Heterocyclic derivatives as pest control agentsThe present invention relates to novel compounds of formula (I) wherein Q represents a heteroaromatic 9-or 12-membered fused bicyclic or tricyclic ring system selected from the series Q1 to Q5, and R1、R2、R3、R4、R5、R6And n has the meaning given herein. The invention also relates to the use thereof as acaricides and/or insecticides for controlling animal pests.A compound of formula (i)whereinr1is represented by (c)1-c6) alkyl radicals, (c)1-c6) -haloalkyl, (c)2-c6) -alkenyl, (c)2-c6) -haloalkenyl, (c)2-c6) -alkynyl, (c)2-c6) -haloalkynyl, (c)3-c8) -cycloalkyl, halo- (c)3-c8) -cycloalkyl, (c)3-c6) -cycloalkyl- (c)1-c6) alkyl radicals, (c)3-c6) -cycloalkyl- (c)1-c6) -haloalkyl, (c)1-c6) -alkyl- (c)3-c8) -cycloalkyl, (c)1-c6) -haloalkyl- (c)3-c8) -cycloalkyl, (c)3-c8) -cycloalkyl- (c)3-c8) -cycloalkyl, spiro- (c)3-c8) -cycloalkyl- (c)3-c8) -cycloalkyl, (c)4-c12) -bicycloalkyl, (c)1-c6) cyanoalkyl, (c)1-c6) -alkoxy- (c)1-c6) alkyl radicals, (c)2-c6) -cyanoalkenyl, (c)3-c6) -cycloalkyl- (c)2-c6) -alkenyl, (c)2-c6) -cyanoalkynyl, (c)3-c6) -cycloalkyl- (c)2-c6) -alkynyl, (c)1-c6) -haloalkoxy- (c)1-c6) alkyl radicals, (c)2-c6) -alkenyloxy- (c)1-c6) alkyl radicals, (c)2-c6) -haloalkenyloxy- (c)1-c6) alkyl radicals, (c)2-c6) -alkynyloxy- (c)1-c4) alkyl radicals, (c)2-c6) -haloalkynyloxy- (c)1-c6) alkyl radicals, (c)1-c6) -alkylthio- (c)1-c6) alkyl radicals, (c)1-c6) -alkylsulfinyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkylsulfonyl- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkylthio- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkylsulfinyl- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkylsulfonyl- (c)1-c6) alkyl or tri- (c)1-c6) -an alkylsilyl group,r2、r3independently of one another, hydrogen, halogen, (c)1-c6) alkyl radicals, (c)1-c6) -haloalkyl, (c)1-c6) -alkoxy, (c)1-c6) -haloalkoxy, (c)1-c6) -haloalkylthio, (c)1-c6) -haloalkylsulfinyl, (c)1-c6) -haloalkylsulfonyl, oris represented by (c)1-c6) -haloalkyl- (c)3-c8) -cycloalkyl, (c)1-c6) -cyanoalkyl- (c)3-c8) -cycloalkyl, (c)1-c6) -haloalkyl- (c)3-c8) -cyanocycloalkyl, (c)1-c6) -haloalkyl- (c)3-c8) -halocycloalkyl optionally substituted by (c)1-c6) -cyano- (c) mono-or polysubstituted with alkyl or halogen3-c6) -cycloalkyl, optionally mono-or polysubstituted by cyano or halogenspiro- (c) of3-c8) -cycloalkyl- (c)3-c8) -cycloalkyl or (c) optionally mono-or polysubstituted by cyano or halogen4-c12) -a bicycloalkyl group,wherein the radical r2or r3one of them must be selected from (c)1-c6) -haloalkyl- (c)3-c8) -cycloalkyl, (c)1-c6) -cyanoalkyl- (c)3-c8) -cycloalkyl, (c)1-c6) -haloalkyl- (c)3-c8) -cyanocycloalkyl, (c)1-c6) -haloalkyl- (c)3-c8) -halocycloalkyl optionally substituted by (c)1-c6) -cyano- (c) mono-or polysubstituted with alkyl or halogen3-c6) -cycloalkyl, spiro- (c) optionally mono-or polysubstituted with cyano or halogen3-c8) -cycloalkyl- (c)3-c8) -cycloalkyl or (c) optionally mono-or polysubstituted by cyano or halogen4-c12) -a bicycloalkyl group,n represents 0,1 or 2,q represents a heteroaromatic 9-or 12-membered fused bicyclic or tricyclic ring system selected from q1 to q5,whereinr4is represented by (c)1-c4) alkyl radicals, (c)1-c4) -haloalkyl, (c)1-c4) cyanoalkyl, (c)1-c4) -hydroxyalkyl, (c)1-c4) -alkoxy- (c)1-c4) alkyl radicals, (c)1-c4) -haloalkoxy- (c)1-c4) alkyl radicals, (c)2-c4) -alkenyl, (c)2-c4) -alkenyloxy- (c)1-c4) alkyl radicals, (c)2-c4) -haloalkenyloxy- (c)1-c4) alkyl radicals, (c)2-c4) -haloalkenyl,(c2-c4) -cyanoalkenyl, (c)2-c4) -alkynyl, (c)2-c4) -alkynyloxy- (c)1-c4) alkyl radicals, (c)2-c4) -haloalkynyl, (c)3-c6) -cycloalkyl, (c)3-c6) -cycloalkyl- (c)3-c6) -cycloalkyl, (c)1-c4) -alkyl- (c)3-c6) -cycloalkyl, halo- (c)3-c6) -cycloalkyl, (c)1-c4) -alkylthio- (c)1-c4) alkyl radicals, (c)1-c4) -alkylsulfinyl- (c)1-c4) alkyl radicals, (c)1-c4) -alkylsulfonyl- (c)1-c4) -alkyl or (c)1-c4) -alkylcarbonyl- (c)1-c4) -an alkyl group,r5is represented by (c)1-c6) alkyl radicals, (c)2-c6) -alkenyl, (c)2-c6) -alkynyl, (c)1-c6) -haloalkyl, (c)2-c6) -haloalkenyl, (c)2-c6) -haloalkynyl, (c)3-c8) -cycloalkyl or halo- (c)3-c8) -a cycloalkyl group,r6represents hydrogen, cyano, halogen, (c)1-c4) alkyl radicals, (c)1-c4) -haloalkyl, (c)2-c4) -alkenyl, (c)2-c4) -haloalkenyl, (c)2-c4) -alkynyl, (c)2-c4) -haloalkynyl, (c)3-c6) -cycloalkyl, (c)3-c6) -cycloalkyl- (c)3-c6) -cycloalkyl, (c)1-c4) -alkyl- (c)3-c6) -cycloalkyl, (c)1-c4) -alkoxy, (c)1-c4) -haloalkoxy, (c)1-c4) -alkoxyimino group, (c)1-c4) alkylthio group(s), (c)1-c4) -haloalkylthio, (c)1-c4) -alkylsulfinyl, (c)1-c4) -haloalkylenessulfonyl group, (c)1-c4) -alkylsulfonyl, (c)1-c4) -haloalkylsulfonyl, (c)1-c4) -alkylsulfonyloxy, (c)1-c4) -alkylcarbonyl, (c)1-c4) -haloalkylcarbonyl, aminocarbonyl, (c)1-c4) -alkylaminocarbonyl, di- (c)1-c4) -alkylaminocarbonyl, (c)1-c4) -alkylsulfonylamino, (c)1-c4) alkylamino, di- (c)1-c4) alkylamino, aminosulfonyl, (c)1-c4) an alkylaminosulfonyl or di- (c)1-c4) an alkylaminosulfonyl radical, anda represents n (nitrogen) or c (h).
해충 방제제로서의 헤테로시클렌 유도체본 발명은 하기 화학식 (I)의 신규 화합물에 관한 것이며, 여기서 Q는 시리즈 하기 Q1 내지 Q5로부터의 헤테로방향족 9-원 또는 12-원 융합 비시클릭 또는 트리시클릭 고리계를 나타내고, R1, R2, R3, R4, R5, R6 및 n은 상기 주어진 의미를 갖는다. 본 발명은 또한 동물 해충 방제를 위한 살진드기제 및/또는 살곤충제로서의 그의 용도에 관한 것이다.[이미지][이미지]하기 화학식 (I)의 화합물.[이미지]여기서R1은 (C1-C6)-알킬, (C1-C6)-할로알킬, (C2-C6)-알케닐, (C2-C6)-할로알케닐, (C2-C6)-알키닐, (C2-C6)-할로알키닐, (C3-C8)-시클로알킬, 할로-(C3-C8)-시클로알킬, (C3-C6)-시클로알킬-(C1-C6)-알킬, (C3-C6)-시클로알킬-(C1-C6)-할로알킬, (C1-C6)-알킬-(C3-C8)-시클로알킬, (C1-C6)-할로알킬-(C3-C8)-시클로알킬, (C3-C8)-시클로알킬-(C3-C8)-시클로알킬, 스피로-(C3-C8)-시클로알킬-(C3-C8)-시클로알킬, (C4-C12)-비시클로알킬, (C1-C6)-시아노알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C2-C6)-시아노알케닐, (C3-C6)-시클로알킬-(C2-C6)-알케닐, (C2-C6)-시아노알키닐, (C3-C6)-시클로알킬-(C2-C6)-알키닐, (C1-C6)-할로알콕시-(C1-C6)-알킬, (C2-C6)-알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐옥시-(C1-C6)-알킬, (C2-C6)-알키닐옥시-(C1-C4)-알킬, (C2-C6)-할로알키닐옥시-(C1-C6)-알킬, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-할로알킬티오-(C1-C6)-알킬, (C1-C6)-할로알킬술피닐-(C1-C6)-알킬, (C1-C6)-할로알킬술포닐-(C1-C6)-알킬 또는 트리-(C1-C6)-알킬실릴을 나타내고,R2, R3은 서로 독립적으로 수소, 할로겐, (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-알콕시, (C1-C6)-할로알콕시, (C1-C6)-할로알킬티오, (C1-C6)-할로알킬술피닐, (C1-C6)-할로알킬술포닐을 나타내거나, 또는(C1-C6)-할로알킬-(C3-C8)-시클로알킬, (C1-C6)-시아노알킬-(C3-C8)-시클로알킬, (C1-C6)-할로알킬-(C3-C8)-시아노시클로알킬, (C1-C6)-할로알킬-(C3-C8)-할로시클로알킬, (C1-C6)-알킬 또는 할로겐에 의해 임의로 일치환 또는 다치환된 시아노-(C3-C6)-시클로알킬, 시아노 또는 할로겐에 의해 임의로 일치환 또는 다치환된 스피로-(C3-C8)-시클로알킬-(C3-C8)-시클로알킬 또는 시아노 또는 할로겐에 의해 임의로 일치환 또는 다치환된 (C4-C12)-비시클로알킬을 나타내고,여기서 라디칼 R2 또는 R3 중 1개는 (C1-C6)-할로알킬-(C3-C8)-시클로알킬, (C1-C6)-시아노알킬-(C3-C8)-시클로알킬, (C1-C6)-할로알킬-(C3-C8)-시아노시클로알킬, (C1-C6)-할로알킬-(C3-C8)-할로시클로알킬, (C1-C6)-알킬 또는 할로겐에 의해 임의로 일치환 또는 다치환된 시아노-(C3-C6)-시클로알킬, 시아노 또는 할로겐에 의해 임의로 일치환 또는 다치환된 스피로-(C3-C8)-시클로알킬-(C3-C8)-시클로알킬 또는 시아노 또는 할로겐에 의해 임의로 일치환 또는 다치환된 (C4-C12)-비시클로알킬로부터 선택되어야 하고,n은 0, 1 또는 2를 나타내고,Q는 하기 Q1 내지 Q5로 이루어진 군으로부터의 헤테로방향족 9-원 또는 12-원 융합된 비시클릭 또는 트리시클릭 고리계를 나타내고:[이미지]여기서R4는 (C1-C4)-알킬, (C1-C4)-할로알킬, (C1-C4)-시아노알킬, (C1-C4)-히드록시알킬, (C1-C4)-알콕시-(C1-C4)-알킬, (C1-C4)-할로알콕시-(C1-C4)-알킬, (C2-C4)-알케닐, (C2-C4)-알케닐옥시-(C1-C4)-알킬, (C2-C4)-할로알케닐옥시-(C1-C4)-알킬, (C2-C4)-할로알케닐, (C2-C4)-시아노알케닐, (C2-C4)-알키닐, (C2-C4)-알키닐옥시-(C1-C4)-알킬, (C2-C4)-할로알키닐, (C3-C6)-시클로알킬, (C3-C6)-시클로알킬-(C3-C6)-시클로알킬, (C1-C4)-알킬-(C3-C6)-시클로알킬, 할로-(C3-C6)-시클로알킬, (C1-C4)-알킬티오-(C1-C4)-알킬, (C1-C4)-알킬술피닐-(C1-C4)-알킬, (C1-C4)-알킬술포닐-(C1-C4)-알킬 또는 (C1-C4)-알킬카르보닐-(C1-C4)-알킬을 나타내고,R5는 (C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-알키닐, (C1-C6)-할로알킬, (C2-C6)-할로알케닐, (C2-C6)-할로알키닐, (C3-C8)-시클로알킬 또는 할로-(C3-C8)-시클로알킬을 나타내고,R6은 수소, 시아노, 할로겐, (C1-C4)-알킬, (C1-C4)-할로알킬, (C2-C4)-알케닐, (C2-C4)-할로알케닐, (C2-C4)-알키닐, (C2-C4)-할로알키닐, (C3-C6)-시클로알킬, (C3-C6)-시클로알킬-(C3-C6)-시클로알킬, (C1-C4)-알킬-(C3-C6)-시클로알킬, (C1-C4)-알콕시, (C1-C4)-할로알콕시, (C1-C4)-알콕시이미노, (C1-C4)-알킬티오, (C1-C4)-할로알킬티오, (C1-C4)-알킬술피닐, (C1-C4)-할로알킬술피닐, (C1-C4)-알킬술포닐, (C1-C4)-할로알킬술포닐, (C1-C4)-알킬술포닐옥시, (C1-C4)-알킬카르보닐, (C1-C4)-할로알킬카르보닐, 아미노카르보닐, (C1-C4)-알킬아미노카르보닐, 디-(C1-C4)-알킬아미노카르보닐, (C1-C4)-알킬술포닐아미노, (C1-C4)-알킬아미노, 디-(C1-C4)-알킬아미노, 아미노술포닐, (C1-C4)-알킬아미노술포닐 또는 디-(C1-C4)-알킬아미노술포닐을 나타내고,A는 N (질소) 또는 C(H)를 나타낸다.