Fungicidal Mixtures Comprising Substituted 1-methylpyrazol-4-ylcarboxanilidesFungicidal mixtures, comprising as active components: 1) at least one 1-methylpyrazol-4-ylcarboxanilide of the formula (I) where X=hydrogen or fluorine, R1=C1-C4-alkyl or C1-C4-haloalkyl, R2=hydrogen or halogen, R3=hydrogen, cyano, nitro, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy or C1-C4-alkylthio, R4 and R5=independently of one another hydrogen, cyano, nitro, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, —CH═N—OR6 or —C(CH3)═N—OR6, where R6 is hydrogen, methyl or ethyl; and 2) at least one active compound II, selected from the active compound groups A) to G): A) azoles; B) strobilurins; C) carboxamides; D) heterocyclic compounds; E) carbamates; F) other fungicides; G) plant growth regulators; in a synergistically effective amount, methods for controlling harmful fungi using mixtures of at least one compound I and at least one active compound II, the use of a compound I or compounds I with active compounds II for preparing such mixtures, and also compositions and seed comprising such mixtures.  A fungicidal mixture for controlling phytopathogenic harmful fungi, comprising 1) at least one 1-methylpyrazol-4-ylcarboxanilide compound of the formula I in which the substituents are as defined below: X is hydrogen or fluorine; R1 is C1-C4-alkyl or C1-C4-haloalkyl; R2 is hydrogen or halogen; R3 is hydrogen, cyano, nitro, halogen, C1-C4-alkyl, C1-C4-haloalkyl, Cl-C4-alkoxy, C1-C4-haloalkoxy or C1-C4-alkylthio; R4 and R5 independently of one another are hydrogen, cyano, nitro, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, —CH═N—OR6 or —C(CH3)═N—OR6, where R6 is hydrogen, methyl or ethyl;  and 2) at least one active compound II, selected from the active compound groups A) to A) an azole selected from the group consisting of azaconazole, diniconazole-M, oxpoconazol, paclobutrazol, uniconazol, 1-(4-chloro-phenyl)-2-([1,2,4]triazol-1-yl)-cycloheptanol and imazalil-sulfphate; B) a strobilurin selected from the group consisting of 2-(2-(6-(3-chloro-2-methyl-phenoxy)-5-fluoro-pyrim idin-4-yloxy)-phenyl)-2-methoxyimino-N-methyl-acetamide and 3-methoxy-2-(2-(N-(4-methoxy-phenyl)-cyclo-propanecarboximidoylsulfanylmethyl)-phenyl)-acrylic acid methyl ester; C) a carboxamide selected from the group consisting of benalaxyl-M, 2-amino-4-methyl-thiazole-5-carboxylic acid anilide, 2-chloro-N-(1,1,3-trimethyl-indan-4-yl)-nicotinamide, N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxylic acid amide, N-(4′-chloro-3′,5-difluoro-biphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid amide, N-(4′-chloro-3′,5-difluoro-biphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid amide, N-(3′,4′-dichloro-5-fluoro-biphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid amide, N-(3′,5-difluoro-4′-methyl-biphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid amide, N-(3′,5-difluoro-4′-methyl-biphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid amide, N-(cis-2-bicyclopropyl-2-yl-phenyl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid amide, N-(trans-2-bicyclopropyl-2-yl-phenyl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid amide, fluopyram, N-(3-ethyl-3,5-5-trimethyl-cyclohexyl)-3-formylamino-2-hydroxy-benzamide, oxytetracyclin, silthiofam, N-(6-methoxy-pyridin-3-yl) cyclopropanecarboxylic acid amide, isotianil and 3-(difluoromethyl)-1-methyl-N-[1,2,3,4-tetrahydro-9-(1-methylethyl)-1,4-methano-naphthalen-5-yl]-1H-pyrazole-4-carboxamide of the following formula:  D) a heterocyclic compound selected from the group consisting of 2,3,5,6-tetrachloro-4-methanesulfonyl-pyridine, 3,4,5-trichloro-pyridine-2,6-di-carbonitrile, N-(1-(5-bromo-3-chloro-pyridin-2-yl)-ethyl)-2,4-dichloro-nicotinamide, N-((5-bromo-3-chloro-pyridin-2-yl)-methyl)-2,4-dichloro-nicotinamide, diflumetorim, nitrapyrin, dodemorph-acetate, fluoroimid, blasticidin-S, chinomethionat, debacarb, difenzoquat, difenzoquat-methylsulphat, oxolinic acid, piperalin, 3-[5-(4-chloro-phenyl)-2,3-dimethyl-isoxazolidin-3-yl]-pyridine   and 5-amino-2-iso-propyl-4-ortho-tolyl-pyrazol-3-on-1-thiocarboxylic acid allyl ester  E) a carbamate selected from the group consisting of methasulphocarb, pyribencarb and propamocarb hydrochlorid, F) an other fungicide selected from the group consisting of dodine free base, guazatine-acetate, iminoctadine-triacetate, iminoctadine-tris(albesilate), kasugamycin-hydrochlorid-hydrat, dichlorophen, N-(4-chloro-2-nitro-phenyl)-N-ethyl-4-methyl-benzenesulfon-amide, dicloran, nitrothal-isopropyl, tecnazen, biphenyl, bronopol, diphenylamine, mildiomycin, oxin-copper, N-(cyclopropylmethoxyimino-(6-difluoromethoxy-2,3-difluoro-phenyl)-methyl)-2-phenyl acetamide, N′-(4-(4-chloro-3-trifluoromethyl-phenoxy)-2,5-dimethyl-phenyl)-N-ethyl-N-methyl formamidine, N′-(4-(4-fluoro-3-trifluoromethyl-phenoxy)-2,5-dimethyl-phenyl)-N-ethyl-N-methyl formamidine, N′-(2-methyl-5-trifluormethyl-4-(3-trimethylsilanyl-propoxy)-phenyl)-N-ethyl-N-methyl formamidine and N′-(5-difluormethyl-2-methyl-4-(3-trimethylsilanyl-propoxy)-phenyl)-N-ethyl-N-methyl formamidine; G) a plant growth regulator selected from the group consisting of clofibric acid, 4-CPA (4-chlorophenoxyacetic acid), 2,4-D, 2,4-DB, 2,4-DEP, dichlorprop, fenoprop, IAA (indole-3-acetic acid), IBA (4-indol-3-ylbutyric acid), naphthaleneacetamide, α-naphthaleneacetic acid, 1-naphthol, naphthoxyacetic acid, potassium naphthenate, sodium naphthenate, 2,4,5-T, 2iP (N-(3-methylbut-2-enyl)-1H-purin-6-amine), 6-benzylaminopurine (6-BA), 2,6-dimethylpuridine (N-oxide-2,6-lultidine), benzyladenine, kinetin, zeatin, calcium cyanamide, dimethipin, endothal, ethephon, merphos, metoxuron, pentachlorophenol and its salts, thidiazuron, tribufos, aviglycine, 1-methylcyclopropene, ACC (1-aminocyclopropanecarboxylic acid), etacelasil, ethephon, glyoxime, gibberellins, gibberellic acid, abscisic acid, ancymidol, butralin, carbaryl, chlorphonium, chlor...
치환된 １-메틸피라졸-４-일카르복스아닐리드를 포함하는 살진균 혼합물본 발명은 활성 성분으로서 하기 성분 1) 및 2)를 상승작용 유효량으로 포함하는 살진균 혼합물, 하나 이상의 화합물 I 및 하나 이상의 활성 화합물 II의 혼합물을 이용하여 유해 진균을 방제하는 방법, 상기 혼합물의 제조를 위한 화합물 I 또는 화합물 I과 활성 화합물 II의 용도, 및 상기 혼합물을 포함하는 조성물 및 종자에 관한 것이다: 1) 하나 이상의 하기 화학식 I의 1-메틸피라졸-4-일카르복스아닐리드 <화학식 I>  (식 중, X는 수소 또는 불소이고; R1은 C1-C4-알킬 또는 C1-C4-할로알킬이고; R2는 수소 또는 할로겐이고; R3은 수소, 시아노, 니트로, 할로겐, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시 또는 C1-C4-알킬티오이고; R4 및 R5는 서로 독립적으로 수소, 시아노, 니트로, 할로겐, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시, C1-C4-알킬티오, -CH=N-OR6 또는 -C(CH3)=N-OR6 (여기서, R6은 수소, 메틸 또는 에틸임)임); 및 2) 하기의 활성 화합물 군 A) 내지 G)로부터 선택되는 하나 이상의 활성 화합물 II: A) 아졸; B) 스트로빌루린; C) 카르복스아미드; D) 헤테로시클릭 화합물; E) 카르바메이트; F) 기타 살진균제; G) 식물 성장 조절제.1) 하나 이상의 하기 화학식 I의 1-메틸피라졸-4-일카르복스아닐리드 <화학식 I>  (여기서, 치환기는 하기 정의된 것과 같음; X는 수소 또는 불소이고; R1은 C1-C4-알킬 또는 C1-C4-할로알킬이고; R2는 수소 또는 할로겐이고; R3은 수소, 시아노, 니트로, 할로겐, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시 또는 C1-C4-알킬티오이고; R4 및 R5는 서로 독립적으로 수소, 시아노, 니트로, 할로겐, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시, C1-C4-알킬티오, -CH=N-OR6 또는 -C(CH3)=N-OR6 (여기서, R6은 수소, 메틸 또는 에틸임)임); 및 2) 하기의 활성 화합물 군 A) 내지 G)로부터 선택되는 하나 이상의 활성 화합물 II: A) 아자코나졸, 디니코나졸-M, 옥스포코나졸, 파클로부트라졸, 우니코나졸, 1-(4-클로로-페닐)-2-([1,2,4]트리아졸-1-일)-시클로헵탄올 및 이마잘릴-술페이트로 구성되는 군으로부터 선택되는 아졸; B) 2-(2-(6-(3-클로로-2-메틸-페녹시)-5-플루오로-피리미딘-4-일옥시)-페닐)-2-메톡시이미노-N-메틸-아세트아미드 및 3-메톡시-2-(2-(N-(4-메톡시-페닐)-시클로프로판-카르복스이미도일술파닐메틸)-페닐)-아크릴산 메틸 에스테르로 구성되는 군으로부터 선택되는 스트로빌루린; C) 베날락실-M, 2-아미노-4-메틸-티아졸-5-카르복실산 아닐리드, 2-클로로-N-(1,1,3-트리메틸-인단-4-일)-니코틴아미드, N-(2-(1,3-디메틸부틸)-페닐)-1,3-디메틸-5-플루오로-1H-피라졸-4-카르복실산 아미드, N-(4'-클로로-3',5-디플루오로-바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복실산 아미드, N-(4'-클로로-3',5-디플루오로-바이페닐-2-일)-3-트리플루오로메틸-1-메틸-1H-피라졸-4-카르복실산 아미드, N-(3',4'-디클로로-5-플루오로-바이페닐-2-일)-3-트리플루오로메틸-1-메틸-1H-피라졸-4-카르복실산 아미드, N-(3',5-디플루오로-4'-메틸-바이페닐-2-일)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복실산 아미드, N-(3',5-디플루오로-4'-메틸-바이페닐-2-일)-3-트리플루오로메틸-1-메틸-1H-피라졸-4-카르복실산 아미드, N-(시스-2-바이시클로프로필-2-일-페닐)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복실산 아미드, N-(트랜스-2-바이시클로프로필-2-일-페닐)-3-디플루오로메틸-1-메틸-1H-피라졸-4-카르복실산 아미드, 플루오피람, N-(3-에틸-3,5,5-트리메틸-시클로헥실)-3-포르밀아미노-2-히드록시-벤즈아미드, 옥시테트라시클린, 실티오팜, N-(6-메톡시-피리딘-3-일) 시클로프로판카르복실산 아미드, 이소티아닐 및 하기 화학식의 3-(디플루오로메틸)-1-메틸-N-[1,2,3,4-테트라히드로-9-(1-메틸에틸)-1,4-메타노-나프탈렌-5-일]-1H-피라졸-4-카르복스아미드로 구성되는 군으로부터 선택되는 카르복스아미드:  D) 2,3,5,6-테트라클로로-4-메탄술포닐-피리딘, 3,4,5-트리클로로-피리딘-2,6-디카르보니트릴, N-(1-(5-브로모-3-클로로-피리딘-2-일)-에틸)-2,4-디클로로-니코틴아미드, N-[(5-브로모-3-클로로-피리딘-2-일)-메틸]-2,4-디클로로-니코틴아미드, 디플루메토림, 니트라피린, 도데모르프-아세테이트, 플루오로이미드, 블라스티시딘-S, 치노메티오나트, 데바카르브, 디펜조콰트, 디펜조콰트-메틸술파트, 옥솔린산, 피페랄린, 하기 화학식의 3-[5-(4-클로로-페닐)-2,3-디메틸-이속사졸리딘-3-일]-피리딘  및 하기 화학식의 5-아미노-2-이소-프로필-4-오르토-톨릴-피라졸-3-온-1-티오카르복실산 알릴 에스테르로 구성되는 군으로부터 선택되는 헤테로시클릭 화합물;  E) 메탄술포카르브, 피리벤카르브 및 프로파모카르브 히드로클로리드로 구성되는 군으로부터 선택되는 카르바메이트; F) 도딘 유리 염기, 구아자틴-아세테이트, 이민옥타딘-트리아세테이트, 이민옥타딘-트리스(알베실레이트), 카수가마이신-히드로클로리드-히드라트, 디클로로펜, N-(4-클로로-2-니트로-페닐)-N-에틸-4-메틸-벤젠술폰아미드, 디클로란, 니트로탈-이소프로필, 테크나젠, 바이페닐, 브로노폴, 디페닐아민, 밀디오마이신, 옥신-구리, N-(시클로프로필메톡시이미노-(6-디플루오로메톡시-2,3-디플루오로-페닐)-메틸)-2-페닐 아세트아미드, N'-(4-(4-클로로-3-트리플루오로메틸-페녹시)-2,5-디메틸-페닐)-N-에틸-N-메틸 포름아미딘, N'-(4-(4-플루오로-3-트리플루오로메틸-페녹시)-2,5-디메틸-페닐)-N-에틸-N-메틸 포름아미딘, N'-(2-메틸-5-트리플루오르메틸-4-(3-트리메틸실라닐-프로폭시)-페닐)-N-에틸-N-메틸 포름아미딘 및 N'-(5-디플루오르메틸-2-메틸-4-(3-트리메틸실라닐-프로폭시)-페닐)-N-에틸-N-메틸 포름아미딘으로 구성되는 군으로부터 선택되는 기타 살진균제; G) 클로피브릭산, 4-CPA (4-클로로페녹시아세트산), 2,4-D, 2,4-DB, 2,4-DEP, 디클로르프로프, 페노프로프, IAA (인돌-3-아세트산), IBA (4-인돌-3-일부티르산), 나프탈렌아세트아미드, α-나프탈렌아세트산, 1-나프톨, 나프톡시아세트산, 칼륨 나프테네이트, 나트륨 나프테네이트, 2,4,5-T, 2iP (N-(3-메틸부트-2-에닐)-1H-푸린-6-아민), 6-벤질아미노푸린 (6-BA), 2,6-디메틸푸리딘 (N-옥시드-2,6-루티딘), 벤질아데닌, 키네틴, 제아틴, 칼슘 시안아미드, 디메티핀, 엔도탈, 에테폰, 메르포스, 메톡수론, 펜타클로로페놀 및 그의 염, 티디아주론, 트리부포스, 아비글리신, 1-메틸시클로프로펜, ACC (1-아미노시클로프로판카르복실산), 에타셀라실, 에테폰, 글리옥심, 지베렐린, 지베렐린산, 아브시스산, 안시미돌, 부트랄린, 카르브아릴, 클로르포니움, 클로르프로팜, 디케굴락, 플루메트랄린, 플루오리다미드, 포사민, 글리포신, 이소피리몰, 자스몬산, 말레익 히드라지드, 메피콰트 (메피콰트 클로라이드, 메피콰트 펜타보레이트), 피프록타닐, 프로히드로자스몬, 프로팜, 2,3,5-트리-요오도벤조산, 클로르플루렌, 클로르플루레놀, 디클로르플루레놀, 플루레놀, 클로르메콰트, 다미노지드, 플루프리미돌, 메플루이디드, 파클로부트라졸, 테트시클라시스, 우니코나졸, 브라시놀리드, 포르클로르페누론, 히멕사졸, 아미도클로르, 벤조플루오르, 부미나포스, 카르본, 시오부티드, 클로펜세트, 클록시포낙, 시안아미드, 시클라닐리드, 시클로헥스이미드, 시프로술파미드, 에포콜레온, 에티클로제이트, 에틸렌, 펜리다존, 플루프리미돌, 헵토파르길, 홀로술프, 이나벤피드, 카레타잔, 비산납, 메타술포카르브, 프로헥사디온 (프로헥사디온 칼슘), 피다논, 신토펜, 트리아펜테놀 및 트리넥사팍 (트리넥사팍-에틸)로 구성되는 군으로부터 선택되는 식물 성장 조절제 를 상승작용 유효량으로 포함하는, 식물병원성 유해 진균을 방제하기 위한 살진균 혼합물.