Selective heteroaryloxy-acetamide-based herbicidesThe invention relates to novel herbicidal, synergistic active agent combinations which consist of heteroaryloxy acetamides and known herbicidal compounds and/or safeners as listed in the description and which can be used particularly effectively for selective weed control in various crop cultures.Composition comprises the active substance combinations of effective dose, and this mixture is made up of following component(a) heteroaryloxy-acetamide-of general formula (i) whereinar representative randomly by halogen-, c 1-c 4-alkyl-or c 1-c 4the phenyl that-haloalkyl replaces, het represents thiadiazolyl group, and this group is by halogen or by the c that randomly replaced by halogen separately 1-c 4-alkyl or phenyl replace and the r representative has the alkyl of 4 carbon atoms at the most separately, alkenyl or alkynyl,(' the 1st group of reactive compound ') and(b) be selected from one or more compounds in the 2nd group of weed killer herbicide that contains following reactive compound:1h-1,2,4-triazole-3-amine (amrol); 2-[2,4-two chloro-5-(2-third alkynyloxy group)-phenyl]-5,6; 7,8-tetrahydrochysene-1,2; 4-triazol-[4,3-a]-pyridine-3 (2h)-ketone (azoles pyridine alkynes grass), n-(4; 6-dimethoxy-pyrimidine-2-base)-and n '-[1-methyl-4-(2-methyl-2h-tetrazolium-5-yl)-1h-pyrazoles-5-base-sulfonyl]-urea (azimsulfuron), n-benzyl-2-(4-fluoro-3-trifluoromethyl-phenoxy group) butyramide (beflubutamid), n-butyl-n-ethyl-2; 6-dinitro-4-trifluoromethyl-aniline (benfluralin), and 2-[2-[4-(3,6-dihydro-3-methyl-2; 6-dioxo-4-trifluoromethyl-1 (2h)-pyrimidine radicals-phenoxy group] methyl]-5-ethyl-phenoxy group-methyl propionate (benzfendizone), 3-(2-chloro-4-methyl sulphonyl-benzoyl)-4-thiophenyl-two ring-[3.2.1]-xin-3-alkene-2-ketone (benzobicyclon), [1; 1-dimethyl-2-oxo-2-(2-propenyloxy group)]-ethyl 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2h)-pyrimidine radicals)-benzoic ether (butafenacil-allyl); 2-(1-ethoxy imino-propyl group)-3-hydroxyl-5-[2,4,6-trimethyl-3-(1-oxo-butyl)-phenyl]-2-cyclohexene-1-ketone (fourth oxygen cyclic ketones); 2-[1-[(3-chloro-2-acrylic)-oxygen base-imino group]-propyl group]-3-hydroxyl-5-(tetrahydrochysene-2h-pyrans-4-yl)-2-cyclohexene-1-ketone (quinone oximes grass), 2-chloro-3-[2-chloro-5-(1,3; 4,5,6; 7-six hydrogen-1; 3-dioxo-2h-iso-indoles-2-yl)-phenyl]-2-ethyl propionate (cinidon-ethyl), 2-[1-[2-(4-chloro-phenoxy group)]-the amino butyl of propoxyl group]-5-(tetrahydrochysene-2h-thiapyran-3-yl)-1,3-cyclohexanedione (clefoxydim); (e; e)-(+)-2-[1-[[(3-chloro-2-propylene)-the oxygen base]-imino group]-propyl group]-3-hydroxyl-2-cyclohexene-1-ketone (clethodim), 3-chloro-2-[[(5-ethyoxyl-7-fluorine [1,2; 4] triazol [1; 5-c] pyrimidine-2-base-sulfonyl)-amino]-methyl benzoate (the phonetic sulfanilamide (sn) salt of azoles), 2-(1-ethoxy imino butyl)-3-hydroxyl-5-(tetrahydrochysene-2h-thiapyran-3-yl)-2-cyclohexene-1-ketone (cycloxydim), n-(2; 6-two chloro-phenyl)-5-ethyoxyl-7-fluoro-[1; 2,4]-triazol-[1,5-c]-pyrimidine-2-sulfonamide (the phonetic sulfanilamide (sn) of azoles); 2-[1-[(3; 5-two fluoro-phenyl)-amino-carbonyl-hydrazono-]-ethyl]-pyridine-3-carboxylic acid (the difluoro pyrrole is grand), (s-) 2-chloro-n-(2,4-dimethyl-3-thienyl)-n-(2-methoxyl group-1-methyl-ethyl)-acetamide (p dimethenamidp); 2-[2-(3-chloro-phenyl)-oxirane methyl]-2-ethyl-1h-indenes-1; 3 (2h)-diketone (epropodan), (r)-2-[4-(6-chloro-benzoxazole-2-base-oxygen base)-phenoxy group]-ethyl propionate (fenoxaprop), n-(2; 6-two fluoro-phenyl)-8-fluoro-5-methoxyl group-[1; 2,4]-triazol-[1,5-c]-pyrimidine-2-sulfonamide (florasulam); (r)-2-[4-(5-trifluoromethyl-pyridine-2-base-oxygen base)-phenoxy group]-butyl propionate (efficient fluazifop butyl ester); 4,5-dihydro-3-methoxyl group-4-methyl-5-oxo-n-[(2-trifluoromethoxyphen-l)-sulfonyl]-1h-1,2; 4-triazole-1-formamide sodium salt (flucarbazone-sodium salt); [2-chloro-4-fluoro-5-(5-methyl-6-oxo-4-trifluoromethyl-1 (6h)-pyridazinyl)-phenoxy group]-ethyl acetate (flufenpyr), 2-[7-fluoro-3,4-dihydro-3-oxo-4-(2-propynyl)-2h-1; 4-benzoxazine-6-yl]-4; 5,6,7-tetrahydrochysene-1h-iso-indoles-1; 3-diketone (flumioxazin); the sodium salt of n-(4,6-dimethoxy-pyrimidine-2-base)-n '-(3-methoxycarbonyl-6-trifluoromethyl-pyridine-2-base-sulfonyl)-urea (the fluorine pyridine is yellow grand), 2-[[[[(4; 6-dimethoxy-2-pyrimidine radicals)-amino]-carbonyl]-amino]-sulfonyl]-4-formoxyl amino-n; n-dimethyl-benzamide (foramsulfuron), (r)-2-[4-(3-chloro-5-trifluoromethyl-pyridine-2-base-oxygen base)-phenoxy group]-propionic acid (with its methyl esters, 2-ethyoxyl-ethyl ester and butyl ester) (fluazifop-butyl; haloxyfop-p-methyl; haloxyfop-methyl, fluazifop-butyl ethoxy ethyl ester, fluazifop-butyl butyl ester); 2-[4; 5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1h-imidazoles-2-yl)-and 5-(methoxy)-3-picolinic acid (imazamox), n-(4-methoxyl group-6-methyl isophthalic acid, 3; 5-triazine-2-yl)-sodium salt (iodosulfuron-methyl-sodium) of n '-(5-iodo-2-methoxycarbonyl-phenyl sulfonyl)-urea; (4-chloro-2-methyl sulphonyl-phenyl)-(5-cyclopropyl-isoxazole-4-bases)-ketone (isoxachlortole), 2-[[[[(4,6-dimethoxy-2-pyrimidine radicals)-amino]-carbonyl]-amino]-sulfonyl]-the 4-[[(methyl sulphonyl)-amino]-methyl]-methyl benzoate (mesosulfuron); 2-(4-methyl sulphonyl-2-nitro-benzoyl)-1;...
헤테로아릴옥시-아세트아미드를 기본으로 한 선택적 제초제본 발명은 헤테로아릴옥시-아세트아미드 및 공지된 제초 활성 화합물 및/또는 명세서에 기술된 독성완화제를 함유하며 사용시 유용한 각종 작물중에서 잡초를 선택적으로 방제하는데 특히 우수한 결과를 나타낼 수 있는 신규한 상승적 제초 활성 배합물에 관한 것이다.(a) 하기 일반식 (I)의 헤테로아릴옥시-아세트아미드("그룹 1의 활성 화합물") 및 (b) 1H-1,2,4-트리아졸-3-아민(아미트롤), 2-[2,4-디클로로-5-(2-프로피닐옥시)-페닐]-5,6,7,8-테트라하이드로-1,2,4-트리아졸로-[4,3-a]-피리딘-3(2H)-온(아자페니딘), N-(4,6-디메톡시-피리미딘-2-일)-N'-[1-메틸-4-(2-메틸-2H-테트라졸-5-일)-1H-피라졸-5-일설포닐]우레아(아짐설푸론), N-벤질-2-(4-플루오로-3-트리플루오로메틸페녹시)-부탄아미드(베플루타미드), N-부틸-N-에틸-2,6-디니트로-4-트리플루오로메틸-벤젠아민(벤플루랄린), 메틸 2-[2-[4-(3,6-디하이드로-3-메틸-2,6-디옥소-4-트리플루오로메틸-1(2H)-피리미디닐)페녹시]메틸]-5-에틸-페녹시-프로파노에이트(벤즈펜디존), 3-(2-클로로-4-메틸설포닐벤조일)-4-페닐티오-비사이클로-[3.2.1]-옥트-3-엔-2-온(벤조비사이클론), [1,1-디메틸-2-옥소-2-(2-프로페닐옥시)]-에틸 2-클로로-5-(3,6-디하이드로-3-메틸-2,6-디옥소-4-트리플루오로메틸-1(2H)-피리미디닐)-벤조에이트(부타페나실-알릴), 2-(1-에톡스이미노-프로필)-3-하이드록시-5-[2,4,6-트리메틸-3-(1-옥소-부틸)-페닐]-2-사이클로헥센-1-온(부트록시딤), 2-[1-[(3-클로로-2-프로페닐)-옥시-이미노]-프로필]-3-하이드록시-5-(테트라하이드로-2H-피란-4-일)-2-사이클로헥센-1-온(칼록시딤, 테프랄록시딤), 에틸 2-클로로-3-[2-클로로-5-(1,3,4,5,6,7-헥사하이드로-1,3-디옥소-2H-이소인돌-2-일)-페닐]-2-프로파노에이트(시니돈-에틸), 2-[1-[2-(4-클로로-페녹시)-프로폭시아미노]부틸]-5-(테트라하이드로-2H-티오피란-3-일)-1,3-사이클로헥산디온(클레폭시딤), (E,E)-(+)-2-[1-[[(3-클로로-2-프로페닐)-옥시]-이미노]-프로필]-3-하이드록시-2-사이클로헥센-1-온(클레토딤), 메틸 3-클로로-2-[[(5-에톡시-7-플루오로[1,2,4]트리아졸로[1,5-c]피리미딘-2-일)-설포닐]-아미노]-벤조에이트(클로란설람-메틸), 2-(1-에톡스이미노부틸)-3-하이드록시-5-(테트라하이드로-2H-티오피란-3-일)-2-사이클로헥센-1-온(사이클록시딤), N-(2,6-디클로로-페닐)-5-에톡시-7-플루오로-[1,2,4]-트리아졸로-[1,5-c]-피리미딘-2-설폰아미드(디클로설람), 2-[1-[(3,5-디플루오로-페닐)-아미노-카보닐-하이드라조노]-에틸]-피리딘-3-카복실산(디플루펜조피르), (S)-2-클로로-N-(2,4-디메틸-3-티에닐)-N-(2-메톡시-1-메틸-에틸)-아세트아미드(디메텐아미드-P), 2-[2-(3-클로로-페닐)-옥시라닐메틸]-2-에틸-1H-인덴-1,3(2H) -디온(에프로포단), (R)-에틸 2-[4-(6-클로로-벤족사졸-2-일-옥시)-페녹시]-프로파노에이트(페녹사프로폽-P-에틸), N-(2,6-디플루오로-페닐)-8-플루오로-5-메톡시-[1,2,4]-트리아졸로-[1,5-c]-피리미딘-2-설폰아미드(플로라설람), 부틸 (R)-2-[4-(5-트리플루오로메틸-피리딘-2-일-옥시)-페녹시]-프로파노에이트(플루아지폽-P-부틸), 4,5-디하이드로-3-메톡시-4-메틸-5-옥소-N-[(2-트리플루오로메톡시페닐)-설포닐]-1H-1,2,4-트리아졸-1-카복사미드의 소듐염(플루카바존-소듐), 에틸 [2-클로로-4-플루오로-5-(5-메틸-6-옥소-4-트리플루오로메틸-1(6H)-피리다지닐)-페녹시]-아세테이트(플루펜피르), 2-[7-플루오로-3,4-디하이드로-3-옥소-4-(2-프로피닐)-2H-1,4-벤족사진-6-일]-4,5,6,7-테트라하이드로-1H-이소인돌-1,3-디온(플루미옥사진), N-(4,6-디메톡시-피리미딘-2-일)-N'-(3-메톡시카보닐-6-트리플루오로메틸-피리딘-2-일-설포닐)-우레아의 소듐염(플루피르설푸론-메틸-소듐), 2-[[[[(4,6-디메톡시-2-피리미디닐)-아미노]-카보닐]-아미노]-설포닐]-4-포르밀아미노-N,N-디메틸벤즈아미드(포람설푸론), (R)-2-[4-(3-클로로-5-트리플루오로메틸-피리딘-2-일-옥시)-페녹시]프로판산(및 그의 메틸, 2-에톡시에틸 및 부틸 에스테르)(할록시폽, -메틸, -P-메틸, -에톡시에틸, -부틸), 2-(4,5-디하이드로-4-메틸-4-(1-메틸에틸)-5-옥소-1H-이미다졸-2-일)-5-(메톡시메틸)-3-피리딘카복실산(이마자목스), N-(4-메톡시-6-메틸-1,3,5-트리아진-2-일)-N'-(5-요오도-2-메톡시카보닐-페닐설포닐)-우레아의 소듐염(요오도설푸론-메틸-소듐), (4-클로로-2-메틸설포닐-페닐)-(5-사이클로프로필-이속사졸-4-일)메타논(이속사클로르톨), 메틸 2-[[[[(4,6-디메톡시-2-피리미디닐)-아미노]-카보닐]-아미노]-설포닐]-4-[[(메틸설포닐)-아미노]-메틸]-벤조에이트(메소설푸론), 2-(4-메틸설포닐-2-니트로-벤조일)-1,3-사이클로헥산디온(메소트리온), 3-[1-(3,5-디클로로페닐)-1-i-프로필]-2,3-디하이드로-6-메틸-5-페닐-4H-1,3-옥사진-4-온(옥사지클로메폰), 2-클로로-1-(3-에톡시-4-니트로-페녹시)-4-트리플루오로메틸벤젠(옥시플루오르펜), 2-(2,2-디플루오로에톡시)-N-(5,8-디메톡시 [1,2,4]트리아졸로[1,5-c]피리미딘-2-일)-6-트리플루오로메틸벤젠설폰아미드(페녹스설람), 2-클로로-N-(2-에톡시에틸)-N-(2-메틸-1-페닐-1-프로페닐)-아세트아미드(페톡사미드), 메틸 2-[[[(4,5-디하이드로-4-메틸-5-옥소-3-프로폭시-1H-1,2,4-트리아졸-1-일)-카보닐]-아미노]-설포닐]-벤조에이트의 소듐염(프로카바존-소듐), 1-클로로-N-[2-클로로-4-플루오로-5-[(6S,7aR)-6-플루오로테트라하이드로-1,3-디옥소-1H-피롤로[1,2-c]이미다졸-2(3H)-일]-페닐]-메탄설폰아미드(프로플루아졸), (R)-[2-[[(1-메틸에틸리덴)아미노]옥시]에틸] 2-[4-(6-클로로-2-퀴녹살리닐옥시)-페녹시]-프로파노에이트(프로파퀴자폽), 2-클로로-N-(2-에틸-6-메틸-페닐)-N-[(1-메틸에톡시)-메틸]-아세트아미드(프로피소클로르), 1-(3-클로로-4,5,6,7-테트라하이드로피라졸로[1,5-a]피리딘-2-일)-5-(메틸-2-프로피닐아미노)-1H-피라졸-4-카보니트릴(피라클로닐), 에틸 [2-클로로-5-(4-클로로-5-디플루오로메톡시-1-메틸-1H-피라졸-3-일)-4-플루오로-페녹시]-아세테이트(피라플루펜-에틸), 6-클로로-3-페닐-4-피리다진-4-올(피리다톨), 7-[(4,6-디메톡시-2-피리미디닐)-티오]-3-메틸-1(3H)-이소벤조푸라논(피리프탈리드), 메틸 2-(4,6-디메톡시-피리미딘-2-일-옥시)-벤조에이트(피리미노박-메틸), 2-클로로-6-(4,6-디메톡시-피리미딘-2-일티오)벤조에이트의 소듐염(피리티오박-소듐), 3,7-디클로로퀴놀린-8-카복실산(퀸클로락), (R)-2-[4-(6-클로로-2-퀴녹살리닐옥시)-페녹시]-프로판산(및 그의 에틸 및 테트라하이드로-2-푸라닐-메틸 에스테르)(퀴잘로폽-P-에틸, -P-테푸릴), 메틸 2-디플루오로메틸-5-(4,5-디하이드로-티아졸-2-일)-4-(2-메틸-프로필)-6-트리플루오로메틸-피리딘-3-카복실레이트(티아조피르), (3,5,6-트리클로로)-피리딘-2-일-옥시-아세트산(트리클로피르), N-[[(4,6-디메톡시-2-피리미디닐)-아미노]-카보닐]-3-(2,2,2-트리플루오로에톡시)-2-피리딘설폰아미드의 소듐염(트리플록시설푸론), N-[4-디메틸아미노-6-(2,2,2-트리플루오로에톡시)-1,3,5-트리아진-2-일]-N'-(2-메톡시카보닐페닐설포닐)-우레아(트리플루설푸론메틸), N-[[(4,6-디메톡시-2-피리미디닐)-아미노]-카보닐]-3-(N-메틸-N-메틸설포닐아미노)-2-피리딘설폰아미드(참조: WO-A-92/10660)의 활성 화합물을 포함하는 제초제의 제 2 그룹중에서 선택된 하나 이상의 화합물("그룹 2의 활성 화합물") 및 또한, 경우에 따라 (c) 4-디클로로아세틸-1-옥사-4-아자-스피로[4.5]-데칸(AD-67), 1-디클로로아세틸헥사하이드로-3,3,8a-트리메틸피롤로[1,2-a]-피리미딘-6(2H)-온(디사이클로논, BAS-145138), 4-디클로로아세틸-3,4-디하이드로-3-메틸-2H-1,4-벤족사진(베녹사코르), 1-메틸-헥실 5-클로로-퀴놀린-8-옥시-아세테이트(클로퀸토셋-멕실), α-(시아노메톡스이미노)-페닐아세토니트릴(시오메트리닐), 2,2-디클로로-N-(2-옥소-2-(2-프로페닐아미노)-에틸)-N-(2-프로페닐)-아세트아미드(DKA-24), 2,2-디클로로-N,N-디-2-프로페닐-아세트아미드(디클로르미드), N-(4-메틸-페닐)-N'-(1-메틸-1-페닐-에틸)-우레아(딤론), 4,6-디클로로-2-페닐-피리미딘(펜클로림), 에틸 1-(2,4-디클로로-페닐)-5-트리클로로메틸-1H-1,2,4-트리아졸-3-카복실레이트(펜클로라졸-에틸), 페닐메틸 2-클로로-4-트리플루오로메틸-티아졸-5-카복실레이트(플루라졸), 4-클로로-N-(1,3-디옥솔란-2-일-메톡시)-α-트리플루오로아세토펜 옥심(플룩소페님), 3-디클로로아세틸-5-(2-푸라닐)-2,2-디메틸-옥사졸리딘(푸릴라졸, MON-13900), 에틸 4,5-디하이드로-5,5-디페닐-3-이속사졸카복실레이트(이속사디펜-에틸), 디에틸-1-(2,4-디클로로페닐)-4,5-디하이드로-5-메틸-1H-피라졸-3,5-디카복실레이트(메펜피르-디에틸), 2-디클로로메틸-2-메틸-1,3-디옥솔란(MG-191), 무수 1,8-나프탈렌디카복실산, α-(1,3-디옥솔란-2-일-메톡스이미노)-페닐아세토니트릴(옥사베트리닐), 2,2-디클로로-N-(1,3-디옥솔란-2-일-메틸)-N-(2-프로페닐)-아세트아미드(PPG-1292), 3-디클로로아세틸-2,2-디메틸옥사졸리딘(R-28725), 3-디클로로아세틸-2,2,5-트리메틸옥사졸리딘(R-29148), 메틸 1-(2-클로로페닐)-5-페닐-1H-피라졸-3-카복실레이트 및 N-(2-메톡시벤조일)-4-[(메틸아미노카보닐)-아미노]-벤젠설폰아미드 그룹중에서 선택된 작물 내약성(crop plant tolerance) 개선 화합...