Phenyl acetic acid derivatives, process and intermediate products for their production and their use as parasiticides and fungicidesPhenylacetic acid derivatives of the formula I where the substituents and the index have the following meanings: X is NOCH3, CHOCH3 and CHCH3; Y is NR and O; R, R1 are hydrogen and C1-C4-alkyl; R2 is hydrogen, C1-C6-alkyl, C1-C4-haloalkyl and C3-C6-cycloalkyl; R3 is C4-C6-cycloalkyl, C2-C6-alkyl, substituted C1-C6-alkyl, unsubstituted or substituted C2-C6-alkynyl or unsubstituted or substituted C2-C6-alkenyl, R4 is hydrogen, unsubstituted or substituted C1-C10-alkyl, C3-C6-cycloalkyl, C2-C10-alkenyl, C2-C10-alkynyl, C1-C10-alkylcarbonyl, C2-C10-alkenylcarbonyl, C3-C10-alkynylcarbonyl or C1-C10-alkylsulfonyl, aryl, arylcarbonyl, arylsulfonyl, hetaryl, hetarylcarbonyl or hetarylsulfonyl, and the salts thereof, processes and intermediates for their preparation, and their use.Formula i phenylacetic acid derivatives or its salt: wherein each substituting group and symbol have following implication: x represents noch 3, choch 3and chch 3y represents nr and o; r, r 1represent hydrogen and c 1-c 4alkyl; r 2represent hydrogen, c 1-c 6alkyl, c 1-c 4haloalkyl and c 3-c 6cycloalkyl; r 3represent c 4-c 6cycloalkyl, c 2-c 6alkyl or partly or entirely halogenated and/or be connected with the c of one to three following radicals 1-c 6alkyl: cyano group, nitro, hydroxyl, sulfydryl, amino, carboxyl, aminocarboxyl, amino thiocarbonyl, halogen, c 1-c 6alkyl amino-carbonyl, two-c 1-c 6alkyl amino-carbonyl, c 1-c 6thio-alkyl amino-carbonyl, two-c 1-c 6thio-alkyl amino-carbonyl, c 1-c 6alkyl sulphonyl, c 1-c 6alkyl sulphinyl, c 1-c 6alkoxyl group, c 1-c 6halogenated alkoxy, c 1-c 6alkoxy carbonyl, c 1-c 6alkylthio, c 1-c 6alkylamino, two-c 1-c 6alkylamino, c 2-c 6alkenyloxy, c 3-c 6cycloalkyl, c 3-c 6cycloalkyloxy, heterocyclic radical, heterocyclic oxy group, aryl, aryloxy, aryl-c 1-c 4alkoxyl group, arylthio, aryl-c 1-c 4alkylthio, heteroaryl, heteroaryloxy, heteroaryl-c 1-c 4alkoxyl group, heteroarylthio, heteroaryl-c 1-c 4alkylthio, wherein said cyclic group itself can be connected with one to three following radicals again on part or all of halo and/or its: cyano group, nitro, hydroxyl, sulfydryl, amino, carboxyl, aminocarboxyl, amino thiocarbonyl, c 1-c 6alkyl, c 1-c 6haloalkyl, c 1-c 6alkyl sulphonyl, c 1-c 6alkyl sulphinyl, c 3-c 6cycloalkyl, c 1-c 6alkoxyl group, c 1-c 6halogenated alkoxy, c 1-c 6carbalkoxy, c 1-c 6alkylthio, c 1-c 6alkylamino, two-c 1-c 6alkylamino, c 1-c 6alkyl amino-carbonyl, two-c 1-c 6alkyl amino-carbonyl, c 1-c 6thio-alkyl amino-carbonyl, two-c 1-c 6thio-alkyl amino-carbonyl, c 2-c 6alkenyl, c 2-c 6alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy, heteroarylthio and c (=nor a)-a n-r bc 2-c 6alkynyl or c 2-c 6alkenyl, these groups can be partly or entirely halogenated or its on be connected with one to three following radicals: cyano group, nitro, hydroxyl, sulfydryl, amino, carboxyl, aminocarboxyl, amino thiocarbonyl, halogen, c 1-c 6alkyl amino-carbonyl, two-c 1-c 6alkyl amino-carbonyl, c 1-c 6thio-alkyl amino-carbonyl, two-c 1-c 6thio-alkyl amino-carbonyl, c 1-c 6alkyl sulphonyl, c 1-c 6alkyl sulphinyl, c 1-c 6alkoxyl group, c 1-c 6halogenated alkoxy, c 1-c 6carbalkoxy, c 1-c 6alkylthio, c 1-c 6alkylamino, two-c 1-c 6alkylamino, c 2-c 6alkenyloxy, c 3-c 6cycloalkyl, c 3-c 6cycloalkyloxy, heterocyclic radical, heterocyclic oxy group, aryl, aryloxy, aryl-c 1-c 4alkoxyl group, arylthio, aryl-c 1-c 4alkylthio, heteroaryl, heteroaryloxy, heteroaryl-c 1-c 4alkoxyl group, heteroarylthio, heteroaryl-c 1-c 4alkylthio, wherein said cyclic group itself again can be partly or entirely be connected with one to three following radicals on halo and/or its: cyano group, nitro, hydroxyl, sulfydryl, amino, carboxyl, aminocarboxyl, amino thiocarbonyl, c 1-c 6alkyl, c 1-c 6haloalkyl, c 1-c 6alkyl sulphonyl, c 1-c 6alkyl sulphinyl, c 3-c 6cycloalkyl, c 1-c 6alkoxyl group, c 1-c 6halogenated alkoxy, c 1-c 6carbalkoxy, c 1-c 6alkylthio, c 1-c 6alkylamino, two-c 1-c 6alkylamino, c 1-c 6alkyl amino-carbonyl, two-c 1-c 6alkyl amino-carbonyl, c 1-c 6thio-alkyl amino-carbonyl, two-c 1-c 6thio-alkyl amino-carbonyl, c 2-c 6alkenyl, c 2-c 6alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy, heteroarylthio and c (=nor a)-a n-r br 4represent hydrogen; c 1-c 10alkyl, c 3-c 6cycloalkyl, c 2-c 10alkenyl, c 2-c 10alkynyl, c 1-c 10alkyl-carbonyl, c 2-c 10alkenyl carbonyl, c 3-c 10alkynyl carbonyl or c 1-c 10alkyl sulphonyl, these groups can be connected with one to three following radicals on part or all of halo or its: cyano group, nitro, hydroxyl, sulfydryl, amino, carboxyl, aminocarboxyl, amino thiocarbonyl, halogen, c 1-c 6alkyl, c 1-c 6haloalkyl, c 1-c 6alkyl sulphonyl, c 1-c 6alkyl sulphinyl, c 1-c 6alkoxyl group, c 1-c 6halogenated alkoxy, c 1-c 6carbalkoxy, c 1-c 6alkylthio, c 1-c 6alkylamino, two-c 1-c 6alkylamino, c 1-c 6alkyl amino-carbonyl, two-c 1-c 6alkyl amino-carbonyl, c 1-c 6thio-alkyl amino-carbonyl, two-c 1-c 6thio-alkyl amino-carbonyl, c 2-c 6alkenyl, c 2-c 6alkenyloxy, c 3-c 6cycloalkyl, c 3-c 6cycloalkyloxy, heterocyclic radical, heterocyclic oxy group, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy and heteroarylthio, wherein said cyclic group itself can be connected with one to three following radicals again on part or all of halo or its: cyano group, nitro, hydroxyl, sulfydryl, amino, carboxyl, aminocarboxyl, amino thiocarbonyl, halogen, c 1-c 6alkyl, c 1-c 6haloalkyl, c 1-c 6alkyl sulphonyl, c 1-c 6alkyl sulphinyl, c 3-c 6cycloalkyl, c 1-c 6alkoxyl group, c 1-c 6halogenated alkoxy, c 1-c 6carbalkoxy, c 1-c 6alkylthio, c 1-c 6alkylamino, two-c 1-c 6alkylamino, c 1-c 6alkyl amino-carbonyl, two-c 1-c 6alkyl amino-carbonyl, c 1-c 6thio-alkyl amino-carbonyl, two-c 1-c 6thio-alkyl amino-carbon...
페닐아세트산 유도체, 그의 제조 방법, 제조를 위한 중간 생성물, 및 구충제 및 살질균제로서 그의 용도 본 발명은 화학식 I의 페닐아세트산 유도체 및 그의 염, 제조 방법 및 제조를 위한 중간 생산물 및 그의 용도에 관한 것이다.(상기 식에서,X는 NOCH3, CHOCH3 및 CHCH3이고;Y은 NR 및 O이고;R, R1은 수소 및 C1-C4-알킬이고;R2는 수소, C1-C6-알킬, C1-C4-알킬할라이드 및 C3-C6-시클로알킬이고;R3은 C4-C6-알킬, 치환된 C1-C6-알킬, 가능하게는 치환된 C2-C6-알키닐 또는 가능하게는 치환된 C2-C6-알케닐이고, R4는 수소, 가능하게는 치환된 C1-C10-알케닐, C2-C10-알키닐, C1-C10-알킬카르보닐, C2-C10-알케닐카르보닐, C3-C10-알키닐카르보닐 또는 C1-C10-알킬술포닐, 아릴, 아릴카르보닐, 아릴술포닐, 헤트아릴, 헤트아릴카르보닐 또는 헤트아릴술포닐임)화학식 I의 페닐아세트산 유도체 및 그의 염. [이미지] 상기 식에서, X는 NOCH3, CHOCH3 및 CHCH3이고; Y은 NR 및 O이고; R 및 R1은 수소 및 C1-C4-알킬이고; R2는 수소, C1-C6-알킬, C1-C4-할로알킬 및 C3-C6-시클로알킬이고; R3은 C4-C6-시클로알킬, C2-C6-알킬, 또는 부분적으로 또는 완전히 할로겐화되고(되거나) 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, 할로겐, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C1-C6-알킬술포닐, C1-C6-알킬술폭실, C1-C6-알콕시, C1-C6-할로알콕시, C1-C6-알콕시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C6-알킬아미노, C2-C6-알케닐옥시, C3-C6-시클로알킬, C3-C6-시클로알킬옥시, 헤테로시클릴, 헤테로시클릴옥시, 아릴, 아릴옥시, 아릴-C1-C4-알콕시, 아릴티오, 아릴-C1-C4-알킬티오, 헤트아릴, 헤트아릴옥시, 헤트아릴-C1-C4-알콕시, 헤트아릴티오, 헤트아릴-C1-C4-알킬티오 중 1 내지 3개에 결합되어 있는 C1-C6-알킬 [여기서, 상기 시클릭기는 또한, 부분적으로 또는 완전히 할로겐화될 수 있고(있거나), 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, C1-C6-알킬, C1-C6-할로알킬, C1-C6-알킬술포닐, C1-C6-알킬술폭실, C3-C6-시클로알킬, C1-C6-알콕시, C1-C6-할로알콕시, C1-C6-알콕시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C6-알킬아미노, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C2-C6-알케닐, C2-C6-알케닐옥시, 벤질, 벤질옥시, 아릴, 아릴옥시, 아릴티오, 헤트아릴, 헤트아릴옥시, 헤트아릴티오 및 C(=NORa)-An-Rb 중 1개 내지 3개와 결합할 수 있음], C2-C6-알키닐 또는 C2-C6-알케닐 [이 기들은 부분적으로 또는 완전히 할로겐화되거나, 또는 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, 할로겐, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C1-C6-알킬술포닐, C1-C6-알킬술폭실, C1-C6-알콕시, C1-C6-할로알콕시, C1-C6-알콕시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C6-알킬아미노, C2-C6-알케닐옥시, C3-C6-시클로알킬, C3-C6-시클로알킬옥시, 헤테로시클릴, 헤테로시클릴옥시, 아릴, 아릴옥시, 아릴-C1-C4-알콕시, 아릴티오, 아릴-C1-C4-알킬티오, 헤트아릴, 헤트아릴옥시, 헤트아릴-C1-C4-알콕시, 헤트아릴티오, 헤트아릴-C1-C4-알킬티오 중 1개 내지 3개와 결합할 수 있고, 여기서 상기 시클릭기는 또한 부분적으로 또는 완전히 할로겐화될 수 있고(있거나), 또는 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, C1-C6-알킬, C1-C6-할로알킬, C1-C6-알킬술포닐, C1-C6-알킬술폭실, C3-C6-시클로알킬, C1-C6-알콕시, C1-C6-할로알콕시, C1-C6-알콕시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C6-알킬아미노, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C2-C6-알케닐, C2-C6-알케닐옥시, 벤질, 벤질옥시, 아릴, 아릴옥시, 아릴티오, 헤트아릴, 헤트아릴옥시, 헤트아릴티오 및 C(=NORa)-An-Rb 중 1개 내지 3개와 결합될 수 있음]이고; R4는 수소, C1-C10-알킬, C3-C6-시클로알킬, C2-C10-알케닐, C2-C10-알키닐, C1-C10-알킬카르보닐, C2-C10-알케닐카르보닐, C3-C10-알키닐카르보닐 또는 C1-C10-알킬술포닐 [이 기들은 부분적으로 또는 완전히 할로겐화될 수 있거나, 또는 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, 할로겐, C1-C6-알킬, C1-C6-할로알킬, C1-C6-알킬술포닐, C1-C6-알킬술폭실, C1-C6-알콕시, C1-C6-할로알콕시, C1-C6-알킬옥시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C6-알킬아미노, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C2-C6-알케닐, C2-C6-알케닐옥시, C3-C6-시클로알킬, C3-C6-시클로알킬옥시, 헤테로시클릴, 헤테로시클릴옥시, 벤질, 벤질옥시, 아릴, 아릴옥시, 아릴티오, 헤트아릴, 헤트아릴옥시 및 헤트아릴티오 중 1개 내지 3개와 결합할 수 있으며, 여기서 시클릭기는 또한 부분적으로 또는 완전히 할로겐화될 수 있거나, 또는 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, 할로겐, C1-C6-알킬, C1-C6-할로알킬, C1-C6-알킬술포닐, C1-C6-알킬술폭실, C3-C6-시클로알킬, C1-C6-알콕시, C1-C6-할로알콕시, C1-C6-알킬옥시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C6-알킬아미노, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C2-C6-알케닐, C2-C6-알케닐옥시, 벤질, 벤질옥시, 아릴, 아릴옥시, 아릴티오, 헤트아릴, 헤트아릴옥시, 헤트아릴티오 또는 C(=NORa)-An-Rb 중 1개 내지 3개와 결합할 수 있음]; 아릴, 아릴카르보닐, 아릴술포닐, 헤트아릴, 헤트아릴카르보닐 또는 헤트아릴술포닐 [이 기들은 부분적으로 또는 완전히 할로겐화될 수 있거나, 또는 시아노, 니트로, 히드록실, 메르캅토, 아미노, 카르복실, 아미노카르보닐, 아미노티오카르보닐, 할로겐, C1-C6-알킬, C1-C6-할로알킬, C1-C6-알킬카르보닐, C1-C6-알킬술포닐, C1-C6-알킬술폭실, C3-C6-시클로알킬, C1-C6-알콕시, C1-C6-할로알콕시, C1-C6-알킬옥시카르보닐, C1-C6-알킬티오, C1-C6-알킬아미노, 디-C1-C6-알킬아미노, C1-C6-알킬아미노카르보닐, 디-C1-C6-알킬아미노카르보닐, C1-C6-알킬아미노티오카르보닐, 디-C1-C6-알킬아미노티오카르보닐, C2-C6-알케닐, C2-C6-알케닐옥시, 벤질, 벤질옥시, 아릴, 아릴옥시, 헤트아릴, 헤트아릴옥시 또는 C(=NORa)-An-Rb 중 1개 내지 3개와 결합할 수 있음]이고; 여기서, A는 산소, 황 또는 질소이고, 질소는 수소 또는 C1-C6-알킬과 결합하고 있고; n은 0 또는 1이고; Ra는 수소 또는 C1-C6-알킬이고, Rb는 수소 또는 C1-C6-알킬이되, 단 R1 및 R2가 메틸이고, R3이 에틸이고, R4가 메틸 또는 에틸이고, X가 NOCH3이고, Y가 NH 또는 O인 화합물 및 R3이 t-부틸인 화합물은 제외된다. 