NOVEL 5-SUBSTITUTED IMIDAZOLE DERIVATIVESThe present invention relates to novel 5-substituted imidazolylmethyl derivatives, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials and as plant growth regulators.The imdazole derivatives and its salt or n- oxides of formula (i)whereinr1hydrogen is represented, each the optionally c of side chain1-c8- alkyl, c1-c8- haloalkyl, c2-c7- alkenyl, c2-c7- haloalkenyl group, c2-c8- alkynyl, c2-c8- halo alkynyl, optional halogen-, cyano group-, c1-c4- alkyl-, c1-c4- haloalkyl-, c1-c4- alcoxyl base-, c1-c4- halogenated alkoxy-, c1-c4- alkylthio group-or c1-c4the substituted c of-halogenated alkylthio-3-c7- cycloalkyl, optional halogen element-, cyano group-, c1-c4- alkyl-, c1-c4- haloalkyl-, c1-c4- alkoxy-, c1-c4- halogenated alkoxy-, c1-c4- alkane sulphur base-or c1-c4the substituted bicyclic alkyl of-halogenated alkylthio-, optional halogen-, cyano group-, c1-c4- alkyl-, c1-c4- alkyl halide base-, c1-c4- alkoxy-, c1-c4- halogenated alkoxy-, c1-c4- alkylthio group-or c1-c4the substituted c of-halogenated alkylthio-3-c8- cycloalkyl-alkyl, optional halogen-, cyano group-, c1-c4- alkyl-, c1-c4- haloalkyl-, c1-c4- alkoxy-, c1-c4- halo alkoxy-, c1-c4- alkylthio group-or c1-c4the substituted c of-halogenated alkylthio-3-c7- halogenated cycloalkyl-c1-c4- alkyl, optional halogen element-, cyano group-, c1-c4- alkyl-, c1-c4- haloalkyl-, c1-c4- alkoxy-, c1-c4- halogenated alkoxy-, c1-c4- alkane sulphur base-or c1-c4the substituted c of-halogenated alkylthio-3-c7- halogenated cycloalkyl-c1-c4- haloalkyl, optional halogen-, cyano group-, c1- c4- alkyl-, c1-c4- haloalkyl-, c1-c4- alkoxy-, c1-c4- halogenated alkoxy-, c1-c4- alkylthio group-or c1-c4- halogen for the c of alkylthio group-substituted3-c7- cycloalkyl-c1-c4- haloalkyl, optional halogen-, cyano group-, c1-c4- alkyl-, c1-c4- halogen substituted alkyl-, c1-c4- alkoxy-, c1-c4- halogenated alkoxy-, c1-c4- alkylthio group-or c1-c4- halogenated alkylthio-is substituted c3-c7- cycloalkyl-c3-c7- cycloalkyl, optional halogen-, cyano group-, c1-c4- alkyl-, c1-c4- haloalkyl-, c1-c4- alcoxyl base-, c1-c4- halogenated alkoxy-, c1-c4- alkylthio group-or c1-c4the substituted c of-halogenated alkylthio-3-c7- cycloalkenyl group, optional halogen element-, cyano group-, c1-c4- alkyl-, c1-c4- haloalkyl-, c1-c4- alkoxy-, c1-c4- halogenated alkoxy-, c1-c4- alkane sulphur base-or c1-c4three substituted (c of-halogenated alkylthio-1-c8- alkyl) silicyl-c1-c4- alkyl, optional halogen-, cyano group-, c1-c4- alkyl-, c1-c4- haloalkyl-, c1-c4- alkoxy-, c1-c4- halogenated alkoxy-, c1-c4- alkylthio group-or c1-c4- three (c of halogenated alkylthio-substituted1-c8- alkyl) silicyl-c3-c7- cycloalkyl；r2represent h, c1-c8- alkyl ,-si (r3a)(r3b)(r3c)、-p(o)(oh)2、-ch2-o-p(o)(oh)2、–c(o)-c1-c8- alkyl ,-c (o)-c3-c7- cycloalkyl ,-c (o) nh-c1-c8- the alkyl ,-c of-c (o) n- bis-1-c8- alkyl ,-c (o) o-c1-c8- alkane base, wherein-c (o)-c1-c8- alkyl ,-c (o)-c3-c7- cycloalkyl ,-c (o) nh-c1-c8- the alkyl ,-c of-c (o) n- bis-1-c8- alkane base or-c (o) o-c1-c8- alkyl can with it is unsubstituted or by one or more be selected from halogen or c1-c8the group of-alkoxy substitution；whereinr3a、r3b、r3cphenyl or c are represented independently of one another1-c8- alkyl；r3represent halogen, hydroxyl, cyano group, isocyano group, nitro, amino, sulfanyl, five fluoro- λ6- sulfanyl, carboxaldehyde radicals, hydroxyl carbonyl base, c1-c8- alkyl, c1-c8- haloalkyl, c1-c8- cyanoalkyl, c1-c8- alkoxy, c1-c8- halogenated alkoxy, three (c1- c8- alkyl) silicyl, three (c1-c8- alkyl) silicyl-c1-c8- alkyl, c3-c7- cycloalkyl, c3-c7- halo cycloalkanes base, c3-c7- cycloalkenyl group, c3-c7- halo cycloalkenyl group, c4-c10- cycloalkyl-alkyl, c4-c10- halogenated cycloalkyl alkyl, c6-c12- cycloalkyl ring alkyl, c1-c8- alkyl-c3-c7- cycloalkyl, c1-c8- alkoxy -c3-c7- cycloalkyl, three (c1-c8- alkyl) first silylation-c3-c7- cycloalkyl, c2-c8- alkenyl, c2-c8- alkynyl, c2-c8- alkenyloxy group, c2-c8- halo alkenyloxy group, c3-c8- alkynes epoxide, c3-c8- halo alkynyloxy group, c1-c8- alkyl amino, c1-c8- haloalkylamino, c1-c8- cyano alkoxy, c4-c8- cycloalkyl alkoxy, c3-c6- cycloalkyloxy, c1-c8- alkylthio group, c1-c8- halogenated alkylthio, c1-c8- alkyl-carbonyl, c1-c8- halogenated alkyl carbonyl, aryl carbonyl, aryl-c1-c6- alkyl-carbonyl, c3-c8- naphthene base carbonyl, c3-c8- halogenated cycloalkyl carbonyl base, c1-c8- alkyl-carbamoyl, two-c1-c8- alkyl-carbamoyl, n-c1-c8- alkoxycarbamoyl, c1-c8- alkoxycarbamoyl, n-c1-c8- alkyl-c1-c8- alkoxycarbamoyl, aminothiocarbonyl, c1-c8- alkoxy carbonyl, c1-c8- halo alkoxy carbonyl, c3-c8- cyclo alkoxy carbonyl, c2-c8- alkoxyalkylcarbonyl radicals, c2-c8- haloalkoxy base alkyl-carbonyl, c3-c10- cycloalkoxyalkyl carbonyl, c1-c8- alkyl amino-carbonyl, two-c1-c8- alkyl amino-carbonyl, c3- c8- cycloalkyl amino carbonyl, c1-c8- alkyl carbonyl oxy, c1-c8- haloalkyl carbonyloxy group, c3-c8- cycloalkyl carbonyloxy group, c1- c8- alkyl-carbonyl-amino, c1-c8- haloalkylcarbonylamino, c1-c8- alkyl amino carbonyl oxy, two-c1-c8- alkyl amino carbonyl epoxide, c1-c8- alkoxycarbonyloxy, c1-c8- alkyl sulphinyl, c1-c8- alkylsulfinyl, c1-c8- alkyl sulfonyl, c1-c8- halogenated alkyl sulfonyl,...
신규 5-치환된 이미다졸 유도체 본 발명은 신규 5-치환된 이미다졸릴메틸 유도체, 그의 제조방법, 이들 화합물을 포함하는 조성물, 및 특히 작물 보호 및 재료 보호에서 유해 미생물을 구제하기 위한 생물학적 활성 화합물 및 식물 성장 조절제로서의 그의 용도에 관한 것이다.화학식 (I)의 이미다졸 유도체 및 그의 염 또는 N-옥사이드:[이미지]상기 식에서,R1은 수소, 각 경우 임의로 분지상 C1-C8-알킬, C1-C8-할로알킬, C2-C7-알케닐, C2-C7-할로알케닐, C2-C8-알키닐, C2-C8-할로알키닐, 임의로 할로겐-, 시아노-, C1-C4-알킬-, C1-C4-할로알킬-, C1-C4-알콕시-, C1-C4-할로알콕시-, C1-C4-알킬티오- 또는 C1-C4-할로알킬티오-치환된 C3-C7-사이클로알킬, 임의로 할로겐-, 시아노-, C1-C4-알킬-, C1-C4-할로알킬-, C1-C4-알콕시-, C1-C4-할로알콕시-, C1-C4-알킬티오- 또는 C1-C4-할로알킬티오-치환된 비사이클로알킬, 임의로 할로겐-, 시아노-, C1-C4-알킬-, C1-C4-할로알킬-, C1-C4-알콕시-, C1-C4-할로알콕시-, C1-C4-알킬티오- 또는 C1-C4-할로알킬티오-치환된 C3-C8-사이클로알킬알킬; 임의로 할로겐-, 시아노-, C1-C4-알킬-, C1-C4-할로알킬-, C1-C4-알콕시-, C1-C4-할로알콕시-, C1-C4-알킬티오- 또는 C1-C4-할로알킬티오-치환된 C3-C7-할로사이클로알킬-C1-C4-알킬; 임의로 할로겐-, 시아노-, C1-C4-알킬-, C1-C4-할로알킬-, C1-C4-알콕시-, C1-C4-할로알콕시-, C1-C4-알킬티오- 또는 C1-C4-할로알킬티오-치환된 C3-C7-할로사이클로알킬-C1-C4-할로알킬; 임의로 할로겐-, 시아노-, C1-C4-알킬-, C1-C4-할로알킬-, C1-C4-알콕시-, C1-C4-할로알콕시-, C1-C4-알킬티오- 또는 C1-C4-할로알킬티오-치환된 C3-C7-사이클로알킬-C1-C4-할로알킬; 임의로 할로겐-, 시아노-, C1-C4-알킬-, C1-C4-할로알킬-, C1-C4-알콕시-, C1-C4-할로알콕시-, C1-C4-알킬티오- 또는 C1-C4-할로알킬티오-치환된 C3-C7-사이클로알킬- C3-C7-사이클로알킬; 임의로 할로겐-, 시아노-, C1-C4-알킬-, C1-C4-할로알킬-, C1-C4-알콕시-, C1-C4-할로알콕시-, C1-C4-알킬티오- 또는 C1-C4-할로알킬티오-치환된 C3-C7-사이클로알케닐, 임의로 할로겐-, 시아노-, C1-C4-알킬-, C1-C4-할로알킬-, C1-C4-알콕시-, C1-C4-할로알콕시-, C1-C4-알킬티오- 또는 C1-C4-할로알킬티오-치환된 트리(C1-C8-알킬)실릴-C1-C4-알킬; 임의로 할로겐-, 시아노-, C1-C4-알킬-, C1-C4-할로알킬-, C1-C4-알콕시-, C1-C4-할로알콕시-, C1-C4-알킬티오- 또는 C1-C4-할로알킬티오-치환된 트리(C1-C8-알킬)실릴-C3-C7-사이클로알킬을 나타내고;R2는 H, C1-C8-알킬, -Si(R3a)( R3b)( R3c)-, -P(O)(OH)2, -CH2-O-P(O)(OH)2, -C(O)-C1-C8-알킬, -C(O)-C3-C7-사이클로알킬, -C(O)NH-C1-C8-알킬; -C(O)N-디-C1-C8-알킬; -C(O)O-C1-C8-알킬을 나타내고; 여기서 -C(O)-C1-C8-알킬, -C(O)-C3-C7-사이클로알킬, -C(O)NH-C1-C8-알킬; -C(O)N-디-C1-C8-알킬 또는 -C(O)O-C1-C8-알킬은 비치환되거나, 또는 할로겐 또는 C1-C8-알콕시 중에서 선택된 하나 이상의 그룹(들)에 의해 치환될 수 있고; 여기서, R3a, R3b, R3c는 서로 독립적으로 페닐 또는 C1-C8-알킬을 나타내고;R3은 할로겐; 하이드록실; 시아노; 이소시아노; 니트로; 아미노; 설파닐; 펜타플루오로-λ6-설파닐; 카복스알데히드, 하이드록시카보닐, C1-C8-알킬; C1-C8-할로알킬; C1-C8-시아노알킬; C1-C8-알킬옥시; C1-C8-할로겐알킬옥시; 트리(C1-C8-알킬)실릴; 트리(C1-C8-알킬)실릴-C1-C8-알킬; C3-C7-사이클로알킬; C3-C7-할로겐사이클로알킬; C3-C7-사이클로알케닐; C3-C7-할로겐사이클로알케닐; C4-C10-사이클로알킬알킬; C4-C10-할로사이클로알킬알킬; C6-C12-사이클로알킬사이클로알킬; C1-C8-알킬-C3-C7-사이클로알킬; C1-C8-알콕시-C3-C7-사이클로알킬; 트리(C1-C8-알킬)실릴-C3-C7-사이클로알킬; C2-C8-알케닐; C2-C8-알키닐; C2-C8-알케닐옥시; C2-C8-할로겐알케닐옥시; C3-C8-알키닐옥시; C3-C8-할로게노알키닐옥시; C1-C8-알킬아미노; C1-C8-할로겐알킬아미노; C1-C8-시아노알콕시; C4-C8-사이클로알킬알콕시; C3-C6-사이클로알콕시; C1-C8-알킬설파닐; C1-C8-할로게노알킬설파닐; C1-C8-알킬카보닐; C1-C8-할로게노알킬카보닐; 아릴카보닐; 아릴-C1-C6-알킬카보닐; C3-C8-사이클로알킬카보닐; C3-C8-할로게노사이클로알킬카보닐; C1-C8-알킬카바모일; 디-C1-C8-알킬카바모일; N-C1-C8-알킬옥시카바모일; C1-C8-알콕시카바모일; N-C1-C8-알킬-C1-C8-알콕시카바모일; 아미노티오카보닐; C1-C8-알콕시카보닐; C1-C8-할로게노알콕시카보닐; C3-C8-사이클로알콕시카보닐; C2-C8-알콕시알킬카보닐; C2-C8-할로게노알콕시알킬카보닐; C3-C10-사이클로알콕시알킬카보닐; C1-C8-알킬아미노카보닐; 디-C1-C8-알킬아미노카보닐; C3-C8-사이클로알킬아미노카보닐; C1-C8-알킬카보닐옥시; C1-C8-할로게노알킬카보닐옥시; C3-C8-사이클로알킬카보닐옥시; C1-C8-알킬카보닐아미노; C1-C8-할로게노알킬카보닐아미노; C1-C8-알킬아미노카보닐옥시; 디-C1-C8-알킬아미노카보닐옥시; C1-C8-알킬옥시카보닐옥시; C1-C8-알킬설피닐; C1-C8-할로게노알킬설피닐; C1-C8-알킬설포닐; C1-C8-할로게노알킬설포닐; C1-C8-알킬설포닐옥시; C1-C8-할로게노알킬설포닐옥시; C1-C8-알킬아미노설파모일; 디-C1-C8-알킬아미노설파모일; (C1-C8-알콕시이미노)-C1-C8-알킬; (C3-C7-사이클로알콕시이미노)-C1-C8-알킬; 하이드록시이미노-C1-C8-알킬; (C1-C8-알콕시이미노)-C3-C7-사이클로알킬; 하이드록시이미노-C3-C7-사이클로알킬; (C1-C8-알킬이미노)-옥시; (C1-C8-알킬이미노)-옥시-C1-C8-알킬; (C3-C7-사이클로알킬이미노)-옥시-C1-C8-알킬; (C1-C6-알킬이미노)-옥시-C3-C7-사이클로알킬; (C1-C8-알케닐옥시이미노)-C1-C8-알킬; (C1-C8-알키닐옥시이미노)-C1-C8-알킬; (벤질옥시이미노)-C1-C8-알킬; C1-C8-알콕시알킬; C1-C8-알킬티오알킬; C1-C8-알콕시알콕시알킬; C1-C8-할로게노알콕시알킬; 벤질; 페닐; 5-원 헤테로아릴; 6-원 헤테로아릴; 벤질옥시; 페닐옥시; 벤질설파닐; 벤질아미노; 페닐설파닐; 또는 페닐아미노를 나타내고; 여기서 벤질, 페닐, 5-원 헤테로아릴, 6-원 헤테로아릴, 벤질옥시 또는 페닐옥시는 할로겐; 하이드록실; 시아노; 이소시아노; 아미노; 설파닐; 펜타플루오로-λ6-설파닐; 카복스알데히드, 하이드록시카보닐, C1-C8-알킬; C1-C8-할로알킬; C1-C8-시아노알킬; C1-C8-알킬옥시; C1-C8-할로겐알킬옥시; 트리(C1-C8-알킬)실릴; 트리(C1-C8-알킬)실릴-C1-C8-알킬; C3-C7-사이클로알킬; C3-C7-할로겐사이클로알킬; C3-C7-사이클로알케닐; C3-C7-할로겐사이클로알케닐; C4-C10-사이클로알킬알킬; C4-C10-할로사이클로알킬알킬; C6-C12-사이클로알킬사이클로알킬; C1-C8-알킬-C3-C7-사이클로알킬; C1-C8-알콕시-C3-C7-사이클로알킬; 트리(C1-C8-알킬)실릴-C3-C7-사이클로알킬; C2-C8-알케닐; C2-C8-알키닐; C2-C8-알케닐옥시; C2-C8-할로겐알케닐옥시; C3-C8-알키닐옥시; C3-C8-할로게노알키닐옥시; C1-C8-알킬아미노; C1-C8-할로겐알킬아미노; C1-C8-시아노알콕시; C4-C8-사이클로알킬알콕시; C3-C6-사이클로알콕시; C1-C8-알킬설파닐; C1-C8-할로게노알킬설파닐; C1-C8-알킬카보닐; C1-C8-할로게노알킬카보닐; 아릴카보닐; 아릴-C1-C6-알킬카보닐; C3-C8-사이클로알킬카보닐; C3-C8-할로게노사이클로알킬카보닐; C1-C8-알킬카바모일; 디-C1-C8-알킬카바모일; N-C1-C8-알킬옥시카바모일; C1-C8-알콕시카바모일; N-C1-C8-알킬-C1-C8-알콕시카바모일; 아미노티오카보닐; C1-C8-알콕시카보닐; C1-C8-할로게노알콕시카보닐; C3-C8-사이클로알콕시카보닐; C2-C8-알콕시알킬카보닐; C2-C8-할로게노알콕시알킬카보닐; C3-C10-사이클로알콕시알킬카보닐; C1-C8-알킬아미노카보닐; 디-C1-C8-알킬아미노카보닐; C3-C8-사이클로알킬아미노카보닐; C1-C8-알킬카보닐옥시; C1-C8-할로게노알킬카보닐옥시; C3-C8-사이클로알킬카보닐옥시; C1-C8-알킬카보닐아미노; C1-C8-할로게노알킬카보닐아미노; C1-C8-알킬아미노카보닐옥시; 디-C1-C8-알킬아미노카보닐옥시; C1-C8-알킬옥시카보닐옥시; C1-C8-알킬설피닐; C1-C8-할로게노알킬설피닐; C1-C8-알킬설포닐; C1-C8-할로게노알킬설포닐; C1-C8-알킬설포닐옥시; C1-C8-할로게노알킬설포닐옥시; C1-C8-알킬아미노설파모일; 디-C1-C8-알킬아미노설파모일; (C1-C8-알콕시이미노)-C1-C8-알킬; (C3-C7-사이클로알콕시이미노)-C1-C8-알킬; 하이드록시이미노-C1-C8-알킬; (C1-C8-알콕시이미노)-C3-C7-사이클로알킬; 하이드록시이미노-C3-C7-사이클로알킬; (C1-C8-알킬이미노)-옥시; (C1-C8-알킬이미노)-옥시-C1-C8-알킬; (C3-C7-사이클로알킬이미노)-옥시-C1-C8-알킬; (C1-C6-알킬이미노)-옥시-C3-C7-사이클로알킬; (C1-C8-알케닐옥시이미노)-C1-C8-알킬; (C1-C8-알키닐옥시이미노)-C1-C8-알킬; (벤질옥시이미노)-C1-C8-알킬; C1-C8-알콕시알킬; C1-C8-알킬티오알킬; C1-C8-알콕시알콕시알킬; C1-C8-할로게노알콕시알킬; 벤질; 페닐; 5-원 헤테로아릴; 6-원 헤테로아릴; 벤질옥시; 페닐옥시; 벤질설파닐; 벤질아미노; 페닐설파닐; ...