2-(Het)aryl-substituted condensed bicyclic heterocyclic derivatives as pest control agentsThe invention relates to novel compounds of the formula (I), in which R1, R2, R3, R4, A1, A2 and n have the above-mentioned meanings, to agrochemical formulations containing the compounds according toformula (I), to agrochemical formulations containing the compounds according to formula (I) and to their use as acaricides and/or insecticides for controlling animal pests, primarily arthropods and in particular insects and arachnids.A compound of formula (i)whereina1is nitrogen, ═ n+(o-) -or ═ c (r)5)-，a2is-n (r)6) -, oxygen or sulfur,r1is (c)1-c6) alkyl radicals, (c)1-c6) -haloalkyl, (c)1-c6) cyanoalkyl, (c)1-c6) -hydroxyalkyl, (c)1-c6) -alkoxy- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkoxy- (c)1-c6) alkyl radicals, (c)2-c6) -alkenyl, (c)2-c6) -alkenyloxy- (c)1-c6) alkyl radicals, (c)2-c6) -haloalkenyloxy- (c)1-c6) alkyl radicals, (c)2-c6) -haloalkenyl, (c)2-c6) -cyanoalkenyl, (c)2-c6) -alkynyl, (c)2-c6) -alkynyloxy- (c)1-c6) alkyl radicals, (c)2-c6) -haloalkynyloxy- (c)1-c6) alkyl radicals, (c)2-c6) -haloalkynyl, (c)2-c6) -cyanoalkynyl, (c)3-c8) -cycloalkyl, (c)3-c6) -halocycloalkyl, (c)3-c6) -cyanocycloalkyl, (c)3-c8) -cycloalkyl- (c)3-c8) -cycloalkyl, (c)1-c6) -alkyl- (c)3-c8) -cycloalkyl, halo- (c)3-c8) cycloalkyl, amino, (c)1-c6) alkylamino, di- (c)1-c6) -alkyl-amino, (c)3-c8) -cycloalkylamino, (c)1-c6) -alkylcarbonylamino, (c)1-c6) -alkylthio- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkylthio- (c)1-c6) -alkanesbase, (c)1-c6) -alkylsulfinyl- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkylsulfinyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkylsulfonyl- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkylsulfonyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkoxy- (c)1-c6) -alkylthio- (c)1-c6) alkyl radicals, (c)1-c6) -alkoxy- (c)1-c6) -alkylsulfinyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkoxy- (c)1-c6) -alkylsulfonyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkylcarbonyl- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkylcarbonyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkoxycarbonyl- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkoxycarbonyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkylsulfonylamino, aminosulfonyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkylaminosulfonyl- (c)1-c6) alkyl, di- (c)1-c6) -alkylaminosulfonyl- (c)1-c6) -alkyl or is in each case optionally mono-or poly-aryl-, -heteroaryl-or-heterocyclyl-substituted identically or differently1-c6) alkyl radicals, (c)1-c6) -alkoxy, (c)2-c6) -alkenyl, (c)2-c6) -alkynyl, (c)3-c8) -cycloalkyl, wherein aryl, heteroaryl or heterocyclyl may each be optionally mono-or polysubstituted, identically or differently, by: halogen, cyano, nitro, hydroxy, amino, carboxy, carbamoyl, aminosulfonyl, (c)1-c6) alkyl radicals, (c)3-c6) -cycloalkyl, (c)1-c6) -alkoxy, (c)1-c6) -haloalkyl radicals, (c)1-c6) -haloalkoxy, (c)1-c6) alkylthio group(s), (c)1-c6) -alkylsulfinyl, (c)1-c6) -alkylsulfonyl, (c)1-c6) an alkylsulfimino group, (c)1-c6) -alkylthioimino- (c)1-c6) alkyl radicals, (c)1-c6) -alkylthioimino- (c)2-c6) -alkylcarbonyl, (c)1-c6) -alkylsulfoxide imino group, (c)1-c6) -alkylsulfoxide imino group- (c)1-c6) alkyl radicals, (c)1-c6) -alkylsulfoxide imino group- (c)2-c6) -alkylcarbonyl, (c)1-c6) alkoxycarbonyl, (c)1-c6) -alkylcarbonyl, (c)3-c6) -a trialkylsilyl or benzyl group,r2is a group selected from: -c (═ o) -nr11r12、-c(＝s)-nr11r12、-nr11r12、nr11-c(＝o)-r8and-nr11-c(＝s)-r8，r3is c2-a halogenated alkyl group,r4is hydrogen, cyano, halogen, nitro, acetyl, hydroxyl, amino, scn, tri- (c)1-c6) -alkylsilyl, (c)3-c8) -cycloalkyl, (c)3-c8) -cycloalkyl- (c)3-c8) -cycloalkyl, (c)1-c6) -alkyl- (c)3-c8) -cycloalkyl, halo- (c)3-c8) cycloalkyl, cyano (c)3-c8) -cycloalkyl, (c)1-c6) alkyl radicals, (c)1-c6) -haloalkyl, (c)1-c6) cyanoalkyl, (c)1-c6) -hydroxyalkyl, hydroxycarbonyl- (c)1-c6) -alkoxy, (c)1-c6) -alkoxycarbonyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkoxy- (c)1-c6) alkyl radicals, (c)2-c6) -alkenyl, (c)2-c6) -haloalkenyl, (c)2-c6) -cyanoalkenyl, (c)2-c6) -alkynyl, (c)2-c6) -haloalkynyl, (c)2-c6) -cyanoalkynyl, (c)1-c6) -alkoxy, (c)1-c6) -haloalkoxy, (c)1-c6) -cyanoalkoxy, (c)1-c6) -alkoxycarbonyl- (c)1-c6) -alkoxy, (c)1-c6) -alkoxy- (c)1-c6) -alkoxy, (c)1-c6) -alkylhydroxyimino group, (c)1-c6) -alkoxyimino group, (c)1-c6) -alkyl- (c)1-c6) -alkoxyimino group, (c)1-c6) -haloalkyl- (c)1-c6) -alkoxyimino group, (c)1-c6) alkylthio group(s), (c)1-c6) -haloalkylthio, (c)1-c6) -alkoxy- (c)1-c6) alkylthio group(s), (c)1-c6) -alkylthio- (c)1-c6) alkyl radicals, (c)1-c6) -alkylsulfinyl, (c)1-c6) -haloalkylsulfinyl, (c)1-c6) -alkoxy- (c)1-c6) -alkylsulfinyl, (c)1-c6) -alkylsulfinyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkylsulfonyl, (c)1-c6) -haloalkylsulfonyl, (c)1-c6) -alkoxy- (c)1-c6) -alkylsulfonyl, (c)1-c6) -alkylsulfonyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkylsulfonyloxy, (c)1-c6) -alkylcarbonyl, (c)1-c6) -alkylthiocarbonyl, (c)1-c6) -haloalkylcarbonyl, (c)1-c6) -alkylcarbonyloxy, (c)1-c6) alkoxycarbonyl, (c)1-c6) -haloalkoxycarbonyl, aminocarbonyl, (c)1-c6) -alkylaminocarbonyl, (c)1-c6) -alkylaminothiocarbonyl, di- (c)1-c6) -alkylaminocarbonyl, di- (c)1-c6) -alkylaminothiocarbonyl group, (c)2-c6) -alkenylaminocarbonyl, di- (c)2-c6) -alkenylaminocarbonyl group, (c)3-c8) -cycloalkylaminocarbonyl radical, (c)1-c6) -alkylsulfonylamino, (c)1-c6) alkylamino, di- (c)1-c6) alkylamino, aminosulfonyl, (c)1-c6) -alkylaminosulfonyl, di- (c)1-c6) -alkylaminosulfonyl, (c)1-c6) -alkylsulfoxide imino, aminothiocarbonyl, (c)1-c6) -alkylaminothiocarbonyl, di- (c)1-c6...
해충 방제제로서의 2-(헤트)아릴-치환된 축합된 비시클릭 헤테로시클릭 유도체본 발명은 화학식 (I)의 신규 화합물 (여기서 R1, R2, R3, R4, A1, A2 및 n은 상기-언급된 의미를 가짐), 화학식 (I)에 따른 화합물을 함유하는 농약 제제, 화학식 (I)에 따른 화합물을 함유하는 농약 제제, 및 동물 해충, 주로 절지동물 및 특히 곤충류 및 거미류를 방제하기 위한 살진드기제 및/또는 살곤충제로서의 그의 용도에 관한 것이다.[이미지]화학식 (I)의 화합물.[이미지]여기서A1은 질소, =N+(O-)-, 또는 =C(R5)-이고,A2는 -N(R6)-, 산소 또는 황이고,R1은 (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-히드록시알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C1-C6)-할로알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C3-C8)-시클로알킬, (C3-C6)-할로시클로알킬, (C3-C6)-시아노시클로알킬, (C3-C8)-시클로알킬-(C3-C8)-시클로알킬, (C1-C6)-알킬-(C3-C8)-시클로알킬, 할로-(C3-C8)-시클로알킬, 아미노, (C1-C6)-알킬아미노, 디-(C1-C6)-알킬-아미노, (C3-C8)-시클로알킬아미노, (C1-C6)-알킬카르보닐아미노, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-할로알킬티오-(C1-C6)-알킬, (C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-할로알킬술피닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-할로알킬술포닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-알킬카르보닐-(C1-C6)-알킬, (C1-C6)-할로알킬카르보닐-(C1-C6)-알킬, (C1-C6)-알콕시카르보닐-(C1-C6)-알킬, (C1-C6)-할로알콕시카르보닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐아미노, 아미노술포닐-(C1-C6)-알킬, (C1-C6)-알킬아미노술포닐-(C1-C6)-알킬, 디-(C1-C6)-알킬아미노술포닐-(C1-C6)-알킬이거나,또는 각 경우에 임의로 동일하거나 상이하게 일- 또는 다-아릴-, -헤타릴- 또는 -헤테로시클릴-치환된 (C1-C6)-알킬, (C1-C6)-알콕시, (C2-C6)-알케닐, (C2-C6)-알키닐, (C3-C8)-시클로알킬이고, 여기서 아릴, 헤타릴 또는 헤테로시클릴은 각각 할로겐, 시아노, 니트로, 히드록실, 아미노, 카르복실, 카르바모일, 아미노술포닐, (C1-C6)-알킬, (C3-C6)-시클로알킬, (C1-C6)-알콕시, (C1-C6)-할로알킬, (C1-C6)-할로알콕시, (C1-C6)-알킬티오, (C1-C6)-알킬술피닐, (C1-C6)-알킬술포닐, (C1-C6)-알킬술프이미노, (C1-C6)-알킬술프이미노-(C1-C6)-알킬, (C1-C6)-알킬술프이미노-(C2-C6)-알킬카르보닐, (C1-C6)-알킬술폭시미노, (C1-C6)-알킬술폭시미노-(C1-C6)-알킬, (C1-C6)-알킬술폭시미노-(C2-C6)-알킬카르보닐, (C1-C6)-알콕시카르보닐, (C1-C6)-알킬카르보닐, (C3-C6)-트리알킬실릴 또는 벤질에 의해 임의로 동일하거나 상이하게 일- 또는 다치환될 수 있고,R2는 -C(=O)-NR11R12, -C(=S)- NR11R12, -NR11R12, NR11-C(=O)-R8 및 -NR11-C(=S)-R8로부터 선택된 기이고,R3은 C2-할로알킬이고,R4는 수소, 시아노, 할로겐, 니트로, 아세틸, 히드록실, 아미노, SCN, 트리-(C1-C6)-알킬실릴, (C3-C8)-시클로알킬, (C3-C8)-시클로알킬-(C3-C8)-시클로알킬, (C1-C6)-알킬-(C3-C8)-시클로알킬, 할로-(C3-C8)-시클로알킬, 시아노(C3-C8)-시클로알킬, (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-히드록시알킬, 히드록시카르보닐-(C1-C6)-알콕시, (C1-C6)-알콕시카르보닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C1-C6)-알콕시, (C1-C6)-할로알콕시, (C1-C6)-시아노알콕시, (C1-C6)-알콕시카르보닐-(C1-C6)-알콕시, (C1-C6)-알콕시-(C1-C6)-알콕시, (C1-C6)-알킬히드록시이미노, (C1-C6)-알콕시이미노, (C1-C6)-알킬-(C1-C6)-알콕시이미노, (C1-C6)-할로알킬-(C1-C6)-알콕시이미노, (C1-C6)-알킬티오, (C1-C6)-할로알킬티오, (C1-C6)-알콕시-(C1-C6)-알킬티오, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알킬술피닐, (C1-C6)-할로알킬술피닐, (C1-C6)-알콕시-(C1-C6)-알킬술피닐, (C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐, (C1-C6)-할로알킬술포닐, (C1-C6)-알콕시-(C1-C6)-알킬술포닐, (C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐옥시, (C1-C6)-알킬카르보닐, (C1-C6)-알킬티오카르보닐, (C1-C6)-할로알킬카르보닐, (C1-C6)-알킬카르보닐옥시, (C1-C6)-알콕시카르보닐, (C1-C6)-할로알콕시카르보닐, 아미노카르보닐, (C1-C6)-알킬아미노카르보닐, (C1-C6)-알킬아미노티오카르보닐, 디-(C1-C6)-알킬아미노카르보닐, 디-(C1-C6)-알킬아미노티오카르보닐, (C2-C6)-알케닐아미노카르보닐, 디-(C2-C6)-알케닐아미노카르보닐, (C3-C8)-시클로알킬아미노카르보닐, (C1-C6)-알킬술포닐아미노, (C1-C6)-알킬아미노, 디-(C1-C6)-알킬아미노, 아미노술포닐, (C1-C6)-알킬아미노술포닐, 디-(C1-C6)-알킬아미노술포닐, (C1-C6)-알킬술폭시미노, 아미노티오카르보닐, (C1-C6)-알킬아미노티오카르보닐, 디-(C1-C6)-알킬아미노티오카르보닐, (C3-C8)-시클로알킬아미노, NHCO-(C1-C6)-알킬 ((C1-C6)-알킬카르보닐아미노)이고,각 경우에 임의로 단독으로 또는 다중으로 동일하거나 상이하게 치환된 아릴 또는 헤타릴이고, 여기서 (헤타릴의 경우) 적어도 1개의 카르보닐 기가 임의로 존재할 수 있고 여기서 가능한 치환기는 각 경우에 하기: 시아노, 카르복실, 할로겐, 니트로, 아세틸, 히드록실, 아미노, SCN, 트리-(C1-C6)알킬실릴, (C3-C8)시클로알킬, (C3-C8)시클로알킬-(C3-C8)시클로알킬, (C1-C6)알킬-(C3-C8)시클로알킬, 할로(C3-C8)시클로알킬, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)히드록시알킬, 히드록시카르보닐-(C1-C6)-알콕시, (C1-C6)알콕시카르보닐-(C1-C6)알킬, (C1-C6)알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐, (C2-C6)시아노알키닐, (C1-C6)알콕시, (C1-C6)할로알콕시, (C1-C6)시아노알콕시, (C1-C6)알콕시카르보닐-(C1-C6)알콕시, (C1-C6)알콕시-(C1-C6)알콕시, (C1-C6)알킬히드록시이미노, (C1-C6)알콕시이미노, (C1-C6)알킬-(C1-C6)알콕시이미노, (C1-C6)할로알킬-(C1-C6)알콕시이미노, (C1-C6)알킬티오, (C1-C6)할로알킬티오, (C1-C6)알콕시-(C1-C6)알킬티오, (C1-C6)알킬티오-(C1-C6)알킬, (C1-C6)알킬술피닐, (C1-C6)할로알킬술피닐, (C1-C6)알콕시-(C1-C6)알킬술피닐, (C1-C6)알킬술피닐-(C1-C6)알킬, (C1-C6)알킬술포닐, (C1-C6)할로알킬술포닐, (C1-C6)알콕시-(C1-C6)알킬술포닐, (C1-C6)알킬술포닐-(C1-C6)알킬, (C1-C6)알킬술포닐옥시, (C1-C6)알킬카르보닐, (C1-C6)할로알킬카르보닐, (C1-C6)알킬카르보닐옥시, (C1-C6)알콕시카르보닐, (C1-C6)할로알콕시카르보닐, 아미노카르보닐, (C1-C6)알킬아미노카르보닐, 디-(C1-C6)알킬아미노카르보닐, (C2-C6)알케닐아미노카르보닐, 디-(C2-C6)-알케닐아미노카르보닐, (C3-C8)시클로알킬아미노카르보닐, (C1-C6)알킬술포닐아미노, (C1-C6)알킬아미노, 디-(C1-C6)알킬아미노, 아미노술포닐, (C1-C6)알킬아미노술포닐, 디-(C1-C6)알킬아미노술포닐, (C1-C6)알킬술폭시미노, 아미노티오카르보닐, (C1-C6)알킬아미노티오카르보닐, 디-(C1-C6)알킬아미노티오카르보닐, (C3-C8)시클로알킬아미노, (C1-C6)알킬카르보닐아미노와 같고,R5는 수소, 시아노, 할로겐, 니트로, 아세틸, 히드록실, 아미노, SCN, 트리-(C1-C6)-알킬실릴, (C3-C8)-시클로알킬, (C3-C8)-시클로알킬-(C3-C8)-시클로알킬, (C1-C6)-알킬-(C3-C8)-시클로알킬, 할로-(C3-C8)-시클로알킬, (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-히드록시알킬, 히드록시카르보닐-(C1-C6)-알콕시, (C1-C6)-알콕시카르보닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C1-C6)-알콕시, (C1-C6)-할로알콕시, (C1-C6)-시아노알콕시, (C1-C6)-알콕시카르보닐-(C1-C6)-알콕시, (C1-C6)-알콕시-(C1-C6)-알콕시, (C1-C6)-알킬히드록시이미노, (C1-C6)-알콕시이미노, (C1-C6)-알킬-(C1-C6)-알콕시이미노, (C1-C6)-할로알킬-(C1-C6)-알콕시이미노, (C1-C6)-알킬티오, (C1-C6)-할로알킬티오, (C1-C6)-알콕시-(C1-C6)-알킬티오, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알킬술피닐, (C1-C6)-할로알킬술피닐, ...