Stable Formulation of Pesticidal PyridazinpyrazolamidesThe invention relates to an agrochemical composition comprising propylene carbonate, up to 10 wt % of water, and compounds I [Image]their salts, tautomers, or enantiomers; wherein the variables are as defined in the description. The invention also relates to a process for the preparation of the composition, comprising mixing the propylene carbonate, compounds I, and optionally an acid and/or cyclohexanone. It also relates to a method for controlling pests, which method comprises the application of the composition, or a dilution thereof, to plants, plant propagation material, or the locus of growth of the plants; the pests or their food supply, habitat or breeding grounds. Other objects are the use of cyclohexanone and/or an acid, in particular acetic acid, for stabilizing compositions comprising compounds I; composition for stabilizing water-soluble pesticides as defined in any of claims 1 to 9, comprising 1 to 50 wt % of propylene carbonate, 0.1 to 30 wt % cyclohexanone, and an acid; and an aqueous tank-mix composition comprising the composition in a concentration of 0.01 wt % to 10 wt % with regard to the total weight of the tank-mix.An agrochemical composition comprising a) propylene carbonateb) up to 10 wt % of water; andc) compound (I) [Image]or a salt, a tautomer, or an enantiomer thereof;wherein the variables have the meaningR1 H, C1-C2-alkyl, or C1-C2-alkoxy-C1-C2-alkyl;R2 H, halogen, CN, or NO2; C1-C10-alkyl, C2-C10-alkenyl, or C2-C10-alkynyl, which are unsubstituted, halogenated, or substituted with Rx;ORa, SRa, C(Y)Rb, C(Y)ORc, S(O)Rd, S(O)2Rd, NReRf, C(Y)NRgRh;heterocyclyl, hetaryl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, or phenyl, which are unsubstituted, or substituted with Ry, or Rx;R3 H, halogen, CN, NO2; C1-C10-alkyl, C2-C10-alkenyl, or C2-C10-alkynyl, which are unsubstituted, halogenated, or substituted with Rx;ORa, SRa, C(Y)Rb, C(Y)ORc, S(O)Rd, S(O)2Rd, NReRf, C(Y)NRgRh;heterocyclyl, hetaryl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl or phenyl, which are unsubstituted, or substituted with Ry, or Rx;RN H, CN, NO2; C1-C10-alkyl, C2-C10-alkenyl, or C2-C10-alkynyl, which are unsubstituted, halogenated, or substituted with Rx;ORa, SRa, C(Y)Rb, C(Y)ORc, S(O)Rd, S(O)2Rd, NReRf, C(Y)NRgRh, S(O)mNReRf, C(Y)NRiNReRf, C1-C5-alkylen-ORa, C1-C5-alkylen-CN, C1-C5-alkylen-C(Y)Rb, C1-C5-alkylen-C(Y)ORc, C1-C5-alkylen-NReRf, C1-C5-alkylen-C(Y)NRgRh, C1-C5-alkylen-S(O)mRd, C1-C5-alkylen-S(O)mNReRf, C1-C5-alkylen-NRiNReRf;heterocyclyl, hetaryl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, heterocyclyl-C1-C5-alkyl, hetaryl-C1-C5-alkyl, C3-C10-cycloalkyl-C1-C5-alkyl, C3-C10-cycloalkenyl-C1-C5-alkyl, phenyl-C1-C5-alkyl, or phenyl, in which groups the rings are unsubstituted, or substituted with Ry; Ra, Rb, Rc independently H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C1-C4-alkoxy-C1-C4-alkyl; or heterocyclyl, heterocyclyl-C1-C4-alkyl, phenyl, hetaryl, phenyl-C1-C4-alkyl, hetaryl-C1-C4-alkyl, in which groups the ring is unsubstituted, or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;Rd C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C1-C4-alkoxy-C1-C4-alkyl; or heterocyclyl, heterocyclyl-C1-C4-alkyl, phenyl, hetaryl, phenyl-C1-C4-alkyl, and hetaryl-C1-C4-alkyl, in which groups the ring is unsubstituted, or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;Re, Rf independently H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl; heterocyclyl, heterocyclyl-C1-C4-alkyl, heterocyclylcarbonyl, heterocyclylsulfonyl, phenyl, phenylcarbonyl, phenylsulfonyl, hetaryl, hetarylcarbonyl, hetarylsulfonyl, phenyl-C1-C4-alkyl, and hetaryl-C1-C4-alkyl, in which groups the ring is unsubstituted, or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, and C1-C4-haloalkoxy; orRe and Rf are together with the nitrogen atom to which they are bound form a 5- or 6-membered, saturated, or unsaturated heterocycle, in which heterocycle none, or one ring member atom is replaced by O, S or N, and wherein the heterocycle is unsubstituted or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;Rg, Rh independently H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C1-C4-alkoxy-C1-C4-alkyl; heterocyclyl, heterocyclyl-C1-C4-alkyl, phenyl, hetaryl, phenyl-C1-C4-alkyl, and hetaryl-C1-C4-alkyl, in which groups the ring is unsubstituted, or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;Ri H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C1-C4-alkoxy-C1-C4-alkyl; or phenyl, phenyl-C1-C4-alkyl, in which groups the phenyl rings is unsubstituted, or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;Rx CN, NO2, C1-C4-alkoxy, C1-C4-haloalkoxy, S(O)mRd, S(O)mNReRf, C1-C10-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-haloalkoxycarbonyl; or C3-C6-cycloalkyl, 5- to 7-membered heterocyclyl, 5- or 6-membered hetaryl, phenyl, C3-C6-cycloalkoxy, 3- to 6-membered heterocyclyloxy, phenoxy, which are unsubstituted, or substituted with Ry;Ry halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, S(O)mRd, S(O)mNReRf, C1-C4-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-haloalkoxycarbonyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, or C1-C4-alkoxy-C1-C4-alkyl;Y O or S; andm is 0, 1 or 2.
살충성 피리다진피라졸아미드의 안정한 제형본 발명은 프로필렌 카보네이트, 최대 10 중량%의 물, 및 화합물 I [이미지]그의 염, 호변이성질체 또는 거울상이성질체를 포함하는 농약 조성물에 관한 것입니다. 여기서 변수는 설명에 정의된 대로입니다. 본 발명은 또한 프로필렌 카보네이트, 화합물 I, 및 임의로 산 및/또는 시클로헥사논을 혼합하는 것을 포함하는 조성물의 제조 방법에 관한 것이다. 이는 또한 식물, 식물 번식 물질, 또는 식물의 성장 장소에 조성물 또는 이의 희석액을 적용하는 것을 포함하는 해충 구제 방법에 관한 것이며; 해충 또는 그들의 식량 공급, 서식지 또는 번식지. 다른 목적은 화합물 I; 1 내지 50 중량%의 프로필렌 카보네이트, 0.1 내지 30 중량%의 사이클로헥사논, 및 산을 포함하는 제1항 내지 제9항 중 어느 한 항에 정의된 수용성 살충제 안정화용 조성물; 및 탱크 믹스의 총 중량에 대하여 0.01 중량% 내지 10 중량% 농도의 조성물을 포함하는 수성 탱크 믹스 조성물을 포함한다.a) 프로필렌 카보네이트b) 최대 10 중량%의 물; 및c) 화합물 (I) 또는 그의 염, 호변이성질체 또는 거울상이성질체(여기서 변수는 R1H, C1-C2-알킬, 또는 C1-C2-알콕시-C1-C2-알킬, R2H의 의미를 가짐); , 할로겐, CN 또는 NO2; 비치환, 할로겐화 또는 Rx;ORa, SRa, C(Y)Rb, C(Y)ORc, S(O)로 치환된 C1-C10-알킬, C2-C10-알케닐 또는 C2-C10-알키닐 Rd, S(O)2Rd, NReRf, C(Y)NRgRh, 헤테로시클릴, 헤타릴, C3-C10-시클로알킬, C3-C10-시클로알케닐, 또는 페닐(비치환 또는 Ry, 또는 Rx;R3H로 치환되며,), 할로겐, CN, NO2; 비치환, 할로겐화 또는 Rx;ORa, SRa, C(Y)Rb, C(Y)ORc, S(O)로 치환된 C1-C10-알킬, C2-C10-알케닐 또는 C2-C10-알키닐 Rd, S(O)2Rd, NReRf, C(Y)NRgRh; 헤테로시클릴, 헤타릴, C3-C10-시클로알킬, C3-C10-시클로알케닐 또는 페닐(비치환 또는 Ry로 치환되며,), 또는 Rx;RN H, CN , NO2; 비치환, 할로겐화 또는 Rx;ORa, SRa, C(Y)Rb, C(Y)ORc, S(O)로 치환된 C1-C10-알킬, C2-C10-알케닐 또는 C2-C10-알키닐 Rd, S(O)2Rd, NReRf, C(Y)NRgRh, S(O)mNReRf, C(Y)NRiNReRf, C1-C5-알킬렌-ORa, C1-C5-알킬렌-CN, C1-C5-알킬렌- C(Y)Rb, C1-C5-알킬렌-C(Y)ORc, C1-C5-알킬렌-NReRf, C1-C5-알킬렌-C(Y)NRgRh, C1-C5-알킬렌-S(O)mRd, C1-C5-알킬렌-S(O)mNReRf, C1-C5-알킬렌-NRiNReRf, 헤테로시클릴, 헤타릴, C3-C10-시클로알킬, C3-C10-시클로알케닐, 헤테로시클릴-C1-C5-알킬, 헤타릴-C1-C5- 알킬, C3-C10-시클로알킬-C1-C5-알킬, C3-C10-시클로알케닐-C1-C5-알킬, 페닐-C1-C5-알킬, 또는 페닐(여기서, 고리는 비치환되거나 Ry로 치환되며,); Ra, Rb, Rc는 독립적으로 H, C1-C4-알킬, C1-C4-할로알킬, C3-C6-시클로알킬, C3-C6-시클로알킬메틸, C3-C6-할로시클로알킬, C2-C4-알케닐, C2-C4-할로알케닐, C2-C4-알키닐, C1-C4-알콕시-C1-C4-알킬; 또는 헤테로시클릴, 헤테로시클릴-C1-C4-알킬, 페닐, 헤타릴, 페닐-C1-C4-알킬, 헤타릴-C1-C4-알킬이고, 여기서 고리는 치환되지 않거나 할로겐, CN, NO2, C1- C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, 또는 C1-C4-할로알콕시; Rd C1-C4-알킬, C1-C4-할로알킬, C3-C6-시클로알킬, C3-C6-시클로알킬메틸, C3- C6-할로시클로알킬, C2-C4-알케닐, C2-C4-할로알케닐, C2-C4-알키닐, C1-C4-알콕시-C1-C4-알킬; 또는 헤테로시클릴, 헤테로시클릴-C1-C4-알킬, 페닐, 헤타릴, 페닐-C1-C4-알킬, 및 헤타릴-C1-C4-알킬이고, 여기서 고리는 치환되지 않거나 할로겐, CN, NO2, C1으로 치환되고, -C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, 또는 C1-C4-할로알콕시; Re, Rf는 독립적으로 H, C1-C4-알킬, C1-C4-할로알킬, C3-C6-시클로알킬, C3- C6-시클로알킬메틸, C3-C6-할로시클로알킬, C2-C4-알케닐, C2-C4-할로알케닐, C2-C4-알키닐, C1-C4-알콕시-C1-C4-알킬, C1-C4-알킬카르보닐, C1-C4- 할로알킬카르보닐, C1-C4-알킬술포닐, C1-C4-할로알킬술포닐; 헤테로시클릴, 헤테로시클릴-C1-C4-알킬, 헤테로시클릴카르보닐, 헤테로시클릴술포닐, 페닐, 페닐카르보닐, 페닐술포닐, 헤타릴, 헤타릴카르보닐, 헤타릴술포닐, 페닐-C1-C4-알킬, 및 헤타릴-C1-C4-알킬, 여기서 고리는 비치환되며, 또는 할로겐, CN, NO2, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시 및 C1-C4-할로알콕시로 치환되고; 또는Re 및 Rf는 이들이 결합된 질소 원자와 함께 5원 또는 6원, 포화 또는 불포화 헤테로사이클을 형성하고, 여기서 헤테로사이클이 없거나 하나의 고리 구성원 원자가 O, S 또는 N으로 대체되고, 여기서 헤테로사이클은 비치환되거나 할로겐, CN, NO2, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시 또는 C1-C4-할로알콕시로 치환되고; Rg, Rh는 독립적으로 H, C1-C4-알킬, C1-C4-할로알킬, C3-C6-시클로알킬, C3-C6-할로시클로알킬, C2-C4-알케닐, C2-C4-할로알케닐, C2-C4-알키닐, C1-C4-알콕시-C1-C4-알킬; 헤테로시클릴, 헤테로시클릴-C1-C4-알킬, 페닐, 헤타릴, 페닐-C1-C4-알킬, 및 헤타릴-C1-C4-알킬, 여기서 고리는 치환되지 않거나 할로겐, CN, NO2, C1- C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, 또는 C1-C4-할로알콕시; C3-C6-할로시클로알킬, C2-C4-알케닐, C2-C4-할로알케닐, C2-C4-알키닐, C1-C4-알콕시-C1-C4-알킬; 또는 페닐, 페닐-C1-C4-알킬, 여기서 페닐 고리는 비치환되거나 할로겐, CN, NO2, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, 또는 C1- C4-할로알콕시; Rx CN, NO2, C1-C4-알콕시, C1-C4-할로알콕시, S(O)mRd, S(O)mNReRf, C1-C10-알킬카르보닐, C1-C4-할로알킬카르보닐, C1-C4-알콕시카르보닐 , C1-C4-할로알콕시카르보닐; 또는 Ry로 치환되거나 비치환된 C3-C6-시클로알킬, 5- 내지 7-원 헤테로시클릴, 5- 또는 6-원 헤타릴, 페닐, C3-C6-시클로알콕시, 3- 내지 6-원 헤테로시클릴옥시, 페녹시이고; Ry 할로겐, CN, NO2, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시, S(O)mRd, S(O)mNReRf, C1-C4-알킬카르보닐, C1 -C4-할로알킬카르보닐, C1-C4-알콕시카르보닐, C1-C4-할로알콕시카르보닐, C3-C6-시클로알킬, C3-C6-할로시클로알킬, C2-C4-알케닐, C2-C4-할로알케닐, C2-C4-알키닐, 또는 C1- C4-알콕시-C1-C4-알킬, YO 또는 S; 및 m은 0, 1 또는 2인 것을 특징으로 하는 농약 조성물.