2-[3-(ALKYLSULFONYL)-2H-INDAZOL-2-YL]-3H-IMIDAZO[4,5-B]PYRIDINE DERIVATIVES AND SIMILAR COMPOUNDS AS PESTICIDESThe invention relates to compounds of the formula (Ia) or (Ib), in which Aa, Ab, Ac, Ad, R1, R10R11, R12, R13, R14, R15, R16, R17, Q, R4, R5, R6 and n have the meanings indicated in the claims, and to agrochemical formulations containing the compounds according to formula (Ia) or (Ib) for use as acaricides and/or insecticides for combating animal pests, primarily arthropods and in particular insects and arachnids. 2-[3-(alkylsulfonyl)-2H-indazol-2-yl]-3H- imidazo[4,5-b]pyridine derivatives and similar compounds are particularly preferable.The compound of formula (ia) or (ib)whereinindicate singly-bound or double bond,wherein,ifonly indicate double bond, therefore aa to ad is formed together together with the carbon atom adjacent with aa and ad in each case aromatic ring, thenaa is nitrogen or c (r10),ab is nitrogen or c (r11),ac is nitrogen or c (r12), andad is nitrogen or c (r13),wherein being no more than two in aa, ab, ac and ad is nitrogen,alternatively, ifonly indicate singly-bound, thenaa is c (r10)(r14),ab is c (r11)(r15),ac is c (r12)(r16), andad is c (r13)(r17),r1for (c1-c6) alkyl, (c1-c6) halogenated alkyl, (c1-c6) cyanoalkyl, (c1-c6) hydroxy alkyl, (c1-c6) alcoxyl base-(c1-c6) alkyl, (c1-c6) halogenated alkoxy-(c1-c6) alkyl, (c2-c6) alkenyl, (c2-c6) alkenyloxy group-(c1-c6) alkane base, (c2-c6) haloalkenyloxy-(c1-c6) alkyl, (c2-c6) halogenated alkenyl, (c2-c6) cyano alkenyl, (c2-c6) alkynyl, (c2- c6) alkynyloxy group-(c1-c6) alkyl, (c2-c6) halogenated alkynyloxy group-(c1-c6) alkyl, (c2-c6) halo alkynyl, (c2-c6) cyano alkynes base, (c3-c8) naphthenic base, (c3-c8) naphthenic base-(c3-c8) naphthenic base, (c1-c6) alkyl-(c3-c8) naphthenic base, halogenated (c3- c8) naphthenic base, amino, (c1-c6) alkyl amino, two (c1-c6) alkyl amino, (c3-c8) cycloalkyl amino, (c1-c6) alkyl oxycarbonyl base amino, (c1-c6) alkylthio group-(c1-c6) alkyl, (c1-c6) halogenated alkylthio-(c1-c6) alkyl, (c1-c6) alkyl sulfenyl base-(c1-c6) alkyl, (c1-c6) alkylsulfinyl-(c1-c6) alkyl, (c1-c6) alkyl sulphonyl-(c1-c6) alkane base, (c1-c6) halogenated alkyl sulfonyl-(c1-c6) alkyl, (c1-c6) alkoxy-(c1-c6) alkylthio group-(c1-c6) alkyl, (c1- c6) alkoxy-(c1-c6) alkyl sulphinyl-(c1-c6) alkyl, (c1-c6) alkoxy-(c1-c6) alkyl sulphonyl-(c1-c6) alkyl, (c1-c6) alkyl-carbonyl-(c1-c6) alkyl, (c1-c6) halogenated alkyl carbonyl-(c1-c6) alkyl, (c1-c6) alkoxy carbonyl base-(c1-c6) alkyl, (c1-c6) halo alkoxy carbonyl-(c1-c6) alkyl, (c1-c6) alkyl sulfonyl-amino, aminosulfonyl base-(c1-c6) alkyl, (c1-c6) alkyl amino sulfonyl-(c1-c6) alkyl, two (c1-c6) alkyl amino sulfonyl-(c1-c6) alkyl,or in each case by aryl, heteroaryl or heterocycle be identical or differently monosubstituted or polysubstituted (c1-c6) alkane base, (c1-c6) alkoxy, (c2-c6) alkenyl, (c2-c6) alkynyl, (c3-c8) naphthenic base, wherein aryl, heteroaryl or heterocycle can respectively it is optionally identical or differently monosubstituted or polysubstituted by following groups: halogen, cyano, nitro, hydroxyl, amino, carboxyl, carbamoyl, amino-sulfonyl, (c1-c6) alkyl, (c3-c6) naphthenic base, (c1-c6) alkoxy, (c1-c6) halogenated alkyl, (c1-c6) halogenated alkoxy, (c1-c6) alkylthio group, (c1-c6) alkyl sulphinyl, (c1-c6) alkyl sulphonyl, (c1-c6) alkane base sulphur imino group, (c1-c6) alkyl sulfide imino group-(c1-c6) alkyl, (c1-c6) alkyl sulfide imino group-(c2-c6) alkyl-carbonyl, (c1-c6) alkyl sulfoxide imino group, (c1-c6) alkyl sulfoxide imino group-(c1-c6) alkyl, (c1-c6) alkyl sulfoxide imino group- (c2-c6) alkyl-carbonyl, (c1-c6) alkoxy carbonyl, (c1-c6) alkyl-carbonyl, (c3-c6) trialkylsilkl or benzyl, orr1it is respectively optionally identical or differently monosubstituted or polysubstituted by following groups for aryl, heteroaryl or heterocycle: halogen, cyano, nitro, hydroxyl, amino, carboxyl, carbamoyl, (c1-c6)-alkyl, (c3-c8) naphthenic base, (c1-c6)-alkane oxygroup, (c1-c6) halogenated alkyl, (c1-c6) halogenated alkoxy, (c1-c6) alkylthio group, (c1-c6) alkyl sulphinyl, (c1-c6) alkyl sulphonyl, (c1-c6) alkyl sulfide imino group, (c1-c6) alkyl sulfide imino group-(c1-c6) alkyl, (c1-c6) alkyl sulfide imido base-(c2-c6) alkyl-carbonyl, (c1-c6) alkyl sulfoxide imino group, (c1-c6) alkyl sulfoxide imino group-(c1-c6) alkyl, (c1- c6) alkyl sulfoxide imino group-(c2-c6) alkyl-carbonyl, (c1-c6) alkoxy carbonyl, (c1-c6) alkyl-carbonyl, (c3-c6) three alkane base silicyl, (=o) (only in the case where heterocycle) or (=o)2(only in the case where heterocycle),r10、r11、r12、r13、r14、r15、r16、r17it independently is hydrogen, cyano, halogen, nitro, hydroxyl, amino, three (c1-c6) alkane base silicyl, (c3-c8) naphthenic base, (c3-c8) naphthenic base-(c3-c8) naphthenic base, (c1-c6) alkyl-(c3-c8) naphthenic base, halogenated (c3-c8) naphthenic base, (c1-c6) alkyl, (c1-c6) halogenated alkyl, (c1-c6) cyanoalkyl, (c1-c6) hydroxy alkyl, hydroxyl base carbonyl-(c1-c6)-alkoxy, (c1-c6) alkoxy carbonyl-(c1-c6) alkyl, (c1-c6) alkoxy-(c1-c6) alkyl, (c2-c6) alkenyl, (c2-c6) halogenated alkenyl, (c2-c6) cyano alkenyl, (c2-c6) alkynyl, (c2-c6) halo alkynyl, (c2-c6) cyanogen base alkynyl, (c1-c6) alkoxy, (c1-c6) halogenated alkoxy, (c1-c6) cyano alkoxy, (c1-c6) alkoxy carbonyl-(c1- c6) alkoxy, (c1-c6) alkoxy-(c1-c6) alkoxy, (c1-c6) alkyl hydroxy imino group, (c1-c6) alkoximino, (c1-c6) alkyl-(c1-c6) alkoximino, (c1-c6) halogenated alkyl-(c1-c6) alkoximino, (c1-c6) alkane sulphur base, (c1-c6) halogenated alkylthio, (c1-c6) alkoxy-(c1-c6) alkylthio group, (c1-c6) alkylthio group-(c1-c6) alkyl, (c1- c6) alkyl sulphinyl, (c1-c6) alkylsulfinyl...
살충제로서의 2-[3-(알킬술포닐)-2H-인다졸-2-일]-3H-이미다조[4,5-b]피리딘 유도체 및 유사한 화합물본 발명은 Aa, Ab, Ac, Ad, R1, R10, R11, R12, R13, R14, R15, R16, R17, Q, R4, R5, R6 및 n이 청구범위에 나타난 의미를 갖는 것인 화학식 (Ia) 또는 (Ib)의 화합물, 및 동물 해충, 주로 절지동물 및 특히 곤충 및 거미류를 퇴치하기 위한 살진드기제 및/또는 살곤충제로서 사용하기 위한 화학식 (Ia) 또는 (Ib)에 따른 화합물을 함유하는 농약 제제에 관한 것이다. 2-[3-(알킬술포닐)-2H-인다졸-2-일]-3H-이미다조[4,5-b]피리딘 유도체 및 유사한 화합물이 특히 바람직하다.[이미지]화학식 (Ia) 또는 (Ib)의 화합물.[이미지]여기서 [이미지]는 단일 결합 또는 이중 결합을 나타내고,여기서,[이미지]가 독점적으로 이중 결합을 나타내고, 따라서 각 경우에 Aa 내지 Ad가 Aa 및 Ad에 인접한 탄소 원자와 함께 방향족 고리를 형성하는 경우에,Aa는 질소 또는 C(R10)이고,Ab는 질소 또는 C(R11)이고,Ac는 질소 또는 C(R12)이고,Ad는 질소 또는 C(R13)이고,여기서 Aa, Ab, Ac 및 Ad 중 2개 이하는 질소이거나,또는, [이미지]가 독점적으로 단일 결합을 나타내는 경우에,Aa는 C(R10)(R14)이고,Ab는 C(R11)(R15)이고,Ac는 C(R12)(R16)이고,Ad는 C(R13)(R17)이고,R1은 (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)히드록시알킬, (C1-C6)알콕시-(C1-C6)알킬, (C1-C6)할로알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)알케닐옥시-(C1-C6)알킬, (C2-C6)할로알케닐옥시-(C1-C6)알킬, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C2-C6)알키닐, (C2-C6)알키닐옥시-(C1-C6)알킬, (C2-C6)할로알키닐옥시-(C1-C6)알킬, (C2-C6)할로알키닐, (C2-C6)시아노알키닐, (C3-C8)시클로알킬, (C3-C8)시클로알킬-(C3-C8)시클로알킬, (C1-C6)알킬-(C3-C8)시클로알킬, 할로(C3-C8)시클로알킬, 아미노, (C1-C6)알킬아미노, 디(C1-C6)알킬아미노, (C3-C8)시클로알킬아미노, (C1-C6)알킬카르보닐아미노, (C1-C6)알킬티오-(C1-C6)알킬, (C1-C6)할로알킬티오-(C1-C6)알킬, (C1-C6)알킬술피닐-(C1-C6)알킬, (C1-C6)할로알킬술피닐-(C1-C6)알킬, (C1-C6)알킬술포닐-(C1-C6)알킬, (C1-C6)할로알킬술포닐-(C1-C6)알킬, (C1-C6)알콕시-(C1-C6)알킬티오-(C1-C6)알킬, (C1-C6)알콕시-(C1-C6)알킬술피닐-(C1-C6)알킬, (C1-C6)알콕시-(C1-C6)알킬술포닐-(C1-C6)알킬, (C1-C6)알킬카르보닐-(C1-C6)알킬, (C1-C6)할로알킬카르보닐-(C1-C6)알킬, (C1-C6)알콕시카르보닐-(C1-C6)알킬, (C1-C6)할로알콕시카르보닐-(C1-C6)알킬, (C1-C6)알킬술포닐아미노, 아미노술포닐-(C1-C6)알킬, (C1-C6)알킬아미노술포닐-(C1-C6)알킬, 디(C1-C6)알킬아미노술포닐-(C1-C6)알킬이거나,또는 각 경우에 단일 또는 다중으로, 동일하거나 상이하게 아릴-, 헤타릴- 또는 헤테로시클릴-치환된 (C1-C6)알킬, (C1-C6)알콕시, (C2-C6)알케닐, (C2-C6)알키닐, (C3-C8)시클로알킬이고, 여기서 아릴, 헤타릴 또는 헤테로시클릴은 각각 할로겐, 시아노, 니트로, 히드록실, 아미노, 카르복실, 카르바모일, 아미노술포닐, (C1-C6)알킬, (C3-C6)시클로알킬, (C1-C6)알콕시, (C1-C6)할로알킬, (C1-C6)할로알콕시, (C1-C6)알킬티오, (C1-C6)알킬술피닐, (C1-C6)알킬술포닐, (C1-C6)알킬술프이미노, (C1-C6)알킬술프이미노-(C1-C6)알킬, (C1-C6)알킬술프이미노-(C2-C6)알킬카르보닐, (C1-C6)알킬술폭시미노, (C1-C6)알킬술폭시미노-(C1-C6)알킬, (C1-C6)알킬술폭시미노-(C2-C6)알킬카르보닐, (C1-C6)알콕시카르보닐, (C1-C6)알킬카르보닐, (C3-C6)트리알킬실릴 또는 벤질에 의해 동일하거나 상이하게 임의로 일- 또는 다치환될 수 있거나, 또는R1은 각각 할로겐, 시아노, 니트로, 히드록실, 아미노, 카르복실, 카르바모일, (C1-C6)알킬, (C3-C8)시클로알킬, (C1-C6)-알콕시, (C1-C6)할로알킬, (C1-C6)할로알콕시, (C1-C6)알킬티오, (C1-C6)알킬술피닐, (C1-C6)알킬술포닐, (C1-C6)알킬술프이미노, (C1-C6)알킬술프이미노-(C1-C6)알킬, (C1-C6)알킬술프이미노-(C2-C6)알킬카르보닐, (C1-C6)알킬술폭시미노, (C1-C6)알킬술폭시미노-(C1-C6)알킬, (C1-C6)알킬술폭시미노-(C2-C6)알킬카르보닐, (C1-C6)알콕시카르보닐, (C1-C6)알킬카르보닐, (C3-C6)트리알킬실릴, (=O) (헤테로시클릴 단독의 경우) 또는 (=O)2 (헤테로시클릴 단독의 경우)에 의해 동일하거나 상이하게 임의로 일- 또는 다치환된 아릴, 헤타릴 또는 헤테로시클릴이고,R10, R11, R12, R13, R14, R15, R16, R17은 독립적으로 수소, 시아노, 할로겐, 니트로, 히드록실, 아미노, 트리(C1-C6)알킬실릴, (C3-C8)시클로알킬, (C3-C8)시클로알킬-(C3-C8)시클로알킬, (C1-C6)알킬-(C3-C8)시클로알킬, 할로(C3-C8)시클로알킬, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)히드록시알킬, 히드록시카르보닐-(C1-C6)-알콕시, (C1-C6)알콕시카르보닐-(C1-C6)알킬, (C1-C6)알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐, (C2-C6)시아노알키닐, (C1-C6)알콕시, (C1-C6)할로알콕시, (C1-C6)시아노알콕시, (C1-C6)알콕시카르보닐-(C1-C6)알콕시, (C1-C6)알콕시-(C1-C6)알콕시, (C1-C6)알킬히드록시이미노, (C1-C6)알콕시이미노, (C1-C6)알킬-(C1-C6)알콕시이미노, (C1-C6)할로알킬-(C1-C6)알콕시이미노, (C1-C6)알킬티오, (C1-C6)할로알킬티오, (C1-C6)알콕시-(C1-C6)알킬티오, (C1-C6)알킬티오-(C1-C6)알킬, (C1-C6)알킬술피닐, (C1-C6)할로알킬술피닐, (C1-C6)알콕시-(C1-C6)알킬술피닐, (C1-C6)알킬술피닐-(C1-C6)알킬, (C1-C6)알킬술포닐, (C1-C6)할로알킬술포닐, (C1-C6)알콕시-(C1-C6)알킬술포닐, (C1-C6)알킬술포닐-(C1-C6)알킬, (C1-C6)알킬술포닐옥시, (C1-C6)알킬카르보닐, (C1-C6)알킬티오카르보닐, (C1-C6)할로알킬카르보닐, (C1-C6)알킬카르보닐옥시, (C1-C6)알콕시카르보닐, (C1-C6)할로알콕시카르보닐, 아미노카르보닐, (C1-C6)알킬아미노카르보닐, (C1-C6)알킬아미노티오카르보닐, 디(C1-C6)알킬아미노카르보닐, 디(C1-C6)알킬아미노티오카르보닐, (C2-C6)알케닐아미노카르보닐, 디(C2-C6)알케닐아미노카르보닐, (C3-C8)시클로알킬아미노카르보닐, (C1-C6)알킬술포닐아미노, (C1-C6)알킬아미노, 디(C1-C6)알킬아미노, 아미노술포닐, (C1-C6)알킬아미노술포닐, 디(C1-C6)알킬아미노술포닐, (C1-C6)알킬술폭시미노, 아미노티오카르보닐, (C1-C6)알킬아미노티오카르보닐, 디(C1-C6)알킬아미노티오카르보닐, (C3-C8)시클로알킬아미노, (C1-C6)알킬카르바모일 (-NHCOO(C1-C6)알킬, -N(C1-C6)알킬COO(C1-C6)알킬, -OCONH(C1-C6)알킬 또는 -OCON(C1-C6)디알킬 포함), (C1-C6)알킬카르보닐아미노 ((C1-C6)알킬CONH), (C1-C6)알킬우레아 (-NHCONH(C1-C6)알킬, 및 -NHCON(C1-C6)디알킬 포함)이거나 또는각 경우에 임의로 단일 또는 다중으로, 동일하거나 상이하게 치환된 아릴 또는 헤타릴이고, 여기서 (헤타릴의 경우) 적어도 1개의 카르보닐 기가 임의로 존재할 수 있고 여기서 각 경우에 가능한 치환기는 하기: 시아노, 카르복실, 할로겐, 니트로, 히드록실, 아미노, 트리-(C1-C6)알킬실릴, (C3-C8)시클로알킬, (C3-C8)시클로알킬-(C3-C8)시클로알킬, (C1-C6)알킬-(C3-C8)시클로알킬, 할로(C3-C8)시클로알킬, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)히드록시알킬, 히드록시카르보닐-(C1-C6)-알콕시, (C1-C6)알콕시카르보닐-(C1-C6)알킬, (C1-C6)알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐, (C2-C6)시아노알키닐, (C1-C6)알콕시, (C1-C6)할로알콕시, (C1-C6)시아노알콕시, (C1-C6)알콕시카르보닐-(C1-C6)알콕시, (C1-C6)알콕시-(C1-C6)알콕시, (C1-C6)알킬히드록시이미노, (C1-C6)알콕시이미노, (C1-C6)알킬-(C1-C6)알콕시이미노, (C1-C6)할로알킬-(C1-C6)알콕시이미노, (C1-C6)알킬티오, (C1-C6)할로알킬티오, (C1-C6)알콕시-(C1-C6)알킬티오, (C1-C6)알킬티오-(C1-C6)알킬, (C1-C6)알킬술피닐, (C1-C6)할로알킬술피닐, (C1-C6)알콕시-(C1-C6)알킬술피닐, (C1-C6)알킬술피닐-(C1-C6)알킬, (C1-C6)알킬술포닐, (C1-C6)할로알킬술포닐, (C1-C6)알콕시-(C1-C6)알킬술포닐, (C1-C6)알킬술포닐-(C1-C6)알킬, (C1-C6)알킬술포닐옥시, (C1-C6)알킬카르보닐, (C1-C6)할로알킬카르보닐, (C1-C6)알킬카르보닐옥시, (C1-C6)알콕시카르보닐, (C1-C6)할로알콕시카르보닐, 아미노카르보닐, (C1-C6)알킬아미노카르보닐, 디(C1-C6)알킬아미노카르보닐, (C2-C6)알케닐아미노카르보닐, 디(C2-C6)-알케닐아미노카르보닐, (C3-C8)시클로알킬아미노카르보닐, (C1-C6)알킬술포닐아미노, (C1-C6)알킬아미노, 디(C1-C6)알킬아미노, 아미노술포닐, (C1-C6)알킬아미노술포닐, 디(C1-C6)알킬아미노술포닐, (C1-C6)알킬술폭시미노, 아미노티오카르보닐, (C1-C6)알킬아미노티오카르보닐, 디(C1-C6)알킬아미노티오카르보닐, (C3-C8)시클로알킬아미노 또는 (C1-C6)알킬카르보닐아미노와 같고,여기서 R10, R11, R12, R13, R14, R15, R16 및 R17 라디칼 중 오직 1 또는 2개는 수소 이외의 치환기이고,R10 및 R14, R11 및 R15, R12 및 R...