O-benzyl oxime ether derivatives and their use as pesticidesCompounds of formula (I), wherein Y is hydrogen, C1-C4alkyl, C1-C4alkoxy, OH, CN, NO2, Si(CH3)3, CF3 or halogen, and T is a group (referred to the right formula), and wherein the remaining substituents have the following definitions: X is O, S or NR13; A is O or NR4; R1 is hydrogen, C1-C4alkyl, halo-C1-C4alkyl, cyclopropyl, C1-C4alkoxymethyl, C1-C4alkoxy, C1-C4alkylthio or cyano; R2 is hydrogen, C1-C6alkyl, C3-C6cycloalkyl, cyano unsubstituted or substituted C1-C6alkoxycarbonyl, unsubstituted or substituted di(C1-C6alkyl)aminocarbonyl, unsubstituted or substituted C1-C6alkyl-S(O)q, unsubstituted or substituted aryl-S(O)q, unsubstituted or substituted heteroaryl, unsubstituted or substituted heterocyclyl, unsubstituted or substituted heterocyclylcarbonyl or unsubstituted or substituted phenyl; and R3 is hydrogen, unsubstituted or substituted alkyl, unsubstituted or substituted C3-C6cycloalkyl, unsubstituted or substituted phenyl or unsubstituted or substituted pyridyl; and wherein the remaining substituents are as defined herein, are pesticidal active ingredients. They can be used in pest control, especially as microbicides, insecticides and acaricides in agriculture, in horticulture and in the hygiene sector.The compound of formulas iand its possible isomers or isomer mixture, wherein y is hydrogen, c1-c4alkyl, c1-c4alkoxy, oh, cn, no2、si(ch3)3、cf3or halogen, t is group a) or b) and remaining substituent is to be defined as below：x is o, s or nr13；a is o or nr4；r1it is hydrogen, c1-c4alkyl, halo-c1-c4alkyl, cyclopropyl, c1-c4alkoxy methyl, c1-c4alkoxy, c1-c4alkylthio group or cyano group；r2it is hydrogen, c1-c6alkyl, c3-c6cycloalkyl, cyano group, unsubstituted or substituted c1-c6alkoxy carbonyl, unsubstituted or substituted two (c1-c6alkyl) amino carbonyl, unsubstituted or substituted c1-c6alkyl-s (o)q, unsubstituted or substituted aryl-s (o)q, unsubstituted or substituted heteroaryl, unsubstituted or substituted heterocyclic radical or unsubstituted or substituted heterocyclylcarbonyl；group, group or thienyl；d is identical or different and selected from halogen, c1-c4alkyl, c1-c4alkoxy, c1-c2haloalkyl, c1-c2halogenated alkoxy, c3-c6alkenyloxy, c3-c6alkynyloxy group, c1-c4alkylenedioxy group, cyano group and nitro；n is 0,1,2,3 or 4；z is-o- ,-o- (c1-c4alkyl)-,-(c1-c4alkyl)-o- ,-(so)m-、-(c1-c4alkyl)-s (o)m- or-s (o)m-(c1-c4alkyl)-, m is 0,1 or 2, b are c1-c6alkyl, halo-c1-c6alkyl, c3-c6cycloalkyl；c2-c6alkenyl or c2-c4alkynyl-c1-c2alkyl, they are unsubstituted or each by 1 to 3 halogen atom substitution；aryl, heteroaryl or heterocyclic radical, this three kinds of groups are unsubstituted or replaced by being independently from each other one to five following substituent：c1-c6alkyl, halo-c1-c6alkyl, halogen, c1-c6alkoxy and halo-c1-c6alkoxy, or group or trimethyl silicon substrate；r5、r6、r7、r8and r9independently of one another hydrogen, c1-c4alkyl or halogen, and, p is 0,1,2 or 3；q is 1 or 2；r3it is hydrogen, c1-c6alkyl, the c with 1 to 5 halogen atom1-c6haloalkyl, c1-c4alkoxy -c1-c2alkyl, c unsubstituted or by 1 to 3 halogen atom substitution2-c4alkenyl-c1-c2alkyl, c2-c4alkynyl-c1-c2alkyl, c unsubstituted or by 1 to 4 halogen atom substitution3-c6cycloalkyl, c unsubstituted or by 1 to 4 halogen atom substitution3-c6cycloalkyl-c1-c4alkyl, cyano group-c1-c4alkyl, c1-c4alkoxy carbonyl-c1-c2alkyl, c1-c4alkoxycarbamoyl-c1-c2alkyl, phenyl-c unsubstituted or by following substituent group1-c3alkyl：halogen, c1-c3alkyl, c1-c4alkoxy, c1-c4haloalkyl, cyano group, nitro or c1-c4alkylenedioxy group, phenyl can be replaced by identical or different substituent dan zhisan；phenyl unsubstituted or that following substituent substitution is each independently selected from by one or two：c1-c4alkyl, c1-c4alkoxy, halogen, the c of 1 to 3 halogen atom of band1-c2haloalkyl, nitro and cyano group；or pyridine radicals unsubstituted or that following substituent substitution is each independently selected from by one or two：c1-c4alkyl, c1-c4alkoxy, halogen, the c of 1 to 3 halogen atom of band1-c2haloalkyl, nitro and cyano group；r4it is c1-c4alkyl or phenyl, or r3and r4, and the nitrogen-atoms being bonded therewith forms unsubstituted or by c together1-c4other 1 to 3 hetero atom for being selected from n, o and s can be contained in alkyl substitution, saturation or unsaturation 5- to 7- yuan of rings, ring；r10it is hydrogen, c1-c4alkyl, c2-c4alkenyl, c2-c4alkynyl, c3-c6cycloalkyl, unsubstituted or substituted phenyl, phenyl can be replaced by most three selected from following substituent：halogen, c1-c4alkyl, c1-c4alkoxy and c1-c4alkylthio group, or unsubstituted or substituted benzyl, benzyl are at most replaced on aromatic ring by three substituents in the same way；cvclopropvlmethvl, c1-c4haloalkyl, c2-c4halogenated alkenyl, c2-c5alkoxyalkyl, cyano methyl, co-r14、oh、nh2、c1-c6alkylamine, c1-c4haloalkyl amine or c1-c4alkoxy carbonyl-c1-c2alkyl；r11it is hydrogen, c1-c4alkyl, c2-c4alkenyl, c2-c4alkynyl, c3-c6cycloalkyl, c (o) r14、oh、nh2、c1-c4alkoxy, c2-c4alkenyloxy, c2-c4alkynyloxy group, c1-c4alkylamine or c1-c4haloalkyl amine；r12it is hydrogen, c1-c4alkyl or c2-c4alkenyl；or r11and r12, and the nitrogen-atoms being bonded therewith forms unsubstituted or by c together1-c4other 1 to 3 hetero atom for being selected from n, o and s can be contained in alkyl substitution, saturation or unsaturation 5- to 7- yuan of rings, ring；k is 0 or 1；r13it is hydrogen, c1-c4alkyl, c2-c4alkenyl or c2-c4alkynyl；r14it is hydrogen, c1-c4alkyl, c1-c4haloalkyl, c1-c4alkoxy, c3-c6cycloalkyl, c1-c4alkoxy carbonyl or unsubstituted or substituted phenyl, the substituted-phenyl are replaced by most three selected from following substituent：halogen, c1-c4alkyl and c1-c4alkoxy.
살충제로서 유용한 오르토-벤질 옥심 에테르 유도체(O-Benzyl Oxime Ether Derivatives and their Use as Pesticides)본 발명은 살충 활성 성분인 하기 일반식(I)의 화합물에 관한 것이다. 이들 화합물은 농업, 원예 및 위생 분야에서 해충 방제, 특히 살균제, 살충제 및 살비제로서 사용될 수 있다.상기 식에서, Y는 H, C1-C4알킬, C1-C4알콕시, OH, CN, NO 2, Si(CH3)3, CF3또는 할로겐이고, T는 기이며, X는 O, S 또는 NR13이고; A는 O또는 NR4이며; R1은 H, C1-C 4알킬, 할로-C1-C4알킬, 시클로프로필, C1-C4알콕시메틸, C1-C 4알콕시, C1-C4알킬티오 또는 시아노이고; R2는 H, C1-C6알킬, C3-C6시클로알킬, 시아노, 비치환 또는 치환 C1-C6알콜시카르보닐, 비치환 또는 치환 디(C1-C6알킬) 아미노산카르보닐, 비치환 또는 치환 C1-C6알킬-S(O)q, 비치환 또는 치환 아릴-S(0)q비치환 또는 치환 헤테로아릴, 비치환 또는 치환 헤테로시클릴, 비치환 또는 헤테로시클릴카르보닐 또는 비치환 또는 치환 페닐이며; 및 R3은 H, 비치환 또는 알킬, 비치환 또는 치환 C3-C6시클로알킬, 비치환 또는 치환 페닐 또는 비치환 또는 치환 피리딜이다.하기 일반식(I)의 화합물, 또는 이들의 가능한 이성질체 또는 이성질체 혼합물: [이미지] 상기 식에서, Y는 H, C1-C4알킬, C1-C4알콕시, OH, CN, NO 2, Si(CH3)3, CF3또는 할로겐이고, T는 [이미지] 기이며, X는 O, S 또는 NR13이고: A는 O 또는 NR4이며; R1은 H, C1-C4알킬, 할로-C1-C4알킬, 시클로프로필, C1-C4알콕시메틸, C1-C 4알콕시, C1-C4알킬티오 또는 시아노이고; R2는 H, C1-C6알킬, C3-C6시클로알킬, 시아노, 비치환 또는 치환 C1-C6알콕시카르보닐, 비치환 또는 치환 디(C1-C6알킬) 아미노카르보닐, 비치환 또는 치환 C1-C6알킬-S(O)q, 비치환 또는 치환 아릴-S(O)q, 비치환 또는 치환 헤테로아릴, 비치환 또는 치환 헤테로시클릴 또는 비치환 또는 치환 헤테로시클릴카르보닐; [이미지]기, [이미지]기, 또는 티에닐이며; D는 동일하거나 또는 상이하며 할로겐, C1-C4알킬, C1-C4알콕시, C1-C2할로알킬, C1-C2할로알콕시, C3-C6 알케닐옥시, C3-C6 알키닐옥시, C1-C4 알킬렌디옥시, 시아노 및 니트로로부터 선택되고; n은 0, 1, 2, 3 또는 4이며; Z는 -O-, -O-(C1-C4알킬)-, -(C1-C4알킬)-O, -S(O)m-, -(C1-C4알킬)-S(O)m- 또는 -S(O)m-(C1-C4알킬)이고; m은 0, 1 또는 2이며; B는 C1-C6알킬, 할로-C1-C6알킬, C3-C6시클로알킬; 비치환 또는 1 내지 3개의 할로겐 원자에 의해 각각 치환된 C2-C6알케닐 또는 C2-C4알키닐 -C1-C2알킬; 비치환 또는 C1-C6알킬, 할로 -C1-C6알킬, 할로겐, C1-C6알콕시 및 할로 -C1-C6알콕시로부터 선택된 1 내지 5개의 동일하거나 또는 상이한 치환체로 치환된 아릴, 헤테로아릴 또는 헤테로시클환체로 치환된 아릴, 헤테로아릴 또는 헤테로시클릴; 또는 [이미지]기, 또는 트리메틸실릴이고; R5, R5, R6, R7, R8및 R9는 서로 독립적으로 H, C1-C4알킬 또는 할로겐이며; p는 0, 1, 2 또는 3이고; q는 1 또는 2이며; R3는 H, C1-C6알킬; 1 내지 5개의 할로겐 원자를 갖는 C1-C 6할로알킬; C1-C4알콕시 -C1-C2알킬; 비치환 또는 1 내지 3개의 할로겐 원자로 치환된 C2-C 4알키닐 -C1-C2알킬; C2-C4알키닐-C1-C2알킬 비치환 또는 1 내지 4개의 할로겐 원자로 치환된 C3-C6시클로알킬; 비치환 또는 1 내지 4개의 할로겐 원자로 치환된 C3-C 6시클로알킬-C1-C4알킬; 시아노-C1-C4알킬; C1-C4알콕시카르보닐-C1-C2알킬; C1-C4알콕시카르바모일-C1-C2알킬; 페닐 기가 동일하거나 또는 상이한 치환체에 의한 1 내지 3 치환될 수 있는, 비치환 또는 할로겐, C1-C3알킬, C1-C4알콕시, C1-C4할로알킬, 시아노, 니트로 또는 C1-C4알킬렌디옥시에 의해 치환된 페닐-C1-C3알킬; 비치환 또는 C1-C4알킬, C1-C4알콕시, 할로겐, 1 내지 3개의 할로겐 원자를 갖는 C1-C2할로알킬, 니트로 및 시아노로부터 서로 독립적으로 선택된 1 또는 2개의 치환체에 의해 치환된 페닐; 비치환 또는 C1-C4알킬, C1-C4알콕시, 할로겐, 1 내지 3개의 할로겐 원자를 갖는 C1-C2할로알킬, 니트로 및 시아노로부터 서로 독립적으로 선택된 1 또는 2개의 치환체에 의해 치환된 피리딜이고; R4는 C1-C4알킬 또는 페닐이며; 또는 R3및 R4는 결합된 질소 원자와 함께 N, O 및 S로부터 선택된 1 내지 3개의 추가 헤테로 원자를 함유할 수 있는 비치환 또는 C1-C4알킬-치환, 포화 또는 불포화 5-내지 7-원 고리를 형성하고; R10은 H, C1-C4알킬, C2-C4알케닐, C2-C4알키닐, C3-C6시클로알킬, 비치환 또는 할로겐, C1-C4알킬, C1-C4알콕시 및 C1-C4알킬티오로부터 선택된 최대 3개의 치환체에 의해 치환된 페닐; 또는 비치환 또는 방향족 고리에 최대 3개의 치환체에 의해 동일한 방식으로 치환된 벤질; 시클로프로필메틸; C1-C4할로알킬, C2-C4할로알케닐, C2-C5알콕시알킬, 시아노메틸, CO-R14, OH, NH2, C1-C6알킬아민, C1-C4할로알킬아민 또는 C1-C4알콕시카르보닐-C 1-C2알킬이며; R11은 H, C1-C4알킬, C2-C4알케닐, C2-C4알키닐, C3-C6시클로알킬, C(O)R14, OH, NH2, C1-C4알콕시, C2-C4알케닐옥시, C2-C4알키닐옥시, C1-C 4알킬아민 또는 C1-C4할로알킬아민이고; R12는 H, C1-C4알킬 또는 C2-C4알케닐이거나; 또는 R11및 R12는 결합된 질소 원자와 함께 N, O 및 S로부터 선택된 1 내지 3개의 추가 헤테로 원자를 함유할 수 있는 비치환 또는 C1-C4알킬-치환, 포화 또는 불포화 5-내지 7-원 고리를 형성하고; k가 0 또는 1이며; R13이 H, C1-C4알킬, C2-C4알케닐 또는 C2-C4알키닐이고; R14가 H, C1-C4알킬, C1-C4할로알킬, C1-C 4알콕시, C3-C6시클로알킬, C1-C4알콕시카르보닐; 비치환 또는 할로겐, C1-C4알킬 및, C1-C4알콕시로부터 선택된 최대 3개의 치환체에 의해 치환된 페닐이다.