PROCESS FOR PREPARING IMIDAZOLE DERIVATIVESThe invention relates to a process for preparing imidazole derivatives of formula (II) starting from compounds of the Q-H structure via intermediate steps of formula (IIIa) or (IIIb), formulae (II), (IIIa), (IIIb), wherein Q is a structural element (A), the sign # indicating the bond to the radical of the molecule, and A, Q1, Q2, Q3, Q4, Q5, Q6 and Q7, as well as R2, W, V and Y have the meanings indicated in the description.Process for preparing compounds of formula (ii)whereinq represents a structural elementwherein the symbol # represents a bond to the rest of the molecule, andq1represents n or cr6，q2represents n or cr6，q3represents a group of n or c, wherein,q4representation o, s, n, cr6or nr7，q5represents a group of n or c, wherein,q6represents n or ch, andq7represents a group of n or ch,wherein the variable q1、q2、q3、q4、q5、q6and q7up to five of which represent nitrogen simultaneously, and q3and q5not simultaneously represent n, andr6represents hydrogen, (c)1-c4) alkyl radicals, (c)1-c4) -haloalkyl, (c)1-c4) cyanoalkyl, (c)1-c4) -alkoxy- (c)1-c4) alkyl radicals, (c)1-c4) -haloalkoxy- (c)1-c4) alkyl radicals, (c)2-c4) -alkenyl, (c)2-c4) -alkenyloxy- (c)1-c4) alkyl radicals, (c)2-c4) -haloalkenyloxy- (c)1-c4) alkyl radicals, (c)2-c4) -haloalkenyl, (c)2-c4) -cyanoalkenyl, (c)2-c4) -alkynyl, (c)2-c4) -alkynyloxy- (c)1-c4) alkyl radicals, (c)2-c4) -haloalkynyl, (c)3-c6) -cycloalkyl, (c)3-c6) -cycloalkyl- (c)3-c6) -cycloalkyl, (c)1-c4) -alkyl- (c)3-c6) -cycloalkyl, halo- (c)3-c6) -cycloalkyl, (c)1-c4) -alkylthio- (c)1-c4) alkyl radicals, (c)1-c4) -alkylsulfinyl- (c)1-c4) alkyl radicals, (c)1-c4) -alkylsulfonyl- (c)1-c4) -alkyl or (c)1-c4) -alkylcarbonyl- (c)1-c4) -an alkyl group,r7is represented by (c)1-c4) alkyl radicals, (c)1-c4) -haloalkyl, (c)1-c4) cyanoalkyl, (c)1-c4) -alkoxy- (c)1-c4) alkyl radicals, (c)1-c4) -haloalkoxy- (c)1-c4) alkyl radicals, (c)2-c4) -alkenyl, (c)2-c4) -alkenyloxy- (c)1-c4) alkyl radicals, (c)2-c4) -haloalkenyloxy- (c)1-c4) alkyl radicals, (c)2-c4) -haloalkenyl, (c)2-c4) -cyanoalkenyl, (c)2-c4) -alkynyl, (c)2-c4) -alkynyloxy- (c)1-c4) alkyl radicals, (c)2-c4) -haloalkynyl, (c)3-c6) -cycloalkyl, (c)3-c6) -cycloalkyl- (c)3-c6) -cycloalkyl, (c)1-c4) -alkyl- (c)3-c6) -cycloalkyl, halo- (c)3-c6) -cycloalkyl, (c)1-c4) -alkylthio- (c)1-c4) alkyl radicals, (c)1-c4) -alkylsulfinyl- (c)1-c4) alkyl radicals, (c)1-c4) -alkylsulfonyl- (c)1-c4) -alkyl or (c)1-c4) -alkylcarbonyl- (c)1-c4) -alkyl, anda represents hydrogen, cyano, halogen, or (c)1-c4) alkyl radicals, (c)1-c4) -haloalkyl, (c)2-c4) -alkenyl, (c)2-c4) -haloalkenyl, (c)2-c4) -alkynyl, (c)2-c4) -haloalkynyl, (c)3-c6) -cycloalkyl, (c)3-c6) -cycloalkyl- (c)3-c6) -cycloalkyl, (c)1-c4) -alkyl- (c)3-c6) -cycloalkyl, (c)1-c4) -alkoxy, (c)1-c4) -haloalkoxy, (c)1-c4) -alkoxyimino group, (c)1-c4) alkylthio group(s), (c)1-c4) -haloalkylthio, (c)1-c4) -alkylsulfinyl, (c)1-c4) -haloalkylsulfinyl, (c)1-c4) -alkylsulfonyl, (c)1-c4) -haloalkylsulfonyl, (c)1-c4) -alkylsulfonyloxy, (c)1-c4) -alkylcarbonyl, (c)1-c4) -haloalkylcarbonyl, aminocarbonyl, (c)1-c4) -alkylaminocarbonyl, di- (c)1-c4) -alkyl radicalaminocarbonyl group, (c)1-c4) -alkylsulfonylamino, (c)1-c4) alkylamino, di- (c)1-c4) alkylamino, aminosulfonyl, (c)1-c4) an alkylaminosulfonyl or di- (c)1-c4) -alkylaminosulfonyl, ora represents-o-cf2-o-and with q1and the carbon atoms to which they are attached together form a 5-membered ring, wherein q1which represents carbon, is a carbon atom,w represents halogen or s (o)nr8whereinr8is represented by (c)1-c6) alkyl radicals, (c)1-c6) cyanoalkyl, (c)1-c6) -alkoxy- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkyl, (c)2-c6) -alkenyl, (c)2-c6) -haloalkenyl, (c)2-c6) -alkynyl, (c)2-c6) -haloalkynyl or (c)3-c8) -a cycloalkyl group, andn represents 0, 1 or 2,v represents (c)1-c6) alkyl radicals, (c)1-c6) -haloalkyl, (c)1-c6) cyanoalkyl, (c)1-c6) -alkoxy- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkoxy- (c)1-c6) alkyl radicals, (c)2-c6) -alkenyl, (c)2-c6) -alkenyloxy- (c)1-c6) alkyl radicals, (c)2-c6) -haloalkenyloxy- (c)1-c6) alkyl radicals, (c)2-c6) -haloalkenyl, (c)2-c6) -cyanoalkenyl, (c)2-c6) -alkynyl, (c)2-c6) -alkynyloxy- (c)1-c6) alkyl radicals, (c)2-c6) -haloalkynyloxy- (c)1-c6) alkyl radicals, (c)2-c6) -haloalkynyl, (c)2-c6) -cyanoalkynyl, (c)3-c8) -cycloalkyl, (c)3-c8) -cycloalkyl- (c)3-c8) -cycloalkyl, (c)1-c6) -alkyl- (c)3-c8) -cycloalkyl, halo- (c)3-c8) -cycloalkyl, cyano- (c)3-c8) -cycloalkyl, (c)1-c6) -alkylthio- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkylthio- (c)1-c6) alkyl radicals, (c)1-c6) -alkylsulfinyl- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkylsulfinyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkylsulfonyl- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkylsulfonyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkylcarbonyl- (c)1-c6) alkyl radicals, (c)1-c6) -haloalkylcarbonyl- (c)1-c6) alkyl radicals, (c)1-c6) -alkoxycarbonyl- (c)1-c6) -alkyl or (c)1-c6) -haloalkoxycarbonyl- (c)1-c6) -alkyl, andy represents hydrogen, halogen, cyano, nitro, (c)1-c4) alkyl radicals, (c)1-c4) -haloalkyl, (c)1-c4) -alkoxy, (c)1-c4) -haloalkoxy, (c)1-c4) alkylthio group(s), (c)1-c4) -haloalkylthio, (c)1-c4) -alkylsulfinyl, (c)1-c4) -haloalkylsulfinyl, (c)1-c4) -alkylsulfonyl, (c)1-c4) haloalkylsulfonyl, scn, (c)1-c4) -alkylcarbonyl, (c)1-c4) -haloalkylcarbonyl, (c)1-c4) alkoxycarbonyl, (c)1-c4) -haloalkoxycarbonyl, aminocarbonyl, (c)1-c4) -alkylaminocarbonyl, di- (c)1-c4) -alkylaminocarbonyl, (c)...
이미다졸 유도체의 제조 방법본 발명은 Q-H 구조의 화합물로부터 출발하여 하기 화학식 (IIIa) 또는 (IIIb)의 중간체 단계를 거쳐 하기 화학식 (II)의 이미다졸 유도체를 제조하는 방법에 관한 것이다:[이미지] 여기서 Q는 구조적 요소 [이미지] (A)를 나타내고, 기호 #는 분자의 나머지 부분에 대한 결합을 나타내고, A, Q1, Q2, Q3, Q4, Q5, Q6 및 Q7, 또한 R2, W, V 및 Y는 발명의 설명에 제시된 의미를 갖는다.화학식 (II)의 화합물의 제조 방법이며,[이미지]여기서Q는 하기 구조적 요소를 나타내고:[이미지]여기서 기호 #은 분자의 나머지 부분에 대한 결합을 나타내고,Q1은 N 또는 CR6을 나타내고,Q2는 N 또는 CR6을 나타내고,Q3은 N 또는 C를 나타내고,Q4는 O, S, N, CR6 또는 NR7을 나타내고,Q5는 N 또는 C를 나타내고,Q6은 N 또는 CH를 나타내고,Q7은 N 또는 CH를 나타내고,여기서 가변기 Q1, Q2, Q3, Q4, Q5, Q6 및 Q7 중 최대 5개는 동시에 질소를 나타내고, Q3 및 Q5는 동시에 N을 나타내지는 않고,R6은 수소, (C1-C4)-알킬, (C1-C4)-할로알킬, (C1-C4)-시아노알킬, (C1-C4)-알콕시-(C1-C4)-알킬, (C1-C4)-할로알콕시-(C1-C4)-알킬, (C2-C4)-알케닐, (C2-C4)-알케닐옥시-(C1-C4)-알킬, (C2-C4)-할로알케닐옥시-(C1-C4)-알킬, (C2-C4)-할로알케닐, (C2-C4)-시아노알케닐, (C2-C4)-알키닐, (C2-C4)-알키닐옥시-(C1-C4)-알킬, (C2-C4)-할로알키닐, (C3-C6)-시클로알킬, (C3-C6)-시클로알킬-(C3-C6)-시클로알킬, (C1-C4)-알킬-(C3-C6)-시클로알킬, 할로-(C3-C6)-시클로알킬, (C1-C4)-알킬티오-(C1-C4)-알킬, (C1-C4)-알킬술피닐-(C1-C4)-알킬, (C1-C4)-알킬술포닐-(C1-C4)-알킬 또는 (C1-C4)-알킬카르보닐-(C1-C4)-알킬을 나타내고,R7은 (C1-C4)-알킬, (C1-C4)-할로알킬, (C1-C4)-시아노알킬, (C1-C4)-알콕시-(C1-C4)-알킬, (C1-C4)-할로알콕시-(C1-C4)-알킬, (C2-C4)-알케닐, (C2-C4)-알케닐옥시-(C1-C4)-알킬, (C2-C4)-할로알케닐옥시-(C1-C4)-알킬, (C2-C4)-할로알케닐, (C2-C4)-시아노알케닐, (C2-C4)-알키닐, (C2-C4)-알키닐옥시-(C1-C4)-알킬, (C2-C4)-할로알키닐, (C3-C6)-시클로알킬, (C3-C6)-시클로알킬-(C3-C6)-시클로알킬, (C1-C4)-알킬-(C3-C6)-시클로알킬, 할로-(C3-C6)-시클로알킬, (C1-C4)-알킬티오-(C1-C4)-알킬, (C1-C4)-알킬술피닐-(C1-C4)-알킬, (C1-C4)-알킬술포닐-(C1-C4)-알킬 또는 (C1-C4)-알킬카르보닐-(C1-C4)-알킬을 나타내고,A는 수소, 시아노, 할로겐, (C1-C4)-알킬, (C1-C4)-할로알킬, (C2-C4)-알케닐, (C2-C4)-할로알케닐, (C2-C4)-알키닐, (C2-C4)-할로알키닐, (C3-C6)-시클로알킬, (C3-C6)-시클로알킬-(C3-C6)-시클로알킬, (C1-C4)-알킬-(C3-C6)-시클로알킬, (C1-C4)-알콕시, (C1-C4)-할로알콕시, (C1-C4)-알콕시이미노, (C1-C4)-알킬티오, (C1-C4)-할로알킬티오, (C1-C4)-알킬술피닐, (C1-C4)-할로알킬술피닐, (C1-C4)-알킬술포닐, (C1-C4)-할로알킬술포닐, (C1-C4)-알킬술포닐옥시, (C1-C4)-알킬카르보닐, (C1-C4)-할로알킬카르보닐, 아미노카르보닐, (C1-C4)-알킬아미노카르보닐, 디-(C1-C4)-알킬아미노카르보닐, (C1-C4)-알킬술포닐아미노, (C1-C4)-알킬아미노, 디-(C1-C4)-알킬아미노, 아미노술포닐, (C1-C4)-알킬아미노술포닐 또는 디-(C1-C4)-알킬아미노술포닐을 나타내거나, 또는A는 -O-CF2-O-를 나타내고, Q1 및 그가 부착되어 있는 탄소 원자와 함께 5-원 고리를 형성하고, 여기서 Q1은 탄소를 나타내고,W는 할로겐 또는 S(O)nR8을 나타내고, 여기서R8은 (C1-C6)-알킬, (C1-C6)-시아노알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C1-C6)-할로알킬, (C2-C6)-알케닐, (C2-C6)-할로알케닐, (C2-C6)-알키닐, (C2-C6)-할로알키닐 또는 (C3-C8)-시클로알킬을 나타내고,n은 0, 1 또는 2를 나타내고,V는 (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-시아노알킬, (C1-C6)-알콕시-(C1-C6)-알킬, (C1-C6)-할로알콕시-(C1-C6)-알킬, (C2-C6)-알케닐, (C2-C6)-알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐옥시-(C1-C6)-알킬, (C2-C6)-할로알케닐, (C2-C6)-시아노알케닐, (C2-C6)-알키닐, (C2-C6)-알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐옥시-(C1-C6)-알킬, (C2-C6)-할로알키닐, (C2-C6)-시아노알키닐, (C3-C8)-시클로알킬, (C3-C8)-시클로알킬-(C3-C8)-시클로알킬, (C1-C6)-알킬-(C3-C8)-시클로알킬, 할로-(C3-C8)-시클로알킬, 시아노-(C3-C8)-시클로알킬, (C1-C6)-알킬티오-(C1-C6)-알킬, (C1-C6)-할로알킬티오-(C1-C6)-알킬, (C1-C6)-알킬술피닐-(C1-C6)-알킬, (C1-C6)-할로알킬술피닐-(C1-C6)-알킬, (C1-C6)-알킬술포닐-(C1-C6)-알킬, (C1-C6)-할로알킬술포닐-(C1-C6)-알킬, (C1-C6)-알킬카르보닐-(C1-C6)-알킬, (C1-C6)-할로알킬카르보닐-(C1-C6)-알킬, (C1-C6)-알콕시카르보닐-(C1-C6)-알킬 또는 (C1-C6)-할로알콕시카르보닐-(C1-C6)-알킬을 나타내고,Y는 수소, 할로겐, 시아노, 니트로, (C1-C4)-알킬, (C1-C4)-할로알킬, (C1-C4)-알콕시, (C1-C4)-할로알콕시, (C1-C4)-알킬티오, (C1-C4)-할로알킬티오, (C1-C4)-알킬술피닐, (C1-C4)-할로알킬술피닐, (C1-C4)-알킬술포닐, (C1-C4)-할로알킬술포닐, SCN, (C1-C4)-알킬카르보닐, (C1-C4)-할로알킬카르보닐, (C1-C4)-알콕시카르보닐, (C1-C4)-할로알콕시카르보닐, 아미노카르보닐, (C1-C4)-알킬아미노카르보닐, 디-(C1-C4)-알킬아미노카르보닐, (C1-C4)-할로알킬아미노카르보닐, (C3-C6)-시클로알킬아미노카르보닐, 아미노티오카르보닐, (C1-C4)-알킬아미노티오카르보닐, 디-(C1-C4)-알킬아미노티오카르보닐, (C1-C4)-할로알킬아미노티오카르보닐, (C3-C6)-시클로알킬아미노티오카르보닐, 아미노, (C1-C4)-알킬아미노, (C1-C4)-할로알킬아미노, 디-(C1-C4)-알킬아미노, (C3-C6)-시클로알킬아미노, (C1-C4)-알킬술포닐아미노, (C1-C4)-알킬카르보닐아미노, (C1-C4)-할로알킬카르보닐아미노, (C1-C4)-알킬카르보닐-(C1-C4)-알킬아미노, (C1-C4)-할로알킬카르보닐-(C1-C4)-알킬아미노, (C3-C6)-시클로알킬카르보닐아미노, (C3-C6)-시클로알킬카르보닐-(C1-C4)-알킬아미노, (C1-C4)-알킬티오카르보닐아미노, (C1-C4)-할로알킬티오카르보닐아미노, (C1-C4)-알킬티오카르보닐-(C1-C4)-알킬아미노, (C1-C4)-할로알킬티오카르보닐-(C1-C4)-알킬아미노, (C3-C6)-시클로알킬티오카르보닐아미노, (C3-C6)-시클로알킬티오카르보닐-(C1-C4)-알킬아미노, (C2-C4)-알케닐, (C2-C4)-할로알케닐, (C2-C4)-시아노알케닐, (C3-C6)-시클로알킬-(C2)-알케닐, (C2-C4)-알키닐 또는 (C2-C4)-할로알키닐을 나타내거나,또는 (C3-C6)-시클로알킬 또는 (C5-C6)-시클로알케닐을 나타내고, 이들 각각은 동일하거나 상이한 치환기에 의해 임의로 일치환 또는 다치환되고, 가능한 치환기는 각 경우에: (C3-C6)-시클로알킬, (C1-C4)-알킬, (C1-C4)-할로알킬, (C1-C4)-알콕시, (C1-C4)-할로알콕시, 아미노카르보닐, 아미노티오카르보닐, 할로겐 또는 시아노이거나,또는 아릴 또는 헤타릴을 나타내고, 이들 각각은 동일하거나 상이한 치환기에 의해 임의로 일치환 또는 다치환되고, 여기서 (헤타릴의 경우) 임의로 적어도 1개의 카르보닐 기가 존재할 수 있고, 가능한 치환기는 각 경우에: 시아노, 카르복실, 할로겐, 니트로, 아세틸, 히드록시, 아미노, SCN, SF5, 트리-(C1-C4)-알킬실릴, (C3-C6)-시클로알킬, (C3-C6)-시클로알킬-(C3-C6)-시클로알킬, (C1-C4)-알킬-(C3-C6)-시클로알킬, (C1-C4)-할로알킬-(C3-C6)-시클로알킬, 할로-(C3-C6)-시클로알킬, 시아노-(C3-C6)-시클로알킬, (C1-C4)-알킬, (C1-C4)-할로알킬, (C1-C4)-시아노알킬, (C1-C4)-히드록시알킬, 히드록시카르보닐-(C1-C4)-알콕시, (C1-C4)-알콕시카르보닐-(C1-C4)-알킬, (C1-C4)-알콕시-(C1-C4)-알킬, (C2-C4)-알케닐, (C2-C4)-할로알케닐, (C2-C4)-시아노알케닐, (C3-C6)-시클로알킬-(C2)-알케닐, (C2-C4)-알키닐, (C2-C4)-할로알키닐, (C2-C4)-시아노알키닐, (C1-C4)-알콕시, (C1-C4)-할로알콕시, (C1-C4)-시아노알콕시, (C1-C4)-알콕시카르보닐-(C1-C4)-알콕시, (C1-C4)-알콕시-(C1-C4)-알콕시, (C1-C4)-알콕시이미노, (C1-C4)-할로알콕시이미노, (C1-C4)-알킬티오, (C1-C4)-할로알킬티오, (C1-C4)-알콕시-(C1-C4)-알킬티오, (C1-C4)-알킬티오-(C1-C4)-알킬, (C1-C4)-알킬술피닐, (C1-C4)-할로알킬술피닐, (C1-C4)-알콕시-(C1-C4)-알킬술피닐, (C1-C4)-알킬술피닐-(C1-C4)-알킬, (C1-C4)-알킬술포닐, (C1-C4)-할로알킬술포닐, (C1-C4)-알콕시-(C1-C4)-알킬술포닐, (C1-C4)-알킬술포닐-(C1-C4)-알킬, (C1-C4)-알킬술포닐옥시, (C1-C4)-할로알킬술포닐옥시, (C1-C4)-알킬카르보닐, (C1-C4)-할로알킬카르보닐, (C1-C4)-알킬카르보닐옥시, (C1-C4)-알콕시카르보닐, (C1-C4)-할로알콕시카르보닐, 아미노카르보닐, (C1-C4)-알킬아미노카르보닐, (C1-C4)-할로알킬아미노카르보닐, 디-(C1-C4)-알킬아미노카르보닐, (C2-C4)-알케닐아미노카르보닐, 디-(C2...