Synergistic fungicidal mixturesThe present invention relates to a composition, comprising a 5-amino-3-oxo-2,3- dihydro-pyrazole of the formula I as defined in the claims and the description and at least one active compound Il selected from groups A) to I) in a synergistically effective amount.Composition, it comprises with the synergistic effective dose:1) 5-amino-3-oxo-2,3-dihydro-pyrazoles i:whereinr 1be c 1-c 10alkyl; r 2be c 1-c 6alkyl, c 2-c 6alkenyl or c 2-c 6alkynyl; r 3be aryl, it is chosen wantonly by 1-5 and is independently selected from following substituting group replacement: halogen, c 1-c 6alkyl, c 1-c 6haloalkyl, c 2-c 6alkenyl, c 2-c 6alkynyl, c 1-c 6alkoxyl, c 1-c 6halogenated alkoxy, c 2-c 6alkenyloxy, c 2-c 6halo alkenyloxy, c 2-c 6alkynyloxy group, c 2-c 6halo alkynyloxy group, c 1-c 6alkoxy-c 1-c 6alkyl, c 1-c 6alkoxy-c 1-c 6alkoxyl, c 1-c 6alkylthio group, c 1-c 6halogenated alkylthio, c 2-c 6alkenyl thio, c 2-c 6halo alkenyl thio, cyano group and nitro; with x is o or s;with2) the reactive compound ii at least a group a that is selected from)-i):a) strobilurinsthe nitrile fluoxastrobin, ether bacterium amine, enestroburin, fluoxastrobin, the imines bacterium, fork phenalgin acid amides, orysastrobin, zen 90160, pyraclostrobin, pyribencarb, oxime bacterium ester, 2-(2-(6-(3-chloro-2-methyl-phenoxy group)-5-fluoro-pyrimidine-4-base oxygen base)-phenyl)-2-methoxyimino-n-methyl-acetamide, 3-methoxyl group-2-(2-(n-(4-methoxyl group-phenyl)-cyclopropane imidic acid acyl group sulfidomethyl-phenyl)-methyl acrylate, (2-chloro-5-[1-(3-methyl benzyloxy imino) ethyl] benzyl) methyl carbamate and 2-(2-(3-(2, the 6-dichlorophenyl)-1-methyl-allylidene base amino oxygen ylmethyl)-phenyl)-2-methoxyimino-n-methyl-acetamide;b) carboxyl acylamide-carboxanilides class: m 9834, smart m 9834, benodanil, carboxin, methuroxam, fenhexamid, flutolanil, the spirit of furan pyrazoles, isopyrazam, isotianil, kiralaxyl, third oxygen go out embroider amine, metalaxyl, metalaxyl-m, fenfuram, the frost spirit, oxycarboxin, tecloftalam, thifluzamide, tiadinil, 2-amino-4-methyl-thiazole-5-formailide, 2-chloro-n-(1,1,3-trimethyl-indane-4-yl)-vitamin pp, n-(2 ', 4 '-dfbp-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(2 ', 4 '-dcbp-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(2 ', 5 '-dfbp-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(2 ', 5 '-dcbp-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(3 ', 5 '-dfbp-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(3 '-fluorine biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(3 '-chlordiphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(2 '-fluorine biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(2 '-chlordiphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(3 ', 5 '-dcbp-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-[2-(1,1,2,3,3,3-hexafluoro propoxyl group)-phenyl]-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-[2-(1,1,2,2-tetrafluoro ethyoxyl)-phenyl]-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(4 '-trifluoromethyl sulphur biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, (2-(1 for n-, 3-dimethyl-butyl)-and phenyl)-1,3-dimethyl-5-fluoro-1h-pyrazole-4-carboxamide, (2-(1 for n-, 3,3-trimethyl-butyl)-and phenyl)-1,3-dimethyl-5-fluoro-1h-pyrazole-4-carboxamide, n-(4 '-chloro-3 ', 5 '-two fluoro-biphenyl-2-yls)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(4 '-chloro-3 ', 5 '-two fluoro-biphenyl-2-yls)-3-trifluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(3 ', 4 '-two chloro-5 '-fluoro-biphenyl-2-yl)-3-trifluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(3 ', 5 '-two fluoro-4 '-methyl-biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(3 ', 5 '-two fluoro-4 '-methyl-biphenyl-2-yl)-3-trifluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(2-dicyclo propane-2-base-phenyl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(suitable-2-dicyclo propane-2-base-phenyl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-(anti--2-dicyclo propane-2-base-phenyl)-3-difluoromethyl-1-methyl isophthalic acid h-pyrazole-4-carboxamide, n-[1,2,3,4-tetrahydrochysene-9-(1-methylethyl)-1,4-methanonaphthalene-5-yl]-3-(difluoromethyl)-1-methyl isophthalic acid h-pyrazole-4-carboxamide; -carboxylic acid morpholine thing: dimethomorph, flumorph;-benzamides: fluorine biphenyl bacterium, fluorine pyrrole bacterium amine, fluorine pyrrole bacterium acid amides, zoxamide, n-(3-ethyl-3,5,5-trimethyl-cyclohexyl)-3-formamido group-2-hydroxyl-benzamide;-other carboxylic acid amides: carpropamide, two chlorine zarilamid, mandipropamid amine, terramycin, silicon metsulfovax and n-(6-methoxypyridine-3-yl) cyclopropane carboxamide;c) azole-triazole type: penta ring bacterium, bitertanol, bromuconazole, cyproconazole, ether azoles, alkene azoles...
상승작용적 살진균 혼합물본 발명은 청구항 및 명세서에 정의된 바와 같은 화학식 I의 5-아미노-3-옥소-2,3-디히드로-피라졸 및 A) 내지 I) 군으로부터 선택되는 하나 이상의 활성 화합물 II를 상승작용적 유효량으로 포함하는 조성물에 관한 것이다.1) 하기 화학식 I의 5-아미노-3-옥소-2,3-디히드로-피라졸 I <화학식 I>[이미지](상기 식에서,R1은 C1-C10-알킬이고;R2는 C1-C6-알킬, C2-C6-알케닐 또는 C2-C6-알키닐이고; R3은 할로겐, C1-C6-알킬, C1-C6-할로알킬, C2-C6-알케닐, C2-C6-알키닐, C1-C6-알콕시, C1-C6-할로알콕시, C2-C6-알케닐옥시, C2-C6-할로알케닐옥시, C2-C6-알키닐옥시, C2-C6-할로알키닐옥시, C1-C6-알콕시-C1-C6-알킬, C1-C6-알콕시-C1-C6-알콕시, C1-C6-알킬티오, C1-C6-할로알킬티오, C2-C6-알케닐티오, C2-C6-할로알케닐티오, 시아노 및 니트로로 이루어진 군으로부터 독립적으로 선택되는 1 내지 5개의 치환기로 임의로 치환되는 아릴이고;X는 O 또는 S임)및2) 하기 A) 내지 I) 군으로부터 선택되는 하나 이상의 활성 화합물 II를 상승작용적 유효량으로 포함하는 조성물:A) 스트로빌루린아족시스트로빈, 디목시스트로빈, 에네스트로부린, 플루옥사스트로빈, 크레속심-메틸, 메토미노스트로빈, 오리사스트로빈, 피콕시스트로빈, 피라클로스트로빈, 피리벤카르브, 트리플록시스트로빈, 2-(2-(6-(3-클로로-2-메틸-페녹시)-5-플루오로-피리미딘-4-일옥시)-페닐)-2-메톡시이미노-N-메틸-아세트아미드, 3-메톡시-2-(2-(N-(4-메톡시-페닐)-시클로프로판-카르복스이미도일술파닐메틸)-페닐)-아크릴산 메틸 에스테르, 메틸 (2-클로로-5-[1-(3-메틸벤질옥시이미노)에틸]벤질)카르바메이트 및 2-(2-(3-(2,6-디클로로페닐)-1-메틸-알릴리덴아미노옥시메틸)-페닐)-2-메톡시이미노-N-메틸-아세트아미드;B) 카르복스아미드- 카르복스아닐리드: 베날락실, 베날락실-M, 베노다닐, 카르복신, 펜푸람, 펜헥사미드, 플루톨라닐, 푸라메트피르, 이소피라잠, 이소티아닐, 키랄락실, 메프로닐, 메탈락실, 메탈락실-M (메페녹삼), 오푸레이스, 옥사딕실, 옥시카르복신, 테클로프탈람, 티플루자미드, 티아디닐, 2-아미노-4-메틸-티아졸-5-카르복스아닐리드, 2-클로로-N-(1,1,3-트리메틸-인단-4-일)-니코틴아미드, N-(2',4'-디플루오로비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2',4'-디클로로비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2',5'-디플루오로비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2',5'-디클로로비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3',5'-디플루오로비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3'-플루오로비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3'-클로로비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2'-플루오로비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2'-클로로비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3',5'-디클로로비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-[2-(1,1,2,3,3,3-헥사플루오로프로폭시)-페닐]-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-[2-(1,1,2,2-테트라플루오로에톡시)-페닐]-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(4'-트리플루오로메틸티오비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2-(1,3-디메틸-부틸)-페닐)-1,3-디메틸-5-플루오로-1H-피라졸-4-카르복스아미드, N-(2-(1,3,3-트리메틸-부틸)-페닐)-1,3-디메틸-5-플루오로-1H-피라졸-4-카르복스아미드, N-(4'-클로로-3',5'-디플루오로-비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(4'-클로로-3',5'-디플루오로-비페닐-2-일)-3-트리플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3',4'-디클로로-5'-플루오로-비페닐-2-일)-3-트리플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3',5'-디플루오로-4'-메틸-비페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(3',5'-디플루오로-4'-메틸-비페닐-2-일)-3-트리플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(2-비시클로프로필-2-일-페닐)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(시스-2-비시클로프로필-2-일-페닐)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-(트랜스-2-비시클로프로필-2-일-페닐)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복스아미드, N-[1,2,3,4-테트라히드로-9-(1-메틸에틸)-1,4-메타노나프탈렌-5-일]-3-(디플루오로메틸)-1-메틸-1H-피라졸-4-카르복스아미드;- 카르복실산 모르폴리드: 디메토모르프, 플루모르프;- 벤조산 아미드: 플루메토베르, 플루오피콜리드, 플루오피람, 족사미드, N-(3-에틸-3,5-5-트리메틸시클로헥실)-3-포르밀아미노-2-히드록시벤즈아미드;- 다른 카르복스아미드: 카르프로파미드, 디시클로메트, 만디프로아미드, 옥시테트라시클린, 실티오팜 및 N-(6-메톡시-피리딘-3-일) 시클로프로판카르복실산 아미드;C) 아졸- 트리아졸: 아자코나졸, 비테르타놀, 브로무코나졸, 시프로코나졸, 디페노코나졸, 디니코나졸, 디니코나졸-M, 에폭시코나졸, 펜부코나졸, 플루퀸코나졸, 플루실라졸, 플루트리아폴, 헥사코나졸, 이미벤코나졸, 이프코나졸, 메트코나졸, 미클로부타닐, 옥스포코나졸, 파클로부트라졸, 펜코나졸, 프로피코나졸, 프로티오코나졸, 시메코나졸, 테부코나졸, 테트라코나졸, 트리아디메폰, 트리아디메놀, 트리티코나졸, 유니코나졸, 1-(4-클로로-페닐)-2-([1,2,4]트리아졸-1-일)-시클로헵탄올;- 이미다졸: 시아조파미드, 이마잘릴, 페푸라조에이트, 프로클로라즈, 트리플루미졸;- 벤즈이미다졸: 베노밀, 카르벤다짐, 푸베리다졸, 티아벤다졸;- 기타: 에타복삼, 에트리디아졸, 히멕사졸 및 2-(4-클로로-페닐)-N-[4-(3,4-디메톡시-페닐)-이속사졸-5-일]-2-프로프-2-이닐옥시-아세트아미드;D) 헤테로시클릭 화합물- 피리딘: 피리페녹스, 3-[5-(4-클로로-페닐)-2,3-디메틸-이속사졸리딘-3-일]-피리딘, 3-[5-(4-메틸-페닐)-2,3-디메틸-이속사졸리딘-3-일]-피리딘, 2,3,5,6-테트라-클로로-4-메탄술포닐-피리딘, 3,4,5-트리클로로피리딘-2,6-디-카르보니트릴, N-(1-(5-브로모-3-클로로-피리딘-2-일)-에틸)-2,4-디클로로니코틴아미드, N-[(5-브로모-3-클로로-피리딘-2-일)-메틸]-2,4-디클로로-니코틴아미드;- 피리미딘: 부피리메이트, 디플루메토림, 페나리몰, 페림존, 니트라피린, 누아리몰;- 피페라진: 트리포린;- 피롤: 펜피클로닐;- 모르폴린: 알디모르프, 도데모르프, 도데모르프-아세테이트, 펜프로피모르프, 트리데모르프;- 피페리딘: 펜프로피딘;- 디카르복스이미드: 플루오로이미드;- 비-방향족 5원 헤테로사이클: 파목사돈, 페나미돈, 옥틸리논, 프로베나졸;- 기타: 아시벤졸라르-S-메틸, 아미술브롬, 아닐라진, 블라스티시딘-S, 캅타폴, 캅탄, 키노메티오나트, 다조메트, 데바카르브, 디클로메진, 디펜조쿼트, 디펜조쿼트-메틸술페이트, 페녹사닐, 폴페트, 옥솔린산, 피페랄린, 프로퀴나지드, 피로퀼론, 퀴녹시펜, 트리아족시드, 트리시클라졸, 2-부톡시-6-요오도-3-프로필크로멘-4-온, 5-클로로-1-(4,6-디메톡시-피리미딘-2-일)-2-메틸-1H-벤조이미다졸, 5-클로로-7-(4-메틸피페리딘-1-일)-6-(2,4,6-트리플루오로페닐)-[1,2,4]트리아졸로[1,5-a]피리미딘, 6-(3,4-디클로로-페닐)-5-메틸-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민, 6-(4-tert-부틸페닐)-5-메틸-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민, 5-메틸-6-(3,5,5-트리메틸-헥실)-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민, 5-메틸-6-옥틸-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민, 6-메틸-5-옥틸-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민, 6-에틸-5-옥틸-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민, 5-에틸-6-옥틸-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민, 5-에틸-6-(3,5,5-트리메틸-헥실)-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민, 6-옥틸-5-프로필-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민, 5-메톡시메틸-6-옥틸-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민, 6-옥틸-5-트리플루오로메틸-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민 및 5-트리플루오로메틸-6-(3,5,5-트리메틸-헥실)-[1,2,4]트리아졸로[1,5-a]피리미딘-7-일아민;E) 카르바메이트- 티오- 및 디티오카르바메이트: 페르밤, 만코제브, 마네브, 메탐, 메타술포카르브, 메티람, 프로피네브, 티람, 지네브, 지람;- 카르바메이트: 벤티아발리카르브, 플루벤티아발리카르브, 이프로발리카르브, 프로파모카르브, 프로파모카르브 히드로클로리드, 발리페날 및 N-(1-(1-(4-시아노-페닐)에탄술포닐)-부트-2-일) 카르밤산-(4-플루오로페닐) 에스테르;F) 다른 활성 물질 - 구아니딘: 구아니딘, 도딘, 도딘 유리 염기, 구아자틴, 구아자틴-아세테이트, 이미녹타딘, 이미녹타딘-트리아세테이트, 이미녹타딘-트리스(알베실레이트);- 항생제: 카수가마이신, 카수가마이신 히드로클로라이드-수화물, 스트렙토마이신, 폴리옥신, 발리다마이신 A;- 니트로페닐 유도체: 비나파크릴, 디노부톤, 디노카프, 니트르탈-이소프로필, 테크나젠,유기금속 화합물: 펜틴 염, 예컨대 펜틴-아세테이트, 펜틴 클로라이드 또는 펜틴 히드록시드;- 황-함유 헤테로시클릴 화합물: 디티아논, 이소프로티올란;- 유기인 화합물: 에디펜포스, 포세틸, 포세틸-알루미늄, 이프로벤포스, 아인산 및 그의 ...