Azine compounds for combating animal pestsThe present invention relates to new azine compounds which are useful combating animal pests, in particular insects and nematodes and to the salts thereof. The invention also relates to a method for combating insects, nematodes and arachnids. The azine compounds of the invention are described by the general formula (I) wherein is absent or a covalent bond; n is 0 or 1, in paarticular 0; A is an optionally substituted cyclic radical selected from phenyl and a 5- or 6-membered heterocyclic radical with 1, 2, 3, or 4 heteroatoms; Ar is an optionally substituted aromatic radical selected from phenyl, pyridyl, pyrimidyl, furyl and thienyl, x is selected from halogen, OR, SR, SOR,SO2R, C1-C4-alkyl and C1-C4-haloalkyl; and wherein R to R and R are as described in the claims and the specification.The azines of a general formula i and salt thereof:wherein... .. does not exist or is covalent bond;n is 0 or 1;a is selected from phenyl and has 1,2,3 or 4 cyclic group that is selected from heteroatomic 5 or the 6 element heterocycle groups of o, n and s independently of each other, and wherein this cyclic group can have 1,2,3,4 or 5 and is selected from following substituent r independently of each other a: halogen, cyano group, nitro, c 1-c 10alkyl, c 1-c 10haloalkyl, c 3-c 10cycloalkyl, c 3-c 10halogenated cycloalkyl, c 2-c 10alkenyl, c 2-c 10halogenated alkenyl, c 2-c 10alkynyl, c 3-c 10halo alkynyl, c 1-c 10alkoxyl, c 1-c 10halogenated alkoxy, c 2-c 10alkenyloxy, c 2-c 10halo alkenyloxy, c 2-c 10alkynyloxy group, c 3-c 10halo alkynyloxy group, c 1-c 10alkylthio group, c 1-c 10halogenated alkylthio, c 1-c 10alkyl sulphinyl, c 1-c 10haloalkyl sulfinyl, c 1-c 10alkyl sulphonyl, c 1-c 10halogenated alkyl sulfonyl, hydroxyl, nr 5r 6, c 1-c 10alkoxy carbonyl group, c 1-c 10haloalkoxy carbonyl, c 2-c 10chain ene keto carbonyl, c 2-c 10halo chain ene keto carbonyl, c 1-c 10alkyl-carbonyl, c 1-c 10halogenated alkyl carbonyl, r 5r 6n-co-, phenyl, benzyl and phenoxy group, wherein phenyl, benzyl and phenoxy group can be selected from following substituent r independently of each other by 1,2,3,4 or 5 breplace: halogen, cyano group, nitro, c 1-c 10alkyl, c 1-c 10haloalkyl, c 3-c 10cycloalkyl, c 3-c 10halogenated cycloalkyl, c 2-c 10alkenyl, c 2-c 10halogenated alkenyl, c 2-c 10alkynyl, c 3-c 10halo alkynyl, c 1-c 10alkoxyl, c 1-c 10halogenated alkoxy, c 2-c 10alkenyloxy, c 2-c 10halo alkenyloxy, c 2-c 10alkynyloxy group, c 3-c 10halo alkynyloxy group, c 1-c 10alkylthio group, c 1-c 10halogenated alkylthio, c 1-c 10alkyl sulphinyl, c 1-c 10haloalkyl sulfinyl, c 1-c 10alkyl sulphonyl, c 1-c 10halogenated alkyl sulfonyl, hydroxyl, nr 5r 6, c 1-c 10alkoxy carbonyl group, c 1-c 10haloalkoxy carbonyl, c 2-c 10chain ene keto carbonyl, c 2-c 10halo chain ene keto carbonyl, c 1-c 10alkyl-carbonyl, c 1-c 10halogenated alkyl carbonyl and r 5r 6n-co-; ar is the aromatic group that is selected from phenyl, pyridine radicals, pyrimidine radicals, furyl and thienyl, and wherein this aromatic group can have 1-5 and is selected from following substituent r independently of each other c: halogen, cyano group, nitro, c 1-c 10alkyl, c 1-c 10haloalkyl, c 3-c 10cycloalkyl, c 3-c 10halogenated cycloalkyl, c 2-c 10alkynyl, c 3-c 10halo alkynyl, c 1-c 10alkoxyl, c 1-c 10halogenated alkoxy, c 2-c 10alkenyloxy, c 2-c 10alkynyloxy group, c 3-c 10halo alkynyloxy group, c 1-c 10alkylthio group, c 1-c 10halogenated alkylthio, c 1-c 10alkyl sulphinyl, c 1-c 10haloalkyl sulfinyl, c 1-c 10alkyl sulphonyl, c 1-c 10halogenated alkyl sulfonyl, hydroxyl, c 1-c 10alkoxy carbonyl group, c 1-c 10haloalkoxy carbonyl, c 2-c 10chain ene keto carbonyl, c 2-c 10halo chain ene keto carbonyl, c 1-c 10alkyl-carbonyl, c 1-c 10halogenated alkyl carbonyl, r 5r 6n-co-, phenyl and phenoxy group, wherein phenyl and phenoxy group can not be substituted or by 1,2,3,4 or 5 substituent r as defined above breplace; x is selected from halogen, or 7, sr 7, sor 7, so 2r 7, c 1-c 4alkyl and c 1-c 4haloalkyl; r 1be h, c 1-c 10alkyl, c 1-c 10haloalkyl, c 3-c 10cycloalkyl, c 3-c 10halogenated cycloalkyl, c 2-c 10alkenyl, c 2-c 10halogenated alkenyl, c 2-c 10alkynyl, c 2-c 10halo alkynyl or can be selected from following substituent r independently of each other by 1,2,3,4 or 5 dthe phenyl that replaces: halogen, cyano group, nitro, c 1-c 10alkyl, c 1-c 10haloalkyl, c 3-c 10cycloalkyl, c 3-c 10halogenated cycloalkyl, c 2-c 10alkenyl, c 2-c 10halogenated alkenyl, c 2-c 10alkynyl, c 3-c 10halo alkynyl, c 1-c 10alkoxyl, c 1-c 10halogenated alkoxy, c 2-c 10alkenyloxy, c 2-c 10halo alkenyloxy, c 2-c 10alkynyloxy group, c 3-c 10halo alkynyloxy group, c 1-c 10alkylthio group, c 1-c 10halogenated alkylthio, c 1-c 10alkyl sulphinyl, c 1-c 10haloalkyl sulfinyl, c 1-c 10alkyl sulphonyl, c 1-c 10halogenated alkyl sulfonyl, hydroxyl, nr 5r 6, c 1-c 10alkoxy carbonyl group, c 1-c 10haloalkoxy carbonyl, c 2-c 10chain ene keto carbonyl, c 2-c 10halo chain ene keto carbonyl, c 1-c 10alkyl-carbonyl, c 1-c 10halogenated alkyl carbonyl and r 5r 6n-co-; r 2for being selected from following univalent perssad: h, halogen, cyano group, c 1-c 10alkyl, c 1-c 10haloalkyl, c 3-c 10cycloalkyl, c 3-c 10halogenated cycloalkyl, c 2-c 10alkenyl, c 2-c 10halogenated alkenyl, c 2-c 10alkynyl, c 3-c 10halo alkynyl, c 1-c 10alkoxyl, c 1-c 10halogenated alkoxy, c 2-c 10alkenyloxy, c 2-c 10halo alkenyloxy, c 2-c 10alkynyloxy group, c 3-c 10halo alkynyloxy group, c 1-c 10alkylthio group, c 1-c 10halogenated alkylthio, hydroxyl-c 1-c 10alkyl, c 1-c 10alkoxy-c 1-c 10alkyl, halo-c 1-c 10alkoxy-c 1-c 10alkyl, c 1-c 10alkoxy carbonyl group-c 1-c 10alkyl, halo-c 1-c 10alkoxy carbonyl group-c 1-c 10alkyl and can be by 1,2,3,4 or 5 substituent r as defined above bthe phenyl that replaces; r 3be h, halogen, cyano group, c 1...
동물 해충 박멸용 아진 화합물본 발명은 동물 해충, 특히 곤충류 및 선충류의 박멸에 유용한 신규 아진 화합물 및 그의 염에 관한 것이다. 본 발명은 또한 곤충류, 선충류 및 거미류의 박멸 방법에 관한 것이다. 본 발명의 아진 화합물은 하기 화학식 I로 표시된다. <화학식 I>  상기 식에서, ....는 부재 또는 공유결합이고, n은 0 또는 1, 특히 0이고, A는 임의로 치환된, 페닐 및 1, 2, 3 또는 4개의 헤테로원자를 갖는 5원 또는 6원 헤테로시클릭 라디칼 중에서 선택된 시클릭 라디칼이고, Ar은 페닐, 피리딜, 피리미딜, 푸릴 및 티에닐 중에서 선택된 방향족 라디칼이고, X는 임의로 치환된, 할로겐, OR7, SR7, SOR7, SO2R7, C1-C4-알킬 및 C1-C4-할로알킬 중에서 선택되고, R1 내지 R4 및 R7은 청구의 범위 및 명세서에 기재된 바와 같다. 하기 화학식 I의 아진 화합물 및 그의 염. <화학식 I> [이미지] .....은 부재 또는 공유 결합이고; n은 0 또는 1이고; A는 페닐, 및 O, N 및 S 중에서 서로 독립적으로 선택된 1, 2, 3 또는 4개의 헤테로원자를 갖는 5원 또는 6원 헤테로시클릭 라디칼 중에서 선택된 시클릭 라디칼이고, 이 시클릭 라디칼은 서로 독립적으로 할로겐, 시아노, 니트로, C1-C10-알킬, C1-C10-할로알킬, C3-C10-시클로알킬, C3-C10-할로시클로알킬, C2-C10-알케닐, C2-C10-할로알케닐, C2-C10-알키닐, C3-C10-할로알키닐, C1-C10-알콕시, C1-C10-할로알콕시, C2-C10-알케닐옥시, C2-C10-할로알케닐옥시, C2-C10-알키닐옥시, C3-C10-할로알키닐옥시, C1-C10-알킬티오, C1-C10-할로알킬티오, C1-C10-알킬술피닐, C1-C10-할로알킬술피닐, C1-C10-알킬술포닐, C1-C10-할로알킬술포닐, 히드록시, NR5R6, C1-C10-알콕시카르보닐, C1-C10-할로알콕시카르보닐, C2-C10-알케닐옥시카르보닐, C2-C10-할로알케닐옥시카르보닐, C1-C10-알킬카르보닐, C1-C10-할로알킬카르보닐, R5R6N-CO-, 페닐, 벤질 및 페녹시 중에서 선택된 1, 2, 3, 4 또는 5개의 치환기 Ra를 가질 수 있고, 여기서 페닐, 벤질 및 페녹시는 할로겐, 시아노, 니트로, C1-C10-알킬, C1-C10-할로알킬, C3-C10-시클로알킬, C3-C10-할로시클로알킬, C2-C10-알케닐, C2-C10-할로알케닐, C2-C10-알키닐, C3-C10-할로알키닐, C1-C10-알콕시, C1-C10-할로알콕시, C2-C10-알케닐옥시, C2-C10-할로알케닐옥시, C2-C10-알키닐옥시, C3-C10-할로알키닐옥시, C1-C10-알킬티오, C1-C10-할로알킬티오, C1-C10-알킬술피닐, C1-C10-할로알킬술피닐, C1-C10-알킬술포닐, C1-C10-할로알킬술포닐, 히드록시, NR5R6, C1-C10-알콕시카르보닐, C1-C10-할로알콕시카르보닐, C2-C10-알케닐옥시카르보닐, C2-C10-할로알케닐옥시카르보닐, C1-C10-알킬카르보닐, C1-C10-할로알킬카르보닐 및 R5R6N-CO- 중에서 서로 독립적으로 선택된 1, 2, 3, 4 또는 5개의 치환기 Rb로 치환될 수 있고; Ar은 페닐, 피리딜, 피리미딜, 푸릴 및 티에닐 중에서 선택된 방향족 라디칼이고, 이 방향족 라디칼은 할로겐, 시아노, 니트로, C1-C10-알킬, C1-C10-할로알킬, C3-C10-시클로알킬, C3-C10-할로시클로알킬, C2-C10-알키닐, C3-C10-할로알키닐, C1-C10-알콕시, C1-C10-할로알콕시, C2-C10-알케닐옥시, C2-C10-알키닐옥시, C3-C10-할로알키닐옥시, C1-C10-알킬티오, C1-C10-할로알킬티오, C1-C10-알킬술피닐, C1-C10-할로알킬술피닐, C1-C10-알킬술포닐, C1-C10-할로알킬술포닐, 히드록시, C1-C10-알콕시카르보닐, C1-C10-할로알콕시카르보닐, C2-C10-알케닐옥시카르보닐, C2-C10-할로알케닐옥시카르보닐, C1-C10-알킬카르보닐, C1-C10-할로알킬카르보닐, R5R6N-CO-, 페닐 및 페녹시 중에서 서로 독립적으로 선택된 1 내지 5개의 치환기 Rc를 가질 수 있고, 여기서 페닐 및 페녹시는 치환되지 않거나 또는 1, 2, 3, 4 또는 5개의 상기 정의한 치환기 Rb로 치환될 수 있고; X는 할로겐, OR7, SR7, SOR7, SO2R7, C1-C4-알킬 및 C1-C4-할로알킬 중에서 선택되고; R1은 H, C1-C10-알킬, C1-C10-할로알킬, C3-C10-시클로알킬, C3-C10-할로시클로알킬, C2-C10-알케닐, C2-C10-할로알케닐, C2-C10-알키닐, C2-C10-할로알키닐 또는 페닐이고, 이들은 할로겐, 시아노, 니트로, C1-C10-알킬, C1-C10-할로알킬, C3-C10-시클로알킬, C3-C10-할로시클로알킬, C2-C10-알케닐, C2-C10-할로알케닐, C2-C10-알키닐, C3-C10-할로알키닐, C1-C10-알콕시, C1-C10-할로알콕시, C2-C10-알케닐옥시, C2-C10-할로알케닐옥시, C2-C10-알키닐옥시, C3-C10-할로알키닐옥시, C1-C10-알킬티오, C1-C10-할로알킬티오, C1-C10-알킬술피닐, C1-C10-할로알킬술피닐, C1-C10-알킬술포닐, C1-C10-할로알킬술포닐, 히드록시, NR5R6, C1-C10-알콕시카르보닐, C1-C10-할로알콕시카르보닐, C2-C10-알케닐옥시카르보닐, C2-C10-할로알케닐옥시카르보닐, C1-C10-알킬카르보닐, C1-C10-할로알킬카르보닐 및 R5R6N-CO- 중에서 서로 독립적으로 선택된 1, 2, 3, 4 또는 5개의 치환기 Rd로 치환될 수 있고; R2는 H, 할로겐, 시아노, C1-C10-알킬, C1-C10-할로알킬, C3-C10-시클로알킬, C3-C10-할로시클로알킬, C2-C10-알케닐, C2-C10-할로알케닐, C2-C10-알키닐, C3-C10-할로알키닐, C1-C10-알콕시, C1-C10-할로알콕시, C2-C10-알케닐옥시, C2-C10-할로알케닐옥시, C2-C10-알키닐옥시, C3-C10-할로알키닐옥시, C1-C10-알킬티오, C1-C10-할로알킬티오, 히드록시-C1-C10-알킬, C1-C10-알콕시-C1-C10-알킬, 할로-C1-C10-알콕시-C1-C10-알킬, C1-C10-알콕시카르보닐-C1-C10-알킬, 할로-C1-C10-알콕시카르보닐-C1-C10-알킬 및 페닐 중에서 선택된 1가 라디칼이고, 이들은 1, 2, 3, 4 또는 5개의 상기 정의한 치환기 Rb로 치환될 수 있고; R3은 H, 할로겐, 시아노, C1-C10-알킬, C1-C10-할로알킬, C3-C10-시클로알킬, C3-C10-할로시클로알킬, C2-C10-알케닐, C2-C10-할로알케닐, C2-C10-알키닐, C3-C10-할로알키닐, C1-C10-알콕시, C1-C10-할로알콕시, C2-C10-알케닐옥시, C2-C10-할로알케닐옥시, C2-C10-알키닐옥시, C3-C10-할로알키닐옥시, C1-C10-알킬티오, C1-C10-할로알킬티오, 히드록시-C1-C10-알킬, C1-C10-알콕시-C1-C10-알킬, 할로-C1-C10-알콕시-C1-C10-알킬, C1-C10-알콕시카르보닐-C1-C10-알킬, 할로-C1-C10-알콕시카르보닐-C1-C10-알킬 또는 페닐이고, 이들은 1 내지 5개의 상기 정의한 치환기 Rb로 치환될 수 있고; R4는 수소이거나 Rc에 주어진 의미 중 하나를 갖거나, 또는 R4는 R2와 함께 O, S, N-R8, CR9=N, CH2-CH2, O-C(O) 또는 O-CH2 중에서 선택된 2가 라디칼이고; R5 및 R6 은 서로 독립적으로 H 또는 C1-C10-알킬이고; R7은 C1-C10-알킬, C1-C10-알킬카르보닐, C1-C10-할로알킬, C2-C10-알케닐, C2-C10-할로알케닐, C3-C10-시클로알킬 및 C3-C10-할로시클로알킬 중에서 선택되고; R8은 수소, 시아노, C1-C10-알킬, C1-C10-할로알킬, C3-C10-시클로알킬, C3-C10-할로시클로알킬, C2-C10-알케닐, C2-C10-할로알케닐, C2-C10-알키닐, C3-C10-할로알키닐, C1-C10-할로알킬술포닐, C1-C10-알킬카르보닐, C1-C10-할로알킬카르보닐, R5R6N-CO-, 페닐 또는 벤질이고, 여기서 페닐 및 벤질은 1, 2, 3, 4 또는 5개의 치환기 Rb로 치환될 수 있고; R9는 수소 또는 Rc에 주어진 의미 중 하나를 갖는다.