Fungicidal mixtures i comprising quinazolinesThe present invention relates to fungicidal mixtures, comprising at least one quinazo- line compound I and one compound II as defined in the description, and to compositions comprising these mixtures.One kind comprises the mixture of following component as reactive compound with the synergistic effective dose:1) but the n-oxide of at least a formula i compound and formula i compound and agricultural salt:whereinr 1be h or f; r 2be h or ch 3r 3be h or ch 3r 4be cn, halogen, c 1-c 2alkyl or c 1-c 2alkoxyl; n representes substituent r on the benzyl ring 4number and n be 0,1 or 2; py is pyrimidine radicals or pyridine radicals, and wherein above-mentioned heteroaromatic group is not substituted or has 1,2 or 3 identical or different substituent r ar abe cn, halogen, c 1-c 2alkyl, c 1-c 2haloalkyl or c 1-c 2alkoxyl; and2) at least aly be selected from following fungicidal active compound ii: fluorine azoles bacterium acid amides; n '-(4-(4-chloro-3-4-trifluoromethylphenopendant)-2; the 5-3,5-dimethylphenyl)-n-ethyl-n-methyl carbonamidine; n '-(4-(4-fluoro-3-4-trifluoromethylphenopendant)-2; the 5-3,5-dimethylphenyl)-n-ethyl-n-methyl carbonamidine; n '-(2-methyl-5-trifluoromethyl-4-(3-tms propoxyl group) phenyl)-n-ethyl-n-methyl carbonamidine; n '-(5-difluoromethyl-2-methyl-4-(3-tms propoxyl group) phenyl)-n-ethyl-n-methyl carbonamidine; 2-[3-(2-chlorphenyl)-2-(3-fluorophenyl) oxiranylmethyl radical]-2h-[1; 2; 4] triazole-3-mercaptan; 2-[2-(3-fluorophenyl)-3-(2-fluorophenyl) oxiranylmethyl radical]-2h-[1,2,4] triazole-3-mercaptan; 2-[(3-fluorophenyl)-3-o-tolyl oxiranylmethyl radical]-2h-[1; 2; 4] triazole-3-mercaptan; 1-[2-(3-fluorophenyl)-3-(2-fluorophenyl) oxiranylmethyl radical]-5-methyl mercapto-1h-[1,2,4] triazole; 1-[2-(3-fluorophenyl)-3-o-tolyl oxiranylmethyl radical]-5-methyl mercapto-1h-[1; 2; 4] triazole; 1-[3-(2-chlorphenyl)-2-(3-fluorophenyl) oxiranylmethyl radical]-5-methyl mercapto-1h-[1,2,4] triazole; 1-[3-(2-chlorphenyl)-2-(3-fluorophenyl) oxiranylmethyl radical]-5-mesyl-1h-[1; 2; 4] triazole; thiocarbonic acid s-{2-[3-(2-chlorphenyl)-2-(3-fluorophenyl) oxiranylmethyl radical]-2h-[1,2,4] triazole-3-yl } the meth ester; 1-[3-(2-chlorphenyl)-2-(3-fluorophenyl) oxiranylmethyl radical]-5-thiocyano-1h-[1; 2; 4] triazole; thioacetic acid s-{2-[3-(2-chlorphenyl)-2-(3-fluorophenyl) oxiranylmethyl radical]-2h-[1,2,4] triazole-3-yl } ester; 2-[3-(2-chlorphenyl)-2-(2; the 4-difluorophenyl) oxiranylmethyl radical]-2h-[1; 2,4] triazole-3-mercaptan; 2-[2-(3, the 4-difluorophenyl)-3-o-tolyl oxiranylmethyl radical]-2h-[1; 2; 4] triazole-3-mercaptan; 2-[3-(2-chlorphenyl)-2-(3, the 4-difluorophenyl) oxiranylmethyl radical]-2h-[1,2; 4] triazole-3-mercaptan; 2-[2-(3; the 4-difluorophenyl)-3-(2-trifluoromethyl) oxiranylmethyl radical]-2h-[1,2,4] triazole-3-mercaptan; 1-[3-(2-chlorphenyl)-2-(3; the 4-difluorophenyl) oxiranylmethyl radical]-5-methyl mercapto-1h-[1; 2,4] triazole; 1-[2-(2, the 4-difluorophenyl)-3-(2-fluorophenyl) oxiranylmethyl radical]-5-methyl mercapto-1h-[1; 2; 4] triazole; 1-[3-(2-chlorphenyl)-2-(2, the 4-difluorophenyl) oxiranylmethyl radical]-5-methyl mercapto-1h-[1,2; 4] triazole; 1-[3-(2-chlorphenyl)-2-(2; the 4-difluorophenyl) oxiranylmethyl radical]-5-thiocyano-1h-[1,2,4] triazole; thiocarbonic acid s-{2-[3-(2-chlorphenyl)-2-(2; the 4-difluorophenyl) oxiranylmethyl radical]-2h-[1; 2,4] triazole-3-yl } the meth ester; 2-[2-(2-chlorphenyl)-3-(2,4 dichloro benzene base) oxiranylmethyl radical]-2h-[1; 2; 4] triazole-3-mercaptan; 2-[3-(3-chloro-2-fluorophenyl)-2-(4-fluorophenyl) oxiranylmethyl radical]-2h-[1,2,4] triazole-3-mercaptan; 2-[2-phenyl-3-(2; 3; the 4-trichlorophenyl) oxiranylmethyl radical]-2h-[1,2,4] triazole-3-mercaptan; 1-[2-(2-chlorphenyl)-3-(2; the 4-dichlorophenyl) oxiranylmethyl radical]-5-methyl mercapto-1h-[1; 2,4] triazole; 1-[3-(3-chloro-2-fluorophenyl)-2-(4-fluorophenyl) oxiranylmethyl radical]-5-methyl mercapto-1h-[1,2; 4] triazole; 1-[2-phenyl-3-(2; 3, the 4-trichlorophenyl) oxiranylmethyl radical]-5-methyl mercapto-1h-[1,2; 4] triazole; 1-[2-(2-chlorphenyl)-3-(2; the 4-dichlorophenyl) oxiranylmethyl radical]-5-mesyl-1h-[1,2,4] triazole; thiocarbonic acid s-{2-[2-(2-chlorphenyl)-3-(2; the 4-dichlorophenyl) oxiranylmethyl radical]-2h-[1; 2,4] triazole-3-yl } the meth ester; 1-[2-(2-chlorphenyl)-3-(2,4 dichloro benzene base) oxiranylmethyl radical]-5-thiocyano-1h-[1; 2; 4] triazole; 2-[3-(2-chlorphenyl)-2-(2-fluorophenyl) oxiranylmethyl radical]-2h-[1,2,4] triazole-3-mercaptan; 1-[3-(2-chlorphenyl)-2-(2-fluorophenyl) oxiranylmethyl radical]-5-methyl mercapto-1h-[1; 2; 4] triazole; 1-[3-(2-chlorphenyl)-2-(2-fluorophenyl) oxiranylmethyl radical]-5-thiocyano-1h-[1,2,4] triazole; thiocarbonic acid s-{2-[3-(2-chlorphenyl)-2-(2-fluorophenyl) oxiranylmethyl radical]-2h-[1; 2; 4] triazole-3-yl } the meth ester; 2-[3-(2-chlorphenyl)-2-(4-fluorophenyl) oxiranylmethyl radical]-2h-[1,2,4] triazole-3-mercaptan; 5-allyl sulfenyl-1-[3-(2-chlorphenyl)-2-(2; the 4-difluorophenyl) oxirane-2-yl] methyl]-1; 2, the 4-triazole; 2-[1-[3-(2,4 dichloro benzene base)-2-methyl-propyl]-2-hydroxyl-3; the 3-dimethylbutyl]-4h-1; 2,4-triazole-3-thioketones; 3-chloro-5-(6-chloro-3-pyridine radicals)-6-...
퀴나졸린을 포함하는 살진균 혼합물 I본 발명은, 본 명세서에 정의된 바와 같은 1종 이상의 퀴나졸린 화합물 I 및 1종의 화합물 II를 포함하는 살진균 혼합물, 및 이러한 혼합물을 포함하는 조성물에 관한 것이다.활성 화합물로서1) 하기 화학식 I의 1종 이상의 화합물, 및 화학식 I의 화합물의 N-옥시드 및 농업상 허용되는 염<화학식 I>[이미지](상기 식에서:R1은 H 또는 F이고;R2는 H 또는 CH3이고;R3은 H 또는 CH3이고;R4는 CN, 할로겐, C1-C2-알킬 또는 C1-C2-알콕시이고;n은 페닐 고리 상의 치환기 R4의 수를 나타내고, n은 0, 1 또는 2이고;Py는 피리미딜 또는 피리딜이고, 여기서 상기 언급된 헤테로방향족 라디칼은 비치환되거나 또는 1, 2 또는 3개의 동일하거나 상이한 치환기 Ra를 보유하고; Ra는 CN, 할로겐, C1-C2-알킬, C1-C2-할로알킬 또는 C1-C2-알콕시임);및2) 하기로부터 선택된 1종 이상의 살진균 활성 화합물 II:플룩사피록사드, N'-(4-(4-클로로-3-트리플루오로메틸-페녹시)-2,5-디메틸-페닐)-N-에틸-N-메틸 포름아미딘, N'-(4-(4-플루오로-3-트리플루오로메틸-페녹시)-2,5-디메틸-페닐)-N-에틸-N-메틸 포름아미딘, N'-(2-메틸-5-트리플루오로메틸-4-(3-트리메틸실라닐-프로폭시)-페닐)-N-에틸-N-메틸 포름아미딘, N'-(5-디플루오로메틸-2-메틸-4-(3-트리메틸실라닐-프로폭시)-페닐)-N-에틸-N-메틸 포름아미딘, 2-[3-(2-클로로페닐)-2-(3-플루오로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 2-[2-(3-플루오로페닐)-3-(2-플루오로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 2-[(3-플루오로페닐)-3-o-톨릴-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 1-[2-(3-플루오로페닐)-3-(2-플루오로페닐)-옥시라닐메틸]-5-메틸술파닐-1H-[1,2,4]트리아졸, 1-[2-(3-플루오로페닐)-3-o-톨릴-옥시라닐메틸]-5-메틸술파닐-1H-[1,2,4]트리아졸, 1-[3-(2-클로로페닐)-2-(3-플루오로페닐)-옥시라닐메틸]-5-메틸술파닐-1H-[1,2,4]트리아졸, 1-[3-(2-클로로페닐)-2-(3-플루오로페닐)-옥시라닐메틸]-5-메탄술포닐-1H-[1,2,4]트리아졸, 티오탄산 S-{2-[3-(2-클로로페닐)-2-(3-플루오로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-일} 에스테르 메틸 에스테르, 1-[3-(2-클로로페닐)-2-(3-플루오로페닐)-옥시라닐메틸]-5-티오시아네이토-1H-[1,2,4]트리아졸, 티오아세트산 S-{2-[3-(2-클로로페닐)-2-(3-플루오로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-일} 에스테르, 2-[3-(2-클로로페닐)-2-(2,4-디플루오로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 2-[2-(3,4-디플루오로페닐)-3-o-톨릴-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 2-[3-(2-클로로페닐)-2-(3,4-디플루오로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 2-[2-(3,4-디플루오로페닐)-3-(2-트리플루오로메틸페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 1-[3-(2-클로로페닐)-2-(3,4-디플루오로페닐)-옥시라닐메틸]-5-메틸술파닐-1H-[1,2,4]트리아졸, 1-[2-(2,4-디플루오로페닐)-3-(2-플루오로페닐)-옥시라닐메틸]-5-메틸술파닐-1H-[1,2,4]트리아졸, 1-[3-(2-클로로페닐)-2-(2,4-디플루오로페닐)-옥시라닐메틸]-5-메틸술파닐-1H-[1,2,4]트리아졸, 1-[3-(2-클로로페닐)-2-(2,4-디플루오로페닐)-옥시라닐메틸]-5-티오시아네이토-1H-[1,2,4]트리아졸, 티오탄산 S-{2-[3-(2-클로로페닐)-2-(2,4-디플루오로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-일} 에스테르 메틸 에스테르, 2-[2-(2-클로로페닐)-3-(2,4-디클로로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 2-[3-(3-클로로-2-플루오로페닐)-2-(4-플루오로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 2-[2-페닐-3-(2,3,4-트리클로로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 1-[2-(2-클로로페닐)-3-(2,4-디클로로페닐)-옥시라닐메틸]-5-메틸술파닐-1H-[1,2,4]트리아졸, 1-[3-(3-클로로-2-플루오로페닐)-2-(4-플루오로페닐)-옥시라닐메틸]-5-메틸술파닐-1H-[1,2,4]트리아졸, 1-[2-페닐-3-(2,3,4-트리클로로페닐)-옥시라닐메틸]-5-메틸술파닐-1H-[1,2,4]트리아졸, 1-[2-(2-클로로페닐)-3-(2,4-디클로로페닐)-옥시라닐메틸]-5-메탄술포닐-1H-[1,2,4]트리아졸, 티오탄산 S-{2-[2-(2-클로로페닐)-3-(2,4-디클로로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-일} 에스테르 메틸 에스테르, 1-[2-(2-클로로페닐)-3-(2,4-디클로로페닐)-옥시라닐메틸]-5-티오시아네이토-1H-[1,2,4]트리아졸, 2-[3-(2-클로로페닐)-2-(2-플루오로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 1-[3-(2-클로로페닐)-2-(2-플루오로페닐)-옥시라닐메틸]-5-메틸술파닐-1H-[1,2,4]트리아졸, 1-[3-(2-클로로페닐)-2-(2-플루오로페닐)-옥시라닐메틸]-5-티오시아네이토-1H-[1,2,4]트리아졸로, 티오탄산 S-{2-[3-(2-클로로페닐)-2-(2-플루오로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-일} 에스테르 메틸 에스테르, 2-[3-(2-클로로페닐)-2-(4-플루오로페닐)-옥시라닐메틸]-2H-[1,2,4]트리아졸-3-티올, 5-알릴술파닐-1-[3-(2-클로로페닐)-2-(2,4-디플루오로페닐)옥시란-2-일]메틸]-1,2,4-트리아졸, 2-[1-[3-(2,4-디클로로페닐)-2-메틸프로필]-2-히드록시-3,3-디메틸부틸]-4H-1,2,4-트리아졸-3-티온, 3-클로로-5-(6-클로로-3-피리딜)-6-메틸-4-(2,4,6-트리플루오로페닐)피리다진, N-[2-(2,4-디클로로페닐)-2-메톡시-1-메틸-에틸]-3-(디플루오로메틸)-1-메틸-피라졸-4-카르복스아미드, 하기 화학식 IIa의 화합물<화학식 IIa>[이미지](상기 식에서:B는 직접 결합 또는 알킬렌 기이고;A는 OH 또는 H임);및 암펠로미세스 퀴스쿠알리스(Ampelomycesquisqualis), 아스페르길루스 플라부스(Aspergillusflavus), 아우레오바시디움 풀루란스(Aureobasidiumpullulans), 바실루스 푸밀루스(Bacilluspumilus), 바실루스 서브틸리스(Bacillussubtilis), 바실루스 서브틸리스 변종 아밀로리쿠에파시엔스(Bacillussubtilisvar. amyloliquefaciens) FZB24, 칸디다 사이토아나(Candidasaitoana), 키토산(Chitosan), 코니오티리움 미니탄스(Coniothyriumminitans), 크리포넥트리아 파라시티카(Cryphonectriaparasitica), 크립토코쿠스 알비두스(Cryptococcus albidus), 메치니코위아 프룩티콜라(Metschnikowiafructicola), 미크로도키움 디메룸(Microdochiumdimerum), 슈도지마 플록쿨로사(Pseudozymaflocculosa), 피티움 올리간드룸(Pythiumoligandrum) DV74, 레이노우트리아 사클리넨시스(Reynoutriasachlinensis), 탈라로미세스 플라부스(Talaromycesflavus) V117b, 트리코더마 아스페렐룸(Trichodermaasperellum) SKT-1, T. 아트로비리데(T. atroviride) LC52, T. 하르지아눔(T. harzianum) T-22, T. 하르지아눔 TH 35, T. 하르지아눔 T-39, T. 하르지아눔 및 T. 비리데(T. viride), T. 하르지아눔 ICC012 및 T. 비리데 ICC080, T. 폴리스포룸(T. polysporum) 및 T. 하르지아눔, T. 스트로마티쿰(T. stromaticum), T. 비렌스(T. virens) GL-21, T. 비리데, T. 비리데 TV1 및 울로클라디움 오우데만시이(Ulocladiumoudemansii) HRU3으로부터 선택된 항진균 생물방제제 및 식물 생물활성화제를 상승작용적 유효량으로 포함하는 혼합물.