HETEROCYCLENE DERIVATIVES AS PEST CONTROL AGENTSThe invention relates to novel compounds of formula (I), wherein X, R1, R2, R3 and n have the meanings indicated in the description, to the use thereof as acaricides and/or insecticides for controlling animal pests, and to methods and intermediate products for the production thereof.The compound of formula (i)wherein:r1for (c1-c6) alkyl, (c1-c6) cyanoalkyl, (c1-c6) hydroxy alkyl, (c1-c6) alkoxy-(c1-c6) alkyl, (c1-c6) halogenated alkyl, (c2-c6) alkenyl, (c2-c6) halogenated alkenyl, (c2-c6) alkynyl, (c2-c6) halo alkynyl or (c3-c8) naphthenic base,r2for hydrogen, (c1-c6) alkyl, (c1-c6) halogenated alkyl, (c1-c6) cyanoalkyl, (c1-c6) hydroxy alkyl, (c1-c6) alkane oxygroup-(c1-c6) alkyl, (c1-c6) halogenated alkoxy-(c1-c6) alkyl, (c2-c6) alkenyl, (c2-c6) alkenyloxy group-(c1-c6) alkyl, (c2-c6) haloalkenyloxy-(c1-c6) alkyl, (c2-c6) halogenated alkenyl, (c2-c6) cyano alkenyl, (c2-c6) alkynyl, (c2-c6) alkynyloxy group-(c1-c6) alkyl, (c2-c6) halogenated alkynyloxy group-(c1-c6) alkyl, (c2-c6) halo alkynyl, (c2-c6) cyanogen base alkynyl, (c3-c8) naphthenic base, (c3-c8) naphthenic base-(c3-c8) naphthenic base, (c1-c6) alkyl-(c3-c8) naphthenic base, halogenated (c3-c8) naphthenic base, cyano (c3-c8) naphthenic base, (c1-c6) alkylthio group-(c1-c6) alkyl, (c1-c6) halogenated alkylthio-(c1- c6) alkyl, (c1-c6) alkyl sulphinyl-(c1-c6) alkyl, (c1-c6) alkylsulfinyl-(c1-c6) alkyl, (c1- c6) alkyl sulphonyl-(c1-c6) alkyl, (c1-c6) halogenated alkyl sulfonyl-(c1-c6) alkyl, (c1-c6) alkyl-carbonyl-(c1- c6) alkyl, (c1-c6) halogenated alkyl carbonyl-(c1-c6) alkyl, (c1-c6) alkoxy carbonyl-(c1-c6) alkyl or (c1-c6) halogen for alkoxy carbonyl-(c1-c6) alkyl,r3for hydrogen, halogen, cyano, nitro, (c1-c6) alkyl, (c1-c6) halogenated alkyl, (c1-c6) alkoxy, (c1-c6) halogenated alkoxy, (c1-c6) alkylthio group, (c1-c6) halogenated alkylthio, (c1-c6) alkyl sulphinyl, (c1-c6) halogenated alkyl sulfenyl base, (c1-c6) alkyl sulphonyl, (c1-c6) halogenated alkyl sulfonyl, scn, (c1-c6) alkyl-carbonyl, (c1-c6) halogenated alkyl carbonyl base, (c1-c6) alkoxy carbonyl, (c1-c6) halo alkoxy carbonyl, amino carbonyl, (c1-c6) alkyl amino-carbonyl, two (c1- c6) alkyl amino-carbonyl, (c1-c6) haloalkylamino carbonyl, (c3-c8) cycloalkyl amino carbonyl, aminothiocarbonyl, (c1- c6) thio-alkyl amino-carbonyl, two (c1-c6) thio-alkyl amino-carbonyl, (c1-c6) haloalkylamino thiocarbonyl, (c3- c8) cycloalkyl amino thiocarbonyl, amino, (c1-c6) alkyl amino, (c1-c6) haloalkylamino, two (c1-c6) alkyl ammonia base, (c3-c8) cycloalkyl amino, (c1-c6) alkyl sulfonyl-amino, (c1-c6) alkyl-carbonyl-amino, (c1-c6) halogenated alkyl carbonyl base amino, (c1-c6) alkyl-carbonyl-(c1-c6) alkyl amino, (c1-c6) halogenated alkyl carbonyl-(c1-c6) alkyl amino, (c3- c8) cycloalkyl amino carbonyl, (c3-c8) naphthene base carbonyl-(c1-c6) alkyl amino, (c1-c6) alkylthiocarbonylamino, (c1- c6) halogenated alkylthio carbonylamino, (c1-c6) alkylthiocarbonyl-(c1-c6) alkyl amino, (c1-c6) halogenated alkylthio carbonyl- (c1-c6) alkyl amino, (c3-c8) cycloalkylthio carbonylamino, (c3-c8) cycloalkylthio carbonyl-(c1-c6) alkyl amino, (c2- c6) alkenyl, (c2-c6) halogenated alkenyl, (c2-c6) cyano alkenyl, (c3-c8) naphthenic base-(c2) alkenyl, (c2-c6) alkynyl, (c2- c6) halo alkynyl, (c3-c6) naphthenic base-(c2) alkynyl, (c3-c6) naphthenic base-(c1-c6) alkyl, (c1-c6) alkyl amino-carbonyl amino, two (c1-c6) alkyl amino-carbonyl-amino, (c3-c6) cycloalkyl amino carbonyl amino, (c1-c6) haloalkylamino carbonyl base amino, (c1-c6) alkyl amino-carbonyl-(c1-c6) alkyl amino, two (c1-c6) alkyl amino-carbonyl-(c1-c6) alkyl ammonia base, (c3-c6) cycloalkyl amino carbonyl-(c1-c6) alkyl amino or (c1-c6) haloalkylamino carbonyl-(c1-c6) alkyl ammonia base,or be aryl, heteroaryl, cyclopentenyl or cyclohexenyl group, it is respectively optionally monosubstituted by identical or different substituent group or it is polysubstituted, wherein (in the case where heteroaryl) can be optionally present at least one carbonyl, and possible in each case take it is as follows for base: cyano, carboxyl, halogen, nitro, acetyl group, hydroxyl, amino, scn, sf5, three (c1-c6) aikylsilyl groups, (c3-c8) naphthenic base, (c3-c8) naphthenic base-(c3-c8) naphthenic base, (c1-c6) alkyl-(c3-c8) naphthenic base, (c1-c6) alkyl halide base-(c3-c8) naphthenic base, halogenated (c3-c8) naphthenic base, cyano (c3-c8) naphthenic base, (c1-c6) alkyl, (c1-c6) alkyl halide base, (c1-c6) cyanoalkyl, (c1-c6) hydroxy alkyl, hydroxycarbonyl group-(c1-c6) alkoxy, (c1-c6) alkoxy carbonyl-(c1- c6) alkyl, (c1-c6) alkoxy-(c1-c6) alkyl, (c2-c6) alkenyl, (c2-c6) halogenated alkenyl, (c2-c6) cyano alkenyl, (c3-c8) naphthenic base-(c2) alkenyl, (c2-c6) alkynyl, (c2-c6) halo alkynyl, (c2-c6) cyano alkynyl, (c1-c6) alkoxy, (c1-c6) halogenated alkoxy, (c1-c6) cyano alkoxy, (c1-c6) alkoxy carbonyl-(c1-c6) alkoxy, (c1-c6) alcoxyl base-(c1-c6) alkoxy, (c1-c6) alkoximino, (c1-c6) halogenated alkoxy imino group, (c1-c6) alkylthio group, (c1- c6) halogenated alkylthio, (c1-c6) alkoxy-(c1-c6) alkylthio group, (c1-c6) alkylthio group-(c1-c6) alkyl, (c1-c6) alkyl asia sulfonyl, (c1-c6) alkylsulfinyl, (c1-c6) alkoxy-(c1-c6) alkyl sulphinyl, (c1-c6) alkyl asia sulphur acyl group-(c1-c6) alkyl, (c1-c6) alkyl sulphonyl, (c1-c6) halogenated alkyl sulfonyl, (c1-c6) a...
해충 방제제로서의 헤테로사이클 유도체본 발명은 화학식 (I)의 신규 화합물, 동물 해충을 방제하기 위한 살응애제 및/또는 살충제로서의 그의 용도, 및 그의 제조를 위한 방법 및 중간체에 관한 것이다:[이미지] 상기 식에서, X, R1, R2, R3 및 n은 각각 상기 정의된 바와 같다.화학식 (I)의 화합물:[이미지]상기 식에서,R1은 (C1-C6)알킬, (C1-C6)시아노알킬, (C1-C6)하이드록시알킬, (C1-C6)알콕시-(C1-C6)알킬, (C1-C6)할로알킬, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐 또는 (C3-C8)사이클로알킬이고,R2는 수소, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)하이드록시알킬, (C1-C6)알콕시-(C1-C6)알킬, (C1-C6)할로알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)알케닐옥시-(C1-C6)알킬, (C2-C6)할로알케닐옥시-(C1-C6)알킬, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C2-C6)알키닐, (C2-C6)알키닐옥시-(C1-C6)알킬, (C2-C6)할로알키닐옥시-(C1-C6)알킬, (C2-C6)할로알키닐, (C2-C6)시아노알키닐, (C3-C8)사이클로알킬, (C3-C8)사이클로알킬-(C3-C8)사이클로알킬, (C1-C6)알킬-(C3-C8)사이클로알킬, 할로(C3-C8)사이클로알킬, 시아노(C3-C8)사이클로알킬, (C1-C6)알킬티오-(C1-C6)알킬, (C1-C6)할로알킬티오-(C1-C6)알킬, (C1-C6)알킬설피닐-(C1-C6)알킬, (C1-C6)할로알킬설피닐-(C1-C6)알킬, (C1-C6)알킬설포닐-(C1-C6)알킬, (C1-C6)할로알킬설포닐-(C1-C6)알킬, (C1-C6)알킬카보닐-(C1-C6)알킬, (C1-C6)할로알킬카보닐-(C1-C6)알킬, (C1-C6)알콕시카보닐-(C1-C6)알킬 또는 (C1-C6)할로알콕시카보닐-(C1-C6)알킬이고, R3은 수소, 할로겐, 시아노, 니트로, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)알콕시, (C1-C6)할로알콕시, (C1-C6)알킬티오, (C1-C6)할로알킬티오, (C1-C6)알킬설피닐, (C1-C6)할로알킬설피닐, (C1-C6)알킬설포닐, (C1-C6)할로알킬설포닐, SCN, (C1-C6)알킬카보닐, (C1-C6)할로알킬카보닐, (C1-C6)알콕시카보닐, (C1-C6)할로알콕시카보닐, 아미노카보닐, (C1-C6)알킬아미노카보닐, 디(C1-C6)알킬아미노카보닐, (C1-C6)할로알킬아미노카보닐, (C3-C8)사이클로알킬아미노카보닐, 아미노티오카보닐, (C1-C6)알킬아미노티오카보닐, 디(C1-C6)알킬아미노티오카보닐, (C1-C6)할로알킬아미노티오카보닐, (C3-C8)사이클로알킬아미노티오카보닐, 아미노, (C1-C6)알킬아미노, (C1-C6)할로알킬아미노, 디(C1-C6)알킬아미노, (C3-C8)사이클로알킬아미노, (C1-C6)알킬설포닐아미노, (C1-C6)알킬카보닐아미노, (C1-C6)할로알킬카보닐아미노, (C1-C6)알킬카보닐-(C1-C6)알킬아미노, (C1-C6)할로알킬카보닐-(C1-C6)알킬아미노, (C3-C8)사이클로알킬카보닐아미노, (C3-C8)사이클로알킬카보닐-(C1-C6)알킬아미노, (C1-C6)알킬티오카보닐아미노, (C1-C6)할로알킬티오카보닐아미노, (C1-C6)알킬티오카보닐-(C1-C6)알킬아미노, (C1-C6)할로알킬티오카보닐-(C1-C6)알킬아미노, (C3-C8)사이클로알킬티오카보닐아미노, (C3-C8)사이클로알킬티오카보닐-(C1-C6)알킬아미노, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C3-C8)사이클로알킬-(C2)알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐, (C3-C6)사이클로알킬-(C2)알키닐, (C3-C6)사이클로알킬-(C1-C6)알킬, (C1-C6)알킬아미노카보닐아미노, 디(C1-C6)알킬아미노카보닐아미노, (C3-C6)사이클로알킬아미노카보닐아미노, (C1-C6)할로알킬아미노카보닐아미노, (C1-C6)알킬아미노카보닐-(C1-C6)알킬아미노, 디(C1-C6)알킬아미노카보닐-(C1-C6)알킬아미노, (C3-C6)사이클로알킬아미노카보닐-(C1-C6)알킬아미노 또는 (C1-C6)할로알킬아미노카보닐-(C1-C6)알킬아미노이거나, 또는각각 동일하거나 상이한 치환체에 의해 임의로 일- 또는 다치환된 아릴, 헤트아릴, 사이클로펜테닐 또는 사이클로헥세닐이고, 여기서 (헤트아릴의 경우) 적어도 하나의 카보닐 그룹이 임의로 존재할 수 있고 가능한 치환체는 각 경우 다음과 같고: 시아노, 카복실, 할로겐, 니트로, 아세틸, 하이드록실, 아미노, SCN, SF5, 트리(C1-C6)알킬실릴, (C3-C8)사이클로알킬, (C3-C8)사이클로알킬-(C3-C8)사이클로알킬, (C1-C6)알킬-(C3-C8)사이클로알킬, (C1-C6)할로알킬-(C3-C8)사이클로알킬, 할로(C3-C8)사이클로알킬, 시아노(C3-C8)사이클로알킬, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)하이드록시알킬, 하이드록시카보닐-(C1-C6)알콕시, (C1-C6)알콕시카보닐-(C1-C6)알킬, (C1-C6)알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C3-C8)사이클로알킬-(C2)알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐, (C2-C6)시아노알키닐, (C1-C6)알콕시, (C1-C6)할로알콕시, (C1-C6)시아노알콕시, (C1-C6)알콕시카보닐-(C1-C6)알콕시, (C1-C6)알콕시-(C1-C6)알콕시, (C1-C6)알콕시이미노, (C1-C6)할로알콕시이미노, (C1-C6)알킬티오, (C1-C6)할로알킬티오, (C1-C6)알콕시-(C1-C6)알킬티오, (C1-C6)알킬티오-(C1-C6)알킬, (C1-C6)알킬설피닐, (C1-C6)할로알킬설피닐, (C1-C6)알콕시-(C1-C6)알킬설피닐, (C1-C6)알킬설피닐-(C1-C6)알킬, (C1-C6)알킬설포닐, (C1-C6)할로알킬설포닐, (C1-C6)알콕시-(C1-C6)알킬설포닐, (C1-C6)알킬설포닐-(C1-C6)알킬, (C1-C6)알킬설포닐옥시, (C1-C6)할로알킬설포닐옥시, (C1-C6)알킬카보닐, (C1-C6)할로알킬카보닐, (C1-C6)알킬카보닐옥시, (C1-C6)알콕시카보닐, (C1-C6)할로알콕시카보닐, 아미노카보닐, (C1-C6)알킬아미노카보닐, 디(C1-C6)알킬아미노카보닐, (C1-C6)할로알킬아미노카보닐, (C2-C6)알케닐아미노카보닐, 디(C2-C6)알케닐아미노카보닐, (C3-C8)사이클로알킬아미노카보닐, (C1-C6)알킬설포닐아미노, (C1-C6)알킬아미노, 디(C1-C6)알킬아미노, (C1-C6)할로알킬아미노, (C3-C8)사이클로알킬아미노, 아미노설포닐, (C1-C6)알킬아미노설포닐, 디(C1-C6)알킬아미노설포닐, (C1-C6)알킬설폭스이미노, 아미노티오카보닐, (C1-C6)알킬아미노티오카보닐, 디(C1-C6)알킬아미노티오카보닐, (C1-C6)할로알킬아미노티오카보닐, (C3-C8)사이클로알킬아미노티오카보닐, (C1-C6)알킬카보닐아미노, (C1-C6)할로알킬카보닐아미노, (C1-C6)알킬카보닐-(C1-C6)알킬아미노, (C1-C6)할로알킬카보닐-(C1-C6)알킬아미노, (C3-C8)사이클로알킬카보닐아미노, (C3-C8)사이클로알킬카보닐-(C1-C6)알킬아미노, (C1-C6)알킬티오카보닐아미노, (C1-C6)할로알킬티오카보닐아미노, (C1-C6)알킬티오카보닐-(C1-C6)알킬아미노, (C1-C6)할로알킬티오카보닐-(C1-C6)알킬아미노, (C3-C8)사이클로알킬티오카보닐아미노, (C3-C8)사이클로알킬티오카보닐-(C1-C6)알킬아미노, 헤트아릴, 옥소헤트아릴, 할로헤트아릴, 할로옥소헤트아릴, 시아노헤트아릴, 시아노옥소헤트아릴, (C1-C6)할로알킬헤트아릴 또는 (C1-C6)할로알킬옥소헤트아릴,X는 Q1 내지 Q12 그룹으로부터의 헤테로방향족 9-원 또는 12-원 융합 비사이클릭 또는 트리사이클릭 환 시스템이고:[이미지]R4는 수소, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)하이드록시알킬, (C1-C6)알콕시-(C1-C6)알킬, (C1-C6)할로알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)알케닐옥시-(C1-C6)알킬, (C2-C6)할로알케닐옥시-(C1-C6)알킬, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐 또는 (C3-C8)사이클로알킬이고, R5, R6은 독립적으로 수소, 시아노, 할로겐, (C1-C6)알킬, (C1-C6)할로알킬, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐, (C3-C8)사이클로알킬, (C3-C8)사이클로알킬-(C3-C8)사이클로알킬, (C1-C6)알킬-(C3-C8)사이클로알킬, (C1-C6)할로알킬-(C3-C8)사이클로알킬, 시아노-(C3-C8)사이클로알킬, 할로(C3-C8)사이클로알킬, (C1-C6)알콕시, (C1-C6)할로알콕시, (C1-C6)알콕시이미노, (C1-C6)할로알콕시이미노 (C1-C6)알킬티오, (C1-C6)할로알킬티오, (C1-C6)알킬설피닐, (C1-C6)할로알킬설피닐, (C1-C6)알킬설포닐, (C1-C6)할로알킬설포닐, (C1-C6)알킬설포닐옥시, (C1-C6)할로알킬설포닐옥시, (C1-C6)알킬카보닐, (C1-C6)할로알킬카보닐, 아미노카보닐, (C1-C6)알킬아미노카보닐, 디(C1-C6)알킬아미노카보닐, (C1-C6)알킬설포닐아미노, (C1-C6)알킬아미노, 디(C1-C6)알킬아미노, 아미노설포닐, (C1-C6)알킬아미노설포닐 또는 디(C1-C6)알킬아미노설포닐이고,n은 0, 1 또는 2이다.