Bicylic 1,3-diones and Their Use as Insecticides, Acaricides and/or FungicidesThe present invention relates to the use of compounds of Formula (I) wherein R1, R2, R3, R4, R5, R6, Y, X, and G have the meanings given above as insecticides and/or acaricides and/or fungicides. The use of compounds of Formula (I) whereinR1 is methyl, ethyl, n-propyl, iso-propyl, cyclopropyl, halomethyl, haloethyl, halogen, vinyl, ethynyl, methoxy, ethoxy, halomethoxy or haloethoxy,R2 and R3 are independently hydrogen, halogen, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, C2-C6alkenyl, C2-C6haloalkenyl, C2-C6alkynyl, C3-C6alkenyloxy, C3-C6haloalkenyloxy, C3-C6alkynyloxy, C3-C6cycloalkyl, C1-C6alkylthio, C1-C6alkylsulfinyl, C1-C6alkylsulfonyl, C1-C6alkylsulfonyloxy, C1-C6haloalkylsulfonyloxy, cyano, nitro, optionally substituted phenyl or optionally substituted heteroaryl where at least one of R2 and R3 is optionally substituted phenyl or optionally substituted heteroaryl,R4 is hydrogen, methyl, ethyl, n-propyl, iso-propyl, halomethyl, haloethyl, halogen, vinyl, ethynyl, methoxy, ethoxy, halomethoxy or haloethoxy,R5 and R6 are independently hydrogen, C1-C6alkyl, C2-C6alkenyl, C2-C6alkynyl, C1-C6haloalkyl, C2-C6haloalkenyl, C1-C6alkoxy, C3-C6alkenyloxy, C3-C6haloalkenyloxy, C3-C6alkynyloxy, C1-C4alkoxy C1-C4alkyl, C1-C4alkoxyC1-C4alkoxy, C1-C4alkoxyC1-C4alkoxyC1-C4alkyl, C1-C6alkylthio, C1-C4alkylthioC1-C4alkyl, C1-C4alkylsulfinyl, C1-C4alkylsulfinylC1-C4alkyl, C1-C4alkylsulfonyl, C1-C4alkylsulfonylC1-C4alkyl, hydroxy-C1-C4alkyl, C1-C6haloalkoxy C1-C4alkyl, C3-C6alkenyloxyC1-C4alkyl, C3-C6haloalkenyloxy C1-C4alkyl, C3-C6alkynyloxy C1-C4alkyl, C1-C6cyanoalkyl, C1-C4cyanoalkoxy, C1-C4cyanoalkoxyC1-C4alkyl, hydroxy, C1-C6alkylcarbonyl, carboxy, C1-C6alkoxycarbonyl, C1-C6alkylaminocarbonyl, di-C1-C6alkylcarbonyl, tri(C1-C4alkyl)silyl or tri(C1-C4alkyl)silyloxy,X is optionally substituted C1-C3alkylene,Y is optionally substituted C1-C3allcylene or optionally substituted C2-C3alkenyleneandG represents hydrogen (a) or represents one of the groups in whichE represents a metal ion or an ammonium ion,L represents oxygen or sulphur andM represents oxygen or sulphur,R11 represents in each case optionally halogen- or cyano-substituted C1-C20-alkyl, C2-C20-alkenyl, C1-C8-alkoxy-C1-C8-alkyl, C1-C8-alkylthio-C1-C8-alkyl or poly-C1-C8-alkoxy-C1-C8-alkyl or represents optionally halogen-, C1-C6-alkyl- or C1-C6-alkoxy-substituted C3-C8-cycloalkyl in which optionally one or two not directly adjacent methylene groups are replaced by oxygen and/or sulphur, represents optionally halogen-, cyano-, nitro-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C6-haloalkyl-, C1-C6-haloalkoxy-, C1-C6-alkylthio- or C1-C6-alkylsulphonyl-substituted phenyl,represents optionally halogen-, nitro-, cyano-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C6-haloalkyl- or C1-C6-haloalkoxy-substituted phenyl-C1-C6-alkyl,represents optionally halogen- or C1-C6-alkyl-substituted 5- or 6-membered hetaryl having one or two heteroatoms from the group consisting of oxygen, sulphur and nitrogen,represents optionally halogen- or C1-C6-alkyl-substituted phenoxy-C1-C6-alkyl orrepresents optionally halogen-, amino- or C1-C6-alkyl-substituted 5- or 6-membered hetaryloxy-C1-C6-alkyl having one or two heteroatoms from the group consisting of oxygen, sulphur and nitrogen,R22 represents in each case optionally halogen- or cyano-substituted C1-C20-alkyl, C2-C20-alkenyl, C1-C8-alkoxy-C2-C8-alkyl or poly-C1-C8-alkoxy-C2-C8-alkyl, represents optionally halogen-, C1-C6-alkyl- or C1-C6-alkoxy-substituted C3-C8-cycloalkyl orrepresents in each case optionally halogen-, cyano-, nitro-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C6-haloalkyl- or C1-C6-haloalkoxy-substituted phenyl or benzyl,R33 represents optionally halogen-substituted C1-C8-alkyl or in each case optionally halogen-, C1-C6-alkyl-, C1-C6-alkoxy-, C1-C4-haloalkyl-, C1-C4-haloalkoxy-, cyano- or nitro-substituted phenyl or benzyl,R44 and R55 independently of one another represent in each case optionally halogen-substituted C1-C8-alkyl, C1-C8-alkoxy, C1-C8-alkylamino, di(C1-C8-alkyl)amino, C1-C8-alkylthio or C3-C8-alkenylthio or represent in each case optionally halogen-, nitro-, cyano-, C1-C4-alkoxy-, C1-C4-haloalkoxy-, C1-C4-alkylthio-, C1-C4-halo-alkylthio-, C1-C4-alkyl- or C1-C4-haloalkyl-substituted phenyl, phenoxy or phenyl-thio,R66 and R77 independently of one another represent hydrogen, represent in each case optionally halogen- or cyano-substituted C1-C8-alkyl, C3-C8-cycloalkyl, C1-C8-alkoxy, C3-C8-alkenyl or C1-C8-alkoxy-C2-C8-alkyl, represent in each case optionally halogen-, C1-C8-alkyl-, C1-C8-haloalkyl- or C1-C8-alkoxy-substituted phenyl or benzyl or together represent an optionally C1-C6-alkyl-substituted C3-C6-alkylene radical in which optionally one methylene group is replaced by oxygen or sulphuras insecticides and/or acaricides and/or fungicides.
비사이클릭 1,3-디온 및 살충제, 살비제 및/또는 살진균제로서의 그의 용도본 발명은 살충제 및/또는 살비제 및/또는 살진균제로서의 하기 화학식 (I)의 화합물의 용도에 관한 것이다: 상기 식에서, R1, R2, R3, R4, R5, R6, Y, X 및 G는 명세서에 정의된 바와 같다.살충제 및/또는 살비제 및/또는 살진균제로서의 하기 화학식 (I)의 화합물의 용도:상기 식에서,R1은 메틸, 에틸, n-프로필, 이소-프로필, 사이클로프로필, 할로메틸, 할로에틸, 할로겐, 비닐, 에티닐, 메톡시, 에톡시, 할로메톡시 또는 할로에톡시를 나타내고,R2 및R3은 독립적으로 수소, 할로겐, C1-C6알킬, C1-C6할로알킬, C1-C6알콕시, C1-C6할로알콕시, C2-C6알케닐, C2-C6할로알케닐, C2-C6알키닐, C3-C6알케닐옥시, C3-C6할로알케닐옥시, C3-C6알키닐옥시, C3-C6사이클로알킬, C1-C6알킬티오, C1-C6알킬설피닐, C1-C6알킬설포닐, C1-C6알킬설포닐옥시, C1-C6할로알킬설포닐옥시, 시아노, 니트로, 임의로 치환된 페닐 또는 임의로 치환된 헤테로아릴을 나타내나, 단 R2 및 R3중 적어도 하나는 임의로 치환된 페닐 또는 임의로 치환된 헤테로아릴을 나타내고,R4는 수소, 메틸, 에틸, n-프로필, 이소-프로필, 할로메틸, 할로에틸, 할로겐, 비닐, 에티닐, 메톡시, 에톡시, 할로메톡시 또는 할로에톡시를 나타내며, R5 및 R6은 독립적으로 수소, C1-C6알킬, C2-C6알케닐, C2-C6알키닐, C1-C6할로알킬, C2-C6할로알케닐, C1-C6알콕시, C3-C6알케닐옥시, C3-C6할로알케닐옥시, C3-C6알키닐옥시, C1-C4알콕시C1-C4알킬, C1-C4알콕시C1-C4알콕시, C1-C4알콕시C1-C4알콕시C1-C4알킬, C1-C6알킬티오, C1-C4알킬티오C1-C4알킬, C1-C4알킬설피닐, C1-C4알킬설피닐C1-C4알킬, C1-C4알킬설포닐, C1-C4알킬설포닐C1-C4알킬, 하이드록시-C1-C4알킬, C1-C6할로알콕시C1-C4알킬, C3-C6알케닐옥시C1-C4알킬, C3-C6할로알케닐옥시C1-C4알킬, C3-C6알키닐옥시C1-C4알킬, C1-C6시아노알킬, C1-C4시아노알콕시, C1-C4시아노알콕시C1-C4알킬, 하이드록시, C1-C6알킬카보닐, 카복시, C1-C6알콕시카보닐, C1-C6알킬아미노카보닐, 디-C1-C6알킬카보닐, 트리(C1-C4알킬)실릴 또는 트리(C1-C4알킬)실릴옥시를 나타내고,X는 임의로 치환된 C1-C3알킬렌을 나타내며,Y는 임의로 치환된 C1-C3알킬렌 또는 임의로 치환된 C2-C3알케닐렌을 나타내고,G 수소 (a)를 나타내거나, 하기 그룹중의 하나를 나타내며,여기에서,E는 금속 이온 또는 암모늄 이온을 나타내고,L은 산소 또는 황을 나타내며,M은 산소 또는 황을 나타내고,R11은 각 경우 임의로 할로겐- 또는 시아노-치환된 C1-C20-알킬, C2-C20-알케닐, C1-C8-알콕시-C1-C8-알킬, C1-C8-알킬티오-C1-C8-알킬 또는 폴리-C1-C8-알콕시-C1-C8-알킬을 나타내거나,임의로 1 또는 2개의 직접 인접하지 않은 메틸렌 그룹이 산소 및/또는 황으로 대체되고 임의로 할로겐-, C1-C6-알킬- 또는 C1-C6-알콕시-치환된 C3-C8-사이클로알킬을 나타내거나,임의로 할로겐-, 시아노-, 니트로-, C1-C6-알킬-, C1-C6-알콕시-, C1-C6-할로알킬-, C1-C6-할로알콕시-, C1-C6-알킬티오- 또는 C1-C6-알킬설포닐-치환된 페닐을 나타내거나,임의로 할로겐-, 니트로-, 시아노-, C1-C6-알킬-, C1-C6-알콕시-, C1-C6-할로알킬- 또는 C1-C6-할로알콕시-치환된 페닐-C1-C6-알킬을 나타내거나,임의로 할로겐- 또는 C1-C6-알킬-치환되고 산소, 황 및 질소로 구성된 그룹중에서 선택되는 1 또는 2개의 헤테로원자를 가지는 5- 또는 6-원 헤트아릴을 나타내거나,임의로 할로겐- 또는 C1-C6-알킬-치환된 페녹시-C1-C6-알킬을 나타내거나, 임의로 할로겐-, 아미노- 또는 C1-C6-알킬-치환되고 산소, 황 및 질소로 구성된 그룹중에서 선택되는 1 또는 2개의 헤테로원자를 가지는 5- 또는 6-원 헤트아릴옥시-C1-C6-알킬을 나타내며,R22는 각 경우 임의로 할로겐- 또는 시아노-치환된 C1-C20-알킬, C2-C20-알케닐, C1-C8-알콕시-C2-C8-알킬 또는 폴리-C1-C8-알콕시-C2-C8-알킬을 나타내거나,임의로 할로겐-, C1-C6-알킬- 또는 C1-C6-알콕시-치환된 C3-C8-사이클로알킬을 나타내거나,각 경우 임의로 할로겐-, 시아노-, 니트로-, C1-C6-알킬-, C1-C6-알콕시-, C1-C6-할로알킬- 또는 C1-C6-할로알콕시-치환된 페닐 또는 벤질을 나타내고,R33은 임의로 할로겐-치환된 C1-C8-알킬 또는 각 경우 임의로 할로겐-, C1-C6-알킬-, C1-C6-알콕시-, C1-C4-할로알킬-, C1-C4-할로알콕시-, 시아노- 또는 니트로-치환된 페닐 또는 벤질을 나타내며,R44 및 R55는 서로 독립적으로 각 경우 임의로 할로겐-치환된 C1-C8-알킬, C1-C8-알콕시, C1-C8-알킬아미노, 디(C1-C8-알킬)아미노, C1-C8-알킬티오 또는 C3-C8-알케닐티오를 나타내거나, 각 경우 임의로 할로겐-, 니트로-, 시아노-, C1-C4-알콕시-, C1-C4-할로알콕시-, C1-C4-알킬티오-, C1-C4-할로알킬티오-, C1-C4-알킬- 또는 C1-C4-할로알킬-치환된 페닐, 페녹시 또는 페닐티오를 나타내고,R66 및 R77은 서로 독립적으로 수소를 나타내거나, 각 경우 임의로 할로겐- 또는 시아노-치환된 C1-C8-알킬, C3-C8-사이클로알킬, C1-C8-알콕시, C3-C8-알케닐 또는 C1-C8-알콕시-C2-C8-알킬을 나타내거나, 각 경우 임의로 할로겐-, C1-C8-알킬-, C1-C8-할로알킬- 또는 C1-C8-알콕시-치환된 페닐 또는 벤질을 나타내거나, 함께, 임의로 하나의 메틸렌 그룹이 산소 또는 황으로 대체되고 임의로 C1-C6-알킬-치환된 C3-C6-알킬렌 래디칼을 나타낸다.