬, S(O)2(C1-C8)알킬, NR14R15로부터 선택된 1개 이상의 치환기를 가짐), 및(3) 치환된 할로(C1-C8)알킬 (여기서 상기 치환된 할로(C1-C8)알킬은 (C1-C8)알콕시, S(C1-C8)알킬, S(O)(C1-C8)알킬, S(O)2(C1-C8)알킬, 및 N(R14)(R15)로부터 선택된 1개 이상의 치환기를 가짐)로부터 선택되고;(k) R11은 C(=X5)N(X6)(R14)이고, 여기서 X5는 O, S, 또는 NH로부터 선택되고, X6은 할로시클로(C3-C6) 알킬, 치환된 시클로(C3-C6) 알킬, 및 치환된 할로시클로(C3-C6) 알킬로부터 선택되고, 여기서 상기 치환된 시클로(C3-C6) 알킬은 CN, NO2, (C1-C8)알킬, (C2-C8)알케닐, (C2-C8)알키닐, 할로(C1-C8)알킬, (C1-C8)알콕시, 시클로(C3-C6)알킬, 아릴, 치환된-아릴, (C1-C8)알킬-아릴, (C1-C8)알킬-(치환된-아릴), O-(C1-C8)알킬-아릴, O-(C1-C8)알킬-(치환된-아릴), 헤테로시클릴, 치환된-헤테로시클릴, (C1-C8)알킬-헤테로시클릴, (C1-C8)알킬-(치환된-헤테로시클릴), O-(C1-C8)알킬-헤테로시클릴, O-(C1-C8)알킬-(치환된-헤테로시클릴), N(R15)(R16), C(=X5)N(R15)(R16), (C1-C8)알킬-C(=X5)N(R15)(R16), C(=O)(C1-C8)알킬, C(=O)(할로(C1-C8)알킬), C(=O)(C3-C6)시클로알킬, (C1-C8)알킬-C(=O)O(C1-C8)알킬, 및 C(=O)H로부터 선택된 1개 이상의 치환기로 치환되고, 여기서 상기 치환된 할로시클로(C3-C6) 알킬은 CN, NO2, (C1-C8)알킬, (C2-C8)알케닐, (C2-C8)알키닐, 할로(C1-C8)알킬, (C1-C8)알콕시, 시클로(C3-C6)알킬, 아릴, 치환된-아릴, (C1-C8)알킬-아릴, (C1-C8)알킬-(치환된-아릴), O-(C1-C8)알킬-아릴, O-(C1-C8)알킬-(치환된-아릴), 헤테로시클릴, 치환된-헤테로시클릴, (C1-C8)알킬-헤테로시클릴, (C1-C8)알킬-(치환된-헤테로시클릴), O-(C1-C8)알킬-헤테로시클릴, O-(C1-C8)알킬-(치환된-헤테로시클릴), N(R15)(R16), C(=X5)N(R15)(R16), (C1-C8)알킬-C(=X5)N(R15)(R16), C(=O)(C1-C8)알킬, C(=O)(할로(C1-C8)알킬), C(=O)(C3-C6)시클로알킬, (C1-C8)알킬-C(=O)O(C1-C8)알킬, 및 C(=O)H로부터 선택된 1개 이상의 치환기로 치환되고, 여기서 각각의 상기 치환된 아릴은 F, Cl, Br, I, CN, NO2, (C1-C8)알킬, 할로(C1-C8)알킬, (C1-C8)알콕시, 할로(C1-C8)알콕시, S(C1-C8)알킬, S(할로(C1-C8)알킬), N((C1-C8)알킬)2 (여기서 각각의 (C1-C8)알킬은 독립적으로 선택됨), 및 옥소로부터 선택된 1개 이상의 치환기를 갖고, 여기서 각각의 상기 치환된 헤테로시클릴은 F, Cl, Br, I, CN, NO2, (C1-C8)알킬, 할로(C1-C8)알킬, (C1-C8)알콕시, 할로(C1-C8)알콕시, S(C1-C8)알킬, S(할로(C1-C8)알킬), N((C1-C8)알킬)2 (여기서 각각의 (C1-C8)알킬은 독립적으로 선택됨), C(=O)(C1-C8)알킬, C(=O)(C3-C6)시클로알킬, S(=O)2(C1-C8)알킬, NR14R15, 및 옥소로부터 선택된 1개 이상의 치환기를 갖고;(l...