4-Amino-1,2,3-benzoxathiazine-derivatives as pesticides4-Amino-1,2,3-benzoxathiazine compounds (I) and their salts, are new. 4-Amino-1,2,3-benzoxathiazine compounds of formula (I) and their salts are new. R1-R4 : H, halo, carbamoyl, thiocarbamoyl, nitro, cyano, hydroxy, SF 5 , 1-6C-alkyl, 2-6C-alkenyl, 2-6C-alkynyl, 3-6C-cycloalkyl, 3-6C-cycloalkyl-1-4C-alkyl, 1-4C-alkylthio, 1-4C-alkylsulfinyl, 1-4C-alkylsulfonyl, 1-4C-alkylcarbonyl, 1-6C-alkoxy, 1-6C-alkoxycarbonyl, 3-6C-alkenyloxy, 3-6C-cycloalkyloxy, 3-6C-cycloalkyloxy-1-4C-alkyl, 1-4C-alkoxy-1-4C-alkyl, aryloxy, hetaryloxy, aryl-1-4C-alkyloxy, hetaryl-1-4C-alkyloxy, O-acetyl, (1-4C-alkyl)amino, di-(1-4C-alkyl)amino, 3-6C-trialkylsilyl, aryl, hetaryl, aryl-1-6C-alkyl or hetaryl-1-6C-alkyl, where R1-R4 is unsubstituted or one or more times substituted by T; R5 : H, (1-6C-alkyl)carbonyl, (1-6C-alkoxy)carbonyl, (1-6C-alkylthio)carbonyl, (1-6C-alkyl)thiocarbonyl, (1-6C-alkoxy)thiocarbonyl, (1-6C-alkylthio)thiocarbonyl, 1-8C-alkyl, 3-6C-cycloalkyl, 2-6C-alkenyl, 1-4C-alkoxy, 1-4C-alkylthio, 1-4C-alkylsulfinyl, 1-4C-alkylsulfonyl, aryl, hetaryl, aryl-1-6C-alkyl, hetaryl-1-6C-alkyl or -(C=X)NR7R7a; R6 : H, (1-6C-alkyl)carbonyl, (1-6C-alkoxy)carbonyl, (1-6C-alkylthio)carbonyl, (1-6C-alkyl)thiocarbonyl, (1-6C-alkoxy)thiocarbonyl, (1-6C-alkylthio)thiocarbonyl, 1-8C-alkyl, 3-6C-cycloalkyl, 2-6C-alkenyl, 1-4C-alkylsulfinyl, 1-4C-alkylsulfonyl, aryl, hetaryl, aryl-1-6C-alkyl, hetaryl-1-6C-alkyl or -(C=X)NR7R7a, where R5 and R6 are unsubstituted or one or more times substituted by T; T : halo, cyano, 1-6C-alkyl, 3-8C-cycloalkyl, 1-4C-alkoxy, 1-4C-alkylthio, 1-4C-alkylsulfinyl, 1-4C-alkylsulfonyl, 1-4C-haloalkyl, 1-4C-haloalkoxy, 1-4C-haloalkylthio, (1-4C-alkyl)amino, di-(1-4C-alkyl)amino, aryl or hetaryl; R7 : 1-6C-alkyl, 3-6C-cycloalkyl, 1-6C-alkoxy, 1-6C-haloalkyl, 1-6C-haloalkoxy, aryl or hetaryl (all unsubstituted or one or more times substituted by halo, cyano, nitro, 1-6C-alkyl, 3-6C-cycloalkyl, 1-6C-alkoxy, 1-6C-haloalkyl or 1-6C-haloalkoxy); R7a : H or R7; and X : O or S. Where: R5, R6 together are not for phenylbutyl and hydrogen, if R1 is methoxy; and R1-R4 are not simultaneously hydrogen, if R5 and R6 are hydrogen. Independent claims are included for: (1) composition comprising (I) and nitrogen- or phosphorus-containing salt compound of formula (((R11-D1 +>(R8)(R10)-R9) m) (R12(m-))) (IX) and/or at least one penetration promoter comprising alkoxy compound of formula (R-O-(-AO) v-R1a) (X); and (2) the preparation of (I). D1 : N or P; R8-R11 : H, 1-8C-alkyl (optionally substituted by halo, nitro or cyano) or 1-8C-alkylene (one or more times unsaturated, optionally substituted by halo, nitro or cyano); R12 : inorganic or organic anion; m : 1-4; R : 4-20C-alkyl; R1a : H, methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, tert-butyl, n-pentyl or n-hexyl; AO : ethylene oxide, propylene oxide and/or butylene oxide; and v : 2-30. [Image] - ACTIVITY : Insecticide; Acaricide; Arachnicide; Anthelmintic; Nematocide; Molluscicide. - MECHANISM OF ACTION : None given.The salt of formula (i) compound and formula (i) compoundwhereinr 1, r 2, r 3and r 4be selected from independently of one another: hydrogen, halogen, formamyl, thiocarbamoyl, nitro, cyanic acid, hydroxyl, sf 5, c 1-c 6alkyl, c 2-c 6thiazolinyl, c 2-c 6alkynyl, c 3-c 6naphthenic base, c 3-c 6naphthenic base-c 1-c 4alkyl, c 1-c 4alkylthio, c 1-c 4alkyl sulphinyl, c 1-c 4alkyl sulphonyl, c 1-c 4alkyl-carbonyl, c 1-c 6alkoxyl group, c 1-c 6alkoxy carbonyl, c 3-c 6thiazolinyl oxygen base, c 3-c 6cycloalkyl oxy, c 3-c 6cycloalkyl oxy-c 1-c 4alkyl, c 1-c 4alkoxy-c 1-c 4alkyl, aryloxy, heteroaryloxy, aryl-c 1-c 4alkyl oxy, heteroaryl-c 1-c 4alkyl oxy, o-ethanoyl, (c 1-c 4alkyl) amino, two-(c 1-c 4alkyl) amino, c 3-c 6trialkylsilkl, aryl, heteroaryl, aryl-c 1-c 6alkyl and heteroaryl-c 1-c 6alkyl, wherein these groups can not be substituted maybe can have one, two or more are selected from following group: halogen, cyanic acid, c 1-c 6alkyl, c 3-c 8naphthenic base, c 1-c 4alkoxyl group, c 1-c 4alkylthio, c 1-c 4alkyl sulphinyl, c 1-c 4alkyl sulphonyl, c 1-c 4haloalkyl, c 1-c 4halogenated alkoxy, c 1-c 4halogenated alkylthio, (c 1-c 4alkyl) amino, two-(c 1-c 4alkyl) amino, aryl and heteroaryl; r 5be selected from hydrogen, (c 1-c 6alkyl) carbonyl, (c 1-c 6alkoxyl group) carbonyl, (c 1-c 6alkylthio) carbonyl, (c 1-c 6alkyl) thiocarbonyl, (c 1-c 6alkoxyl group) thiocarbonyl, (c 1-c 6alkylthio) thiocarbonyl, c 1-c 8alkyl, c 3-c 6naphthenic base, c 2-c 6thiazolinyl, c 1-c 4alkoxyl group, c 1-c 4alkylthio, c 1-c 4alkyl sulphinyl, c 1-c 4alkyl sulphonyl, aryl, heteroaryl, aryl-c 1-c 6alkyl, heteroaryl-c 1-c 6alkyl and-(c=x) nr 7r 7 ', wherein these groups can not be substituted maybe can have one, two or more are selected from following group:halogen, cyanic acid, c 1-c 6alkyl, c 3-c 8naphthenic base, c 1-c 4alkoxyl group, c 1-c 4alkylthio, c 1-c 4alkyl sulphinyl, c 1-c 4alkyl sulphonyl, c 1-c 4haloalkyl, c 1-c 4halogenated alkoxy, c 1-c 4halogenated alkylthio, (c 1-c 4alkyl) amino, two-(c 1-c 4alkyl) amino, aryl and heteroaryl; r 6be selected from hydrogen, (c 1-c 6alkyl) carbonyl, (c 1-c 6alkoxyl group) carbonyl, (c 1-c 6alkylthio) carbonyl, (c 1-c 6alkyl) thiocarbonyl, (c 1-c 6alkoxyl group) thiocarbonyl, (c 1-c 6alkylthio) thiocarbonyl, c 1-c 8alkyl, c 3-c 6naphthenic base, c 2-c 6thiazolinyl, c 1-c 4alkyl sulphinyl, c 1-c 4alkyl sulphonyl, aryl, heteroaryl, aryl-c 1-c 6alkyl, heteroaryl-c 1-c 6alkyl and-(c=x) nr 7r 7 ', wherein these groups can not be substituted maybe can have one, two or more are selected from following group:halogen, cyanic acid, c 1-c 6alkyl, c 3-c 8naphthenic base, c 1-c 4alkoxyl group, c 1-c 4alkylthio, c 1-c 4alkyl sulphinyl, c 1-c 4alkyl sulphonyl, c 1-c 4haloalkyl, c 1-c 4halogenated alkoxy, c 1-c 4halogenated alkylthio, (c 1-c 4alkyl) amino, two-(c 1-c 4alkyl) amino, aryl and heteroaryl; if r wherein 1be methoxyl group, r then 5, r 6be not phenyl butyl together; if r wherein 5and r 6hydrogen, then r respectively do for oneself 1, r 2, r 3, r 4group is not hydrogen entirely; r 7be selected from c 1-c 6alkyl, c 3-c 6naphthenic base, c 1-c 6alkoxyl group, c 1-c 6haloalkyl, c 1-c 6halogenated alkoxy, aryl, heteroaryl, wherein these groups can not be substituted maybe can have one, two or more are selected from following group:halogen, cyanic acid, nitro, c 1-c 6alkyl, c 3-c 6naphthenic base, c 1-c 6alkoxyl group, c 1-c 6haloalkyl, c 1-c 6halogenated alkoxy; r 7 'be selected from hydrogen, c 1-c 6alkyl, c 3-c 6naphthenic base, c 1-c 6alkoxyl group, c 1-c 6haloalkyl, c 1-c 6halogenated alkoxy, aryl, heteroaryl, wherein these groups can not be substituted maybe can have one, two or more are selected from following group:halogen, cyanic acid, nitro, c 1-c 6alkyl, c 3-c 6naphthenic base, c 1-c 6alkoxyl group, c 1-c 6haloalkyl, c 1-c 6halogenated alkoxy; x is o, s.
살해충제로서의 4-아미노-1,2,3-벤족사티아진 유도체본 발명은 하기 화학식 (I)의 신규 벤족사티아진 유도체, 다수의 그의 제조방법, 및 침투제 및/또는 암모늄 또는 포스포늄 염과 같은 추가의 성분들과 배합된 살충제 및/또는 살비제로서의 그의 용도에 관한 것이다: 상기 식에서, R1, R2, R3, R4, R5 및 R6은 각각 명세서에 언급된 의미를 가진다.하기 화학식 (I)의 화합물 및 그의 염:[이미지]상기 식에서,R1, R2, R3 및 R4는 각각 독립적으로 수소, 할로겐, 카바모일, 티오카바모일, 니트로, 시아노, 하이드록실, SF5, C1-C6-알킬, C2-C6-알케닐, C2-C6-알키닐, C3-C6-사이클로알킬, C3-C6-사이클로알킬-C1-C4-알킬, C1-C4-알킬티오, C1-C4-알킬설피닐, C1-C4-알킬설포닐, C1-C4-알킬카보닐, C1-C6-알콕시, C1-C6-알콕시카보닐, C3-C6-알케닐옥시, C3-C6-사이클로알킬옥시, C3-C6-사이클로알킬옥시-C1-C4-알킬, C1-C4-알콕시-C1-C4-알킬, 아릴옥시, 헤트아릴옥시, 아릴-C1-C4-알킬옥시, 헤트아릴-C1-C4-알킬옥시, O-아세틸, (C1-C4-알킬)아미노, 디-(C1-C4-알킬)아미노, C3-C6-트리알킬실릴, 아릴, 헤트아릴, 아릴-C1-C6-알킬 및 헤트아릴-C1-C6-알킬로 구성된 그룹중에서 선택되고,여기서 상기 래디칼들은 비치환될 수 있거나, 할로겐, 시아노, C1-C6-알킬, C3-C8-사이클로알킬, C1-C4-알콕시, C1-C4-알킬티오, C1-C4-알킬설피닐, C1-C4-알킬설포닐, C1-C4-할로알킬, C1-C4-할로알콕시, C1-C4-할로알킬티오, (C1-C4-알킬)아미노, 디-(C1-C4-알킬)아미노, 아릴 및 헤트아릴로 구성된 그룹중에서 선택된 1, 2 또는 그 이상의 래디칼을 가질 수 있으며; R5는 수소, (C1-C6-알킬)카보닐, (C1-C6-알콕시)카보닐, (C1-C6-알킬티오)카보닐, (C1-C6-알킬)티오카보닐, (C1-C6-알콕시)티오카보닐, (C1-C6-알킬티오)티오카보닐, C1-C8-알킬, C3-C6-사이클로알킬, C2-C6-알케닐, C1-C4-알콕시, C1-C4-알킬티오, C1-C4-알킬설피닐, C1-C4-알킬설포닐, 아릴, 헤트아릴, 아릴-C1-C6-알킬, 헤트아릴-C1-C6-알킬 및 -(C=X)NR7R7'로 구성된 그룹중에서 선택되고,여기서 상기 래디칼들은 비치환될 수 있거나, 할로겐, 시아노, C1-C6-알킬, C3-C8-사이클로알킬, C1-C4-알콕시, C1-C4-알킬티오, C1-C4-알킬설피닐, C1-C4-알킬설포닐, C1-C4-할로알킬, C1-C4-할로알콕시, C1-C4-할로알킬티오, (C1-C4-알킬)아미노, 디-(C1-C4-알킬)아미노, 아릴 및 헤트아릴로 구성된 그룹중에서 선택된 1, 2 또는 그 이상의 래디칼을 가질 수 있으며; R6은 수소, (C1-C6-알킬)카보닐, (C1-C6-알콕시)카보닐, (C1-C6-알킬티오)카보닐, (C1-C6-알킬)티오카보닐, (C1-C6-알콕시)티오카보닐, (C1-C6-알킬티오)티오카보닐, C1-C8-알킬, C3-C6-사이클로알킬, C2-C6-알케닐, C1-C4-알킬설피닐, C1-C4-알킬설포닐, 아릴, 헤트아릴, 아릴-C1-C6-알킬, 헤트아릴-C1-C6-알킬 및 -(C=X)NR7R7'로 구성된 그룹중에서 선택되고,여기서 상기 래디칼들은 비치환될 수 있거나, 할로겐, 시아노, C1-C6-알킬, C3-C8-사이클로알킬, C1-C4-알콕시, C1-C4-알킬티오, C1-C4-알킬설피닐, C1-C4-알킬설포닐, C1-C4-할로알킬, C1-C4-할로알콕시, C1-C4-할로알킬티오, (C1-C4-알킬)아미노, 디-(C1-C4-알킬)아미노, 아릴 및 헤트아릴로 구성된 그룹중에서 선택된 1, 2 또는 그 이상의 래디칼을 가질 수 있으며; R1이 메톡시이면, R5, R6는 동시에 페닐부틸 및 수소일 수 없고; R5 및 R6이 수소이면 R1, R2, R3, R4 래디칼이 모두 수소일 수는 없으며;R7은 C1-C6-알킬, C3-C6-사이클로알킬, C1-C6-알콕시, C1-C6-할로알킬, C1-C6-할로알콕시, 아릴 및 헤트아릴로 구성된 그룹중에서 선택되고,여기서 상기 래디칼들은 비치환될 수 있거나, 할로겐, 시아노, 니트로, C1-C6-알킬, C3-C6-사이클로알킬, C1-C6-알콕시, C1-C6-할로알킬 및 C1-C6-할로알콕시로 구성된 그룹중에서 선택된 1, 2 또는 그 이상의 래디칼을 가질 수 있으며; R7'는 수소, C1-C6-알킬, C3-C6-사이클로알킬, C1-C6-알콕시, C1-C6-할로알킬, C1-C6-할로알콕시, 아릴 및 헤트아릴로 구성된 그룹중에서 선택되고,여기서 상기 래디칼들은 비치환될 수 있거나, 할로겐, 시아노, 니트로, C1-C6-알킬, C3-C6-사이클로알킬, C1-C6-알콕시, C1-C6-할로알킬 및 C1-C6-할로알콕시로 구성된 그룹중에서 선택된 1, 2 또는 그 이상의 래디칼을 가질 수 있으며; X는 O 또는 S이다.