HETEROCYCLENE DERIVATIVES AS PEST CONTROL AGENTSThe present invention relates to the compounds of new formula (I), wherein R1、R2、R3、A1, X and n there is meaning shown in specification, the method and intermediate for being used to prevent the purposes of animal pest as acaricide and/or insecticide and preparing for itThe compound of formula (i)whereina1represent nitrogen ,=n+(o-)-or=c (r4)-,r1represent (c1-c6)-alkyl, (c1-c6)-halogenated alkyl, (c1-c6)-cyanoalkyl, (c1-c6)-hydroxy alkyl, (c1- c6)-alkoxy-(c1-c6)-alkyl, (c1-c6)-halogenated alkoxy-(c1-c6)-alkyl, (c2-c6)-alkenyl, (c2-c6)-alkene oxygen base-(c1-c6)-alkyl, (c2-c6)-haloalkenyloxy-(c1-c6)-alkyl, (c2-c6)-halogenated alkenyl, (c2-c6)-cyano alkene base, (c2-c6)-alkynyl, (c2-c6)-alkynyloxy group-(c1-c6)-alkyl, (c2-c6)-halogenated alkynyloxy group-(c1-c6)-alkyl, (c2- c6)-halo alkynyl, (c2-c6)-cyano alkynyl, (c3-c8)-naphthenic base, (c3-c8)-naphthenic base-(c3-c8)-naphthenic base, (c1- c6)-alkyl-(c3-c8)-naphthenic base, halogenated-(c3-c8) naphthenic base, amino, (c1-c6)-alkyl amino, two-(c1-c6)-alkyl amino, (c3-c8)-cycloalkyl amino, (c1-c6)-alkyl-carbonyl-amino, (c1-c6)-alkylthio group-(c1-c6)-alkyl, (c1- c6)-halogenated alkylthio-(c1-c6)-alkyl, (c1-c6)-alkyl sulphinyl-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl is sub- sulfonyl-(c1-c6)-alkyl, (c1-c6)-alkyl sulphonyl-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl sulfonyl-(c1- c6)-alkyl, (c1-c6)-alkoxy-(c1-c6)-alkylthio group-(c1-c6)-alkyl, (c1-c6)-alkoxy-(c1-c6)-alkyl is sub- sulfonyl-(c1-c6)-alkyl, (c1-c6)-alkoxy-(c1-c6)-alkyl sulphonyl-(c1-c6)-alkyl, (c1-c6)-alkyl carbonyl-(c1-c6)-alkyl, (c1-c6)-halogenated alkyl carbonyl-(c1-c6)-alkyl, (c1-c6)-alkoxy carbonyl-(c1-c6)- alkyl, (c1-c6)-halo alkoxy carbonyl-(c1-c6)-alkyl, (c1-c6)-alkyl sulfonyl-amino, amino-sulfonyl-(c1- c6)-alkyl, (c1-c6)-alkyl amino sulfonyl-(c1-c6)-alkyl, two-(c1-c6)-alkyl amino sulfonyl-(c1-c6)- alkyl,or represent (c1-c6)-alkyl, (c1-c6)-alkoxy, (c2-c6)-alkenyl, (c2-c6)-alkynyl, (c3-c8)-naphthenic base, it is respectively optionally monosubstituted or polysubstituted by the identical or different substituent group selected from aryl, heteroaryl and heterocycle, wherein virtue base, heteroaryl and heterocycle can be respectively optionally monosubstituted or polysubstituted by identical or different substituent group selected from the following：halogen element, cyano, nitro, hydroxyl, amino, carboxyl, carbamoyl, amino-sulfonyl, (c1-c6)-alkyl, (c3-c6)-naphthenic base, (c1-c6)-alkoxy, (c1-c6)-halogenated alkyl, (c1-c6)-halogenated alkoxy, (c1-c6)-alkylthio group, (c1-c6)-alkyl is sub- sulfonyl, (c1-c6)-alkyl sulphonyl, (c1-c6)-alkyl sulfide imino group ((c1-c6)-alkylsulphimino)、(c1-c6)- alkyl sulfide imino group-(c1-c6)-alkyl, (c1-c6)-alkyl sulfide imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkyl sulfoxide imino group ((c1-c6)-alkylsulphoximino), (c1-c6)-alkyl sulfoxide imino group-(c1-c6)-alkyl, (c1-c6)- alkyl sulfoxide imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkoxy carbonyl, (c1-c6)-alkyl-carbonyl, (c3-c6)-three alkane base silicyl and benzyl, orr1aryl, heteroaryl or heterocycle are represented, it is respectively optionally monosubstituted by identical or different substituent group selected from the following or it is polysubstituted：halogen, cyano, nitro, hydroxyl, amino, carboxyl, carbamoyl, (c1-c6)-alkyl, (c3-c8)-naphthenic base, (c1-c6)-alkoxy, (c1-c6)-halogenated alkyl, (c1-c6)-halogenated alkoxy, (c1-c6)-alkylthio group, (c1-c6)-alkyl is sub- sulfonyl, (c1-c6)-alkyl sulphonyl, (c1-c6)-alkyl sulfide imino group, (c1-c6)-alkyl sulfide imino group-(c1-c6)-alkane base, (c1-c6)-alkyl sulfide imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkyl sulfoxide imino group, (c1-c6)-alkyl sulfoxide imino group-(c1-c6)-alkyl, (c1-c6)-alkyl sulfoxide imino group-(c2-c6)-alkyl-carbonyl, (c1-c6)-alkoxy carbonyl, (c1-c6)-alkyl-carbonyl, (c3-c6)-trialkylsilkl, (=o) (only in the case of heterocycle) and (=o)2(only exist in the case of heterocycle),r2the heterocycle or heteroaromatic 8 yuan, 9 yuan, 10 yuan, 11 yuan or 12 yuan of condensed-bicyclic member ring systems of fractional saturation or saturation are represented, at least one carbonyl and/or the wherein described member ring systems wherein optionally may be present optionally by identical or different substituent group list substitution is polysubstituted, and the wherein described substituent group can be selected from independently of one another：cyano, carboxyl, halogen, nitro, acetyl group, hydroxyl base, amino, scn, three-(c1-c6)-aikylsilyl groups, (c1-c6)-alkyl, (c1-c6)-halogenated alkyl, (c1-c6)-cyano alkane base, (c1-c6)-hydroxy alkyl, hydroxycarbonyl group-(c1-c6)-alkoxy, (c1-c6)-alkoxy carbonyl-(c1-c6)-alkyl, (c1- c6)-alkoxy-(c1-c6)-alkyl, (c2-c6)-alkenyl, (c2-c6)-halogenated alkenyl, (c2-c6)-cyano alkenyl, (c2-c6)-alkynes base, (c2-c6)-halo alkynyl, (c2-c6)-cyano alkynyl, (c3-c6)-naphthenic base, (c3-c6)-naphthenic base-(c3-c6)-cycloalkanes base, (c1-c4)-alkyl-(c3-c6)-naphthenic base, (c1-c6)-alkoxy, (c1-c6)-halogenated alkoxy, (c1-c6)-cyano alkane oxygroup, (c1-c6)-alkoxy carbonyl-(c1-c6)-alkoxy, (c1-c6)-alkoxy-(c1-c6)-alkoxy, (c1-c6)-alkane oxygroup imino group ,-n=c (h)-o (c1-c6)-alkyl ,-c (h)=n-o (c1-c6)-alkyl, (c1-c6)-halogenated alkyl-(c1- c6)-alkoximino, (c1-c6)-alkylthio group, (c1-c6)-h...
해충 방제제로서의 헤테로사이클렌 유도체본 발명은 신규의 화학식 (I) 의 화합물:[이미지] (식 중, R1, R2, R3, A1, X 및 n 은 명세서에서 나타내는 의미를 가진다), 동물 해충을 방제하기 위한 살비제 및/또는 살곤충제로서의 이의 용도, 및 이의 제조를 위한 방법 및 중간체 생성물에 관한 것이다.화학식 (I) 의 화합물:[이미지][식 중,A1 은 질소, =N+(O-)- 또는 =C(R4)- 를 나타내고,R1 은 (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-히드록시알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C1-C6)-할로알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C3-C8)-시클로알킬, (C3-C8)-시클로알킬-(C3-C8)-시클로알킬, (C1-C6)-알킬-(C3-C8)-시클로알킬, 할로-(C3-C8)시클로알킬, 아미노, (C1-C6)-알킬아미노, 디-(C1-C6)-알킬-아미노, (C3-C8)-시클로알킬아미노, (C1-C6)-알킬카르보닐아미노, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-할로알킬티오-(C1-C6)-알킬, (C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-할로알킬술피닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-할로알킬술포닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-알킬카르보닐-(C1-C6)-알킬, (C1-C6)-할로알킬카르보닐-(C1-C6)-알킬, (C1-C6)-알콕시카르보닐-(C1-C6)-알킬, (C1-C6)-할로알콕시카르보닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐아미노, 아미노술포닐-(C1-C6)-알킬, (C1-C6)-알킬아미노술포닐-(C1-C6)-알킬, 디-(C1-C6)-알킬아미노술포닐-(C1-C6)-알킬을 나타내거나, 또는(C1-C6)-알킬, (C1-C6)-알콕시, (C2-C6)-알케닐, (C2-C6)-알키닐, (C3-C8)-시클로알킬 (이들은 각각 아릴, 헤타릴 및 헤테로시클릴로 이루어진 군으로부터의 동일한 또는 상이한 치환기로 임의로 일- 또는 다치환되고, 아릴, 헤타릴 및 헤테로시클릴은 각각 할로겐, 시아노, 니트로, 히드록시, 아미노, 카르복시, 카르바모일, 아미노술포닐, (C1-C6)-알킬, (C3-C6)-시클로알킬, (C1-C6)-알콕시, (C1-C6)-할로알킬, (C1-C6)-할로알콕시, (C1-C6)-알킬티오, (C1-C6)-알킬술피닐, (C1-C6)-알킬술포닐, (C1-C6)-알킬술피미노, (C1-C6)-알킬술피미노-(C1-C6)-알킬, (C1-C6)-알킬술피미노-(C2-C6)-알킬카르보닐, (C1-C6)-알킬술폭시미노, (C1-C6)-알킬술폭시미노-(C1-C6)-알킬, (C1-C6)-알킬술폭시미노-(C2-C6)-알킬카르보닐, (C1-C6)-알콕시카르보닐, (C1-C6)-알킬카르보닐, (C3-C6)-트리알킬실릴 및 벤질로 이루어진 군으로부터의 동일한 또는 상이한 치환기로 임의로 일- 또는 다치환될 수 있다) 을 나타내고, 또는R1 은 아릴, 헤타릴 또는 헤테로시클릴 (이들은 각각 할로겐, 시아노, 니트로, 히드록시, 아미노, 카르복시, 카르바모일, (C1-C6)-알킬, (C3-C8)-시클로알킬, (C1-C6)-알콕시, (C1-C6)-할로알킬, (C1-C6)-할로알콕시, (C1-C6)-알킬티오, (C1-C6)-알킬술피닐, (C1-C6)-알킬술포닐, (C1-C6)-알킬술피미노, (C1-C6)-알킬술피미노-(C1-C6)-알킬, (C1-C6)-알킬술피미노-(C2-C6)-알킬카르보닐, (C1-C6)-알킬술폭시미노, (C1-C6)-알킬술폭시미노-(C1-C6)-알킬, (C1-C6)-알킬술폭시미노-(C2-C6)-알킬카르보닐, (C1-C6)-알콕시카르보닐, (C1-C6)-알킬카르보닐, (C3-C6)-트리알킬실릴, (=O) (헤테로시클릴의 경우에만) 및 (=O)2 (헤테로시클릴의 경우에만) 로 이루어진 군으로부터의 동일한 또는 상이한 치환기로 임의로 일- 또는 다치환된다) 을 나타내고,R2 는 부분적으로 포화된 또는 포화된 헤테로시클릭 또는 헤테로방향족 8-, 9-, 10-, 11- 또는 12-원 융합 비시클릭 고리계 (임의로 하나 이상의 카르보닐기가 존재할 수 있고, 및/또는 고리계는 동일한 또는 상이한 치환기로 임의로 일- 또는 다치환될 수 있으며, 치환기는 시아노, 카르복시, 할로겐, 니트로, 아세틸, 히드록시, 아미노, SCN, 트리-(C1-C6)-알킬실릴, (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-히드록시알킬, 히드록시카르보닐-(C1-C6)-알콕시, (C1-C6)-알콕시카르보닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C3-C6)-시클로알킬, (C3-C6)-시클로알킬-(C3-C6)-시클로알킬, (C1-C4)-알킬-(C3-C6)-시클로알킬, (C1-C6)-알콕시, (C1-C6)-할로알콕시, (C1-C6)-시아노알콕시, (C1-C6)-알콕시카르보닐-(C1-C6)-알콕시, (C1-C6)-알콕시-(C1-C6)-알콕시, (C1-C6)-알콕시이미노, -N=C(H)-O(C1-C6)-알킬, -C(H)=N-O(C1-C6)-알킬, (C1-C6)-할로알킬-(C1-C6)-알콕시이미노, (C1-C6)-알킬티오, (C1-C6)-할로알킬티오, (C1-C6)-알콕시-(C1-C6)-알킬티오, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알킬술피닐, (C1-C6)-할로알킬술피닐, (C1-C6)-알콕시-(C1-C6)-알킬술피닐, (C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐, (C1-C6)-할로알킬술포닐, (C1-C6)-알콕시-(C1-C6)-알킬술포닐, (C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐옥시, (C1-C6)-알킬카르보닐, (C1-C6)-할로알킬카르보닐, (C1-C6)-알킬카르보닐옥시, (C1-C6)-알콕시카르보닐, (C1-C6)-할로알콕시카르보닐, 아미노카르보닐, (C1-C6)-알킬아미노카르보닐, 디-(C1-C6)-알킬아미노카르보닐, (C2-C6)-알케닐아미노카르보닐, 디-(C2-C6)-알케닐아미노카르보닐, (C3-C8)-시클로알킬아미노카르보닐, (C1-C6)-알킬술포닐아미노, (C1-C6)-알킬아미노, 디-(C1-C6)-알킬아미노, 아미노술포닐, (C1-C6)-알킬아미노술포닐, 디-(C1-C6)-알킬아미노술포닐, (C1-C6)-알킬술폭시미노, 아미노티오카르보닐, (C1-C6)-알킬아미노티오카르보닐, 디-(C1-C6)-알킬아미노티오카르보닐, (C3-C8)-시클로알킬아미노, (C1-C6)-알킬카르보닐아미노로 이루어진 군에서 서로 독립적으로 선택될 수 있다) 를 나타내고,R3 은 수소, 시아노, 할로겐, 니트로, 아세틸, 히드록시, 아미노, SCN, 트리-(C1-C6)-알킬실릴, (C3-C8)-시클로알킬, (C3-C8)-시클로알킬-(C3-C8)-시클로알킬, (C1-C6)-알킬-(C3-C8)-시클로알킬, 할로-(C3-C8)-시클로알킬, (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-히드록시알킬, 히드록시카르보닐-(C1-C6)-알콕시, (C1-C6)-알콕시카르보닐-(C1-C6)-알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C1-C6)-알콕시, (C1-C6)-할로알콕시, (C1-C6)-시아노알콕시, (C1-C6)-알콕시카르보닐-(C1-C6)-알콕시, (C1-C6)-알콕시-(C1-C6)-알콕시, (C1-C6)-알킬히드록시이미노, (C1-C6)-알콕시이미노, (C1-C6)-알킬-(C1-C6)-알콕시이미노, (C1-C6)-할로알킬-(C1-C6)-알콕시이미노, (C1-C6)-알킬티오, (C1-C6)-할로알킬티오, (C1-C6)-알콕시-(C1-C6)-알킬티오, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-알킬술피닐, (C1-C6)-할로알킬술피닐, (C1-C6)-알콕시-(C1-C6)-알킬술피닐, (C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐, (C1-C6)-할로알킬술포닐, (C1-C6)-알콕시-(C1-C6)-알킬술포닐, (C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐옥시, (C1-C6)-알킬카르보닐, (C1-C6)-알킬티오카르보닐, (C1-C6)-할로알킬카르보닐, (C1-C6)-알킬카르보닐옥시, (C1-C6)-알콕시카르보닐, (C1-C6)-할로알콕시카르보닐, 아미노카르보닐, (C1-C6)-알킬아미노카르보닐, (C1-C6)-알킬아미노티오카르보닐, 디-(C1-C6)-알킬아미노카르보닐, 디-(C1-C6)-알킬아미노티오카르보닐, (C2-C6)-알케닐아미노카르보닐, 디-(C2-C6)-알케닐아미노카르보닐, (C3-C8)-시클로알킬아미노카르보닐, (C1-C6)-알킬술포닐아미노, (C1-C6)-알킬아미노, 디-(C1-C6)-알킬아미노, 아미노술포닐, (C1-C6)-알킬아미노술포닐, 디-(C1-C6)-알킬아미노술포닐, (C1-C6)-알킬술폭시미노, 아미노티오카르보닐, (C1-C6)-알킬아미노티오카르보닐, 디-(C1-C6)-알킬아미노티오카르보닐, (C3-C8)-시클로알킬아미노, NHCO-(C1-C6)-알킬 ((C1-C6)-알킬카르보닐아미노) 을 나타내고,아릴 또는 헤타릴 (이들은 각각 동일한 또는 상이한 치환기로 임의로 일- 또는 다치환되고, (헤타릴의 경우) 임의로 하나 이상의 카르보닐기가 존재할 수 있으며, 및/또는 각 경우에 있어서 가능한 치환기는 다음과 같다: 시아노, 카르복시, 할로겐, 니트로, 아세틸, 히드록시, 아미노, SCN, 트리-(C1-C6)-알킬실릴, (C3-C8)-시클로알킬, (C...