Fungicide hydroximoyl-tetrazole derivativesThe present invention relates to hydroximoyl-tetrazole derivatives of formula (I) wherein T represent a tetrazolyl substituents, A represents a carbo- or heterocycle, L and L represent various linking groups and Q represents a carbocycle, their process of preparation, their use as fungicide active agents, particularly in the form of fungicide compositions, and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions.The compound of a general formula (i) and salt thereof, n-oxide, metal complex and metalloid complex compound:in the formulat represents to replace or unsubstituted tetrazole radical;l 1represent direct key or be selected from down the bilvalent radical of organizing: -(cr 1r 2) n- -(cr 1r 2) m-c(＝o)-(cr 1r 2) p- -(cr 1r 2) m-(cr 1＝cr 2)-(cr 1r 2) p- -(cr 1r 2) m-c(＝o)-o-(cr 1r 2) p-(cr 1r 2) m-c≡c-(cr 1r 2) p- -(cr 1r 2) m-o-c(＝o)-(cr 1r 2) p- -(cr 1r 2) m-o-(cr 1r 2) p- -(cr 1r 2) m-c(＝o)-nh-(cr 1r 2) p- -(cr 1r 2) m-nh-(cr 1r 2) p- -(cr 1r 2) m-nh-c(＝o)-(cr 1r 2) p- whereinn represents 1,2,3 or 4;m and p represent 0,1,2 or 3 independently;l 2represent direct key or be selected from down the bilvalent radical of organizing: -(cr 3r 4) q- -(cr 3r 4) a-c(＝o)-(cr 3r 4) b- -(cr 3r 4) a-(cr 3＝cr 4)-(cr 3r 4) b- -(cr 3r 4) a-c(＝o)-o-(cr 3r 4) b-(cr 3r 4) a-c≡c-(cr 3r 4) b- -(cr 3r 4) a-o-c(＝o)-(cr 3r 4) b- -(cr 3r 4) a-o-(cr 3r 4) b- -(cr 3r 4) a-c(＝o)-nh-(cr 3r 4) b- -(cr 3r 4) a-nh-(cr 3r 4) b- -(cr 3r 4) a-nh-c(＝o)-(cr 3r 4) b- whereinq represents 1,2,3 or 4;a and b represent 0,1,2 or 3 independently;a is selected from a 1-a 116whereinz 1, z 2, z 3, z 4, z 5, z 6, z 7, z 8and z 9be independently selected from down group: hydrogen, halogen, [c 1-c 8]-alkyl, [c 1-c 8]-haloalkyl, [c 2-c 8]-thiazolinyl, [c 2-c 8]-haloalkenyl group, [c 2-c 8]-alkynyl, [c 2-c 8]-halo alkynyl, [c 3-c 6]-cycloalkyl, [c 3-c 6]-halogenated cycloalkyl, aryl, aryl-[c 1-c 8]-alkyl, hydroxyl-[c 1-c 8]-alkyl, [c 1-c 8]-alkoxyl-[c 1-c 8]-alkyl ,-c (=o) r 5,-c (=o) or 5,-c (=o) nr 5r 6,-c (=o) sr 5,-c (=s) r 5,-c (=s) or 5,-c (=s) nr 5r 6,-c (=s) sr 5,-cr 5=nr 6,-cr 5=nor 6,-cr 5=n-nr 6r 7,-or 5,-osir 5r 6r 7,-oc (=o) r 5,-oc (=o) or 5,-oc (=o) nr 5r 6,-oc (=s) nr 5r 6,-nr 5r 6,-n (r 5) c (=o) r 6,-n (r 5) c (=o) or 6,-n (r 5) c (=o) nr 6r 7,-n (r 5) c (=s) r 6,-n (r 5) c (=s) nr 6r 7,-n=cr 5r 6,-n=c-nr 5r 6,-n (r 5) c (=nr 6) nr 7r 8,-n (r 5) or 6,-n (r 5) nr 6r 7,-n=nr 5,-n (r 5) s (=o) r 6,-n (r 5) s (=o) 2r 6,-n (r 5) s (=o) 2or 6,-n (r 5) s (=o) or 6,-n (r 5) s (=o) nr 6r 7,-n (r 5) s (=o) 2nr 6r 7,-sr 5,-s (=o) r 5,-s (=o) 2r 5,-s (=o) or 5,-s (=o) nr 5r 6,-s (=o) 2or 5,-s (=o) 2nr 5r 6, nitro, nitroso, azido, cyano group ,-sf 5with-sir 5r 6r 7k 1and k 2be independently selected from down group: hydrogen, [c 1-c 8]-alkyl, [c 1-c 8]-haloalkyl, [c 2-c 8]-thiazolinyl, [c 2-c 8]-haloalkenyl group, [c 2-c 8]-alkynyl, [c 2-c 8]-halo alkynyl, [c 3-c 6]-cycloalkyl, [c 3-c 6]-halogenated cycloalkyl, aryl, aryl-[c 1-c 8]-alkyl, hydroxyl-[c 1-c 8]-alkyl, [c 1-c 8]-alkoxyl-[c 1-c 8]-alkyl ,-c (=o) r 9,-c (=o) or 9,-c (=o) nr 9r 10,-c (=o) sr 9,-c (=s) r 9,-c (=s) or 9,-c (=s) nr 9r 10,-c (=s) sr 9,-cr 9=nr 10,-cr 9=nor 10,-cr 9=n-nr 10r 11,-s (=o) r 9,-s (=o) 2r 9,-s (=o) or 9,-s (=o) nr 9r 10,-s (=o) 2or 9,-s (=o) 2nr 9r 10with-sir 9r 10r 11g 1and g 2be independently selected from down group: oxygen, sulphur, nr 12, n-or 12and n-nr 12r 13q is selected from q 1-q 12whereinx 1-x 11be independently selected from down group: hydrogen, halogen, [c 1-c 8]-alkyl, [c 1-c 8]-haloalkyl, [c 2-c 8]-thiazolinyl, [c 2-c 8]-haloalkenyl group, [c 2-c 8]-alkynyl, [c 2-c 8]-halo alkynyl, [c 3-c 6]-cycloalkyl, [c 3-c 6]-halogenated cycloalkyl, aryl, aryl-[c 1-c 8]-alkyl, hydroxyl-[c 1-c 8]-alkyl, [c 1-c 8]-alkoxyl-[c 1-c 8]-alkyl ,-c (=o) r 14,-c (=o) or 14,-c (=o) nr 14r 15,-c (=o) sr 14,-c (=s) r 14,-c (=s) or 14,-c (=s) nr 14r 15,-c (=s) sr 14,-cr 14=nr 15,-cr 14=nor 15,-cr 14=n-nr 15r 16,-or 14,-osir 14r 15r 16,-oc (=o) r 14,-oc (=o) or 14,-oc (=o) nr 14r 15,-oc (=s) nr 14r 14,-nr 14r 15,-n (r 14) c (=o) r 15,-n (r 14) c (=o) or 15,-n (r 14) c (=o) nr 15r 16,-n (r 14) c (=s) r 15,-n (r 14) c (=s) nr 15r 16,-n=cr 14r 15,-n=c-nr 14r 15,-n (r 14) c (=nr 15) nr 16r 17,-n (r 14) or 15,-n (r 14) nr 15r 16,-n=nr 14,-n (r 14) s (=o) r 15,-n (r 14) s (=o) 2r 15,-n (r 14) s (=o) 2or 15,-n (r 14) s (=o) or 15,-n (r 14) s (=o) nr 15r 16,-n (r 14) s (=o) 2nr 15r 16,-sr 14,-s (=o) r 14,-s (=o) 2r 14,-s (=o) or 14,-s (=o) nr 14r 15,-s (=o) 2or 14,-s (=o) 2nr 14r 15, nitro, nitroso, azido, cyano group ,-sf 5with-sir 14r 15r 16r 1, r 2, r 3and r 4be independently selected from down group: hydrogen, halogen, [c 1-c 4]-alkyl, [c 1-c 4]-haloalkyl, [c 2-c 4]-thiazolinyl, [c 2-c 4]-haloalkenyl group, [c 2-c 4]-alkynyl, [c 2-c 4]-halo alkynyl, [c 3-c 5]-cycloalkyl, [c 3-c 5]-halogenated cycloalkyl, [c 1-c 4]-alkoxyl, [c 1-c 4]-alkoxyl-[c 1-c 4]-alkyl, [c 1-c 4]-alkoxyl-[c 1-c 4]-alkoxyl, [c 1-c 4]-halogenated alkoxy, [c 1-c 4]-halogenated alkoxy-[c 1-c 4]-alkyl and cyano group; r 5-r 17be independently selected from down group: hydrogen, [c 1-c 8]-alkyl, [c 1-c 8]-haloalkyl, [c 2-c 8]-thiazolinyl, [c 2-c 8]-haloalkenyl group, [c 2-c 8]-alkynyl, [c 2-c 8]-halo alkynyl, [c 3-c 6]-cycloalkyl, [c 3-c 6]-halogenated cycloalkyl, aryl and aryl-[c 1-c 8]-alkyl, prerequisite is if a is selected from a 2, a 5, a 11, a 16, a 17, a 18, a 23, a 24, a 29, a 30, a 34or a 36, l 1expression ch 2an...
살진균제 히드록시모일-테트라졸 유도체본 발명은 하기 화학식 (I) 의 히드록시모일-테트라졸 유도체, 이의 제조 방법, 이의 살진균 활성제로서의 용도, 특히 살진균 조성물 형태로의 용도, 및 이들 화합물 또는 조성물을 이용한 특히 식물의 식물병원성 진균류의 방제 방법에 관한 것이다:  여기서, T 는 테트라졸릴 치환기를 나타내고, A 는 카르보- 또는 헤테로사이클을 나타내고, L1 및 L2 은 각종 연결기를 나타내고, Q 는 헤테로사이클을 나타냄. 하기 화학식 (I) 의 화합물 및 이의 염, N-옥시드, 금속성 착물 및 반금속성 착물: [이미지] 여기서, ?T 는 치환 또는 비치환된 테트라졸릴기를 나타냄; ?L1 은 하기로 이루어진 목록에서 선택되는 2 가 기 또는 직접 결합을 나타냄: [이미지] 여기서, ?n 은 1, 2, 3 또는 4 을 나타냄; ?m 및 p 는 독립적으로 0, 1, 2 또는 3 을 나타냄; ?L2 는 하기로 이루어진 목록에서 선택되는 2 가 기 또는 직접 결합을 나타냄: [이미지] 여기서, ?q 는 1, 2, 3 또는 4 를 나타냄; ?a 및 b 는 독립적으로 0, 1, 2 또는 3 을 나타냄; ?A 는 A1 내지 A116 으로 이루어진 목록에서 선택됨: [이미지] [이미지] [이미지] [이미지] [이미지] 여기서, ?Z1, Z2, Z3, Z4, Z5, Z6, Z7, Z8 및 Z9 은 독립적으로 수소, 할로겐, [C1-C8]-알킬, [C1-C8]-할로알킬, [C2-C8]-알케닐, [C2-C8]-할로알케닐, [C2-C8]-알키닐, [C2-C8]-할로알키닐, [C3-C6]-시클로알킬, [C3-C6]-할로시클로알킬, 아릴, 아릴-[C1-C8]-알킬, 히드록시-[C1-C8]-알킬, [C1-C8]-알콕시-[C1-C8]-알킬, -C(=O)R5, -C(=O)OR5, -C(=O)NR5R6, -C(=O)SR5, -C(=S)R5, -C(=S)OR5, -C(=S)NR5R6, -C(=S)SR5, -CR5=NR6, -CR5=NOR6, -CR5=N-NR6R7, -OR5, -OSiR5R6R7, -OC(=O)R5, -OC(=O)OR5, -OC(=O)NR5R6, -OC(=S)NR5R6, -NR5R6, -N(R5)C(=O)R6, -N(R5)C(=O)OR6, -N(R5)C(=O)NR6R7, -N(R5)C(=S)R6, -N(R5)C(=S)NR6R7, -N=CR5R6, -N=C-NR5R6, -N(R5)C(=NR6)NR7R8, -N(R5)OR6, -N(R5)NR6R7, -N=NR5, -N(R5)S(=O)R6, -N(R5)S(=O)2R6, -N(R5)S(=O)2OR6, -N(R5)S(=O)OR6, -N(R5)S(=O)NR6R7, -N(R5)S(=O)2NR6R7, -SR5, -S(=O)R5, -S(=O)2R5, -S(=O)OR5, -S(=O)NR5R6, -S(=O)2OR5, -S(=O)2NR5R6, 니트로, 니트로소, 아지도, 시아노, -SF5 및 -SiR5R6R7 로 이루어진 목록에서 선택됨; ?K1 및 K2 은 독립적으로 수소, [C1-C8]-알킬, [C1-C8]-할로알킬, [C2-C8]-알케닐, [C2-C8]-할로알케닐, [C2-C8]-알키닐, [C2-C8]-할로알키닐, [C3-C6]-시클로알킬, [C3-C6]-할로시클로알킬, 아릴, 아릴-[C1-C8]-알킬, 히드록시-[C1-C8]-알킬, [C1-C8]-알콕시-[C1-C8]-알킬, -C(=O)R9, -C(=O)OR9, -C(=O)NR9R10, -C(=O)SR9, -C(=S)R9, -C(=S)OR9, -C(=S)NR9R10, -C(=S)SR9, -CR9=NR10, -CR9=NOR10, -CR9=N-NR10R11, -S(=O)R9, -S(=O)2R9, -S(=O)OR9, -S(=O)NR9R10, -S(=O)2OR9, -S(=O)2NR9R10 및 -SiR9R10R11 로 이루어진 목록에서 선택됨; ?G1 및 G2 는 독립적으로 산소, 황, NR12, N-OR12 및 N-NR12R13 로 이루어진 목록에서 선택됨; ?Q 는 Q1 내지 Q12 로 이루어진 목록에서 선택됨: [이미지] 여기서, ?X1 내지 X11 는 독립적으로 수소, 할로겐, [C1-C8]-알킬, [C1-C8]-할로알킬, [C2-C8]-알케닐, [C2-C8]-할로알케닐, [C2-C8]-알키닐, [C2-C8]-할로알키닐, [C3-C6]-시클로알킬, [C3-C6]-할로시클로알킬, 아릴, 아릴-[C1-C8]-알킬, 히드록시-[C1-C8]-알킬, [C1-C8]-알콕시-[C1-C8]-알킬, -C(=O)R14, -C(=O)OR14, -C(=O)NR14R15, -C(=O)SR14, -C(=S)R14, -C(=S)OR14, -C(=S)NR14R15, -C(=S)SR14, -CR14=NR15, -CR14=NOR15, -CR14=N-NR15R16, -OR14, -OSiR14R15R16, -OC(=O)R14, -OC(=O)OR14, -OC(=O)NR14R15, -OC(=S)NR14R15, -NR14R15, -N(R14)C(=O)R15, -N(R14)C(=O)OR15, -N(R14)C(=O)NR15R16, -N(R14)C(=S)R15, -N(R14)C(=S)NR15R16, -N=CR14R15, -N=C-NR14R15, -N(R14)C(=NR15)NR16R17, -N(R14)OR15, -N(R14)NR15R16, -N=NR14, -N(R14)S(=O)R15, -N(R14)S(=O)2R15, -N(R14)S(=O)2OR15, -N(R14)S(=O)OR15, -N(R14)S(=O)NR15R16, -N(R14)S(=O)2NR15R16, -SR14, -S(=O)R14, -S(=O)2R14, -S(=O)OR14, -S(=O)NR14R15, -S(=O)2OR14, -S(=O)2NR14R15, 니트로, 니트로소, 아지도, 시아노, -SF5 및 -SiR14R15R16 로 이루어진 목록에서 선택됨; ?R1, R2, R3 및 R4 은 독립적으로 수소, 할로겐, [C1-C4]-알킬, [C1-C4]-할로알킬, [C2-C4]-알케닐, [C2-C4]-할로알케닐, [C2-C4]-알키닐, [C2-C4]-할로알키닐, [C3-C5]-시클로알킬, [C3-C5]-할로시클로알킬, [C1-C4]-알콕시, [C1-C4]-알콕시-[C1-C4]-알킬, [C1-C4]-알콕시-[C1-C4]-알콕시, [C1-C4]-할로알콕시, [C1-C4]-할로알콕시-[C1-C4]-알킬 및 시아노로 이루어진 목록에서 선택됨; ?R5 내지 R17 은 독립적으로 수소, [C1-C8]-알킬, [C1-C8]-할로알킬, [C2-C8]-알케닐, [C2-C8]-할로알케닐, [C2-C8]-알키닐, [C2-C8]-할로알키닐, [C3-C6]-시클로알킬, [C3-C6]-할로시클로알킬, 아릴 및 아릴-[C1-C8]-알킬로 이루어진 목록에서 선택됨; 단, A 가 A2, A5, A11, A16, A17, A18, A23, A24, A29, A30, A34 및 A36 로 이루어진 목록에서 선택되고, L1 은 CH2 을 나타내며, L2 은 직접 결합인 경우, Q 는 Q1 을 나타낼 수 없음.