Pesticidal 1-aryl-3-amidoxime-pyrazole derivatives1-Arylpyrazole-3-substituted-amidoxime derivatives of formula (Ia) or (Ib):  or salts thereof, wherein the various symbols are as defined in the description, and pesticidal compositions thereof, processes for their preparation, and methods for their use for the control of arthropods (including insects and arachnids) and helminths (including nematodes). A compound of formula (Ia) or (Ib): [Image] wherein: R1 is aryl unsubstituted or substituted by one or more R15 radicals; or is R10 or R19; X and Y are each independently H, (C3-C6)-alkenyl, (C3-C6)-haloalkenyl, (C3-C6)-alkynyl, (C3-C6)-haloalkynyl, (C3-C7)-cycloalkyl, ?(C1-C4)-alkyl-(C3-C7)-cycloalkyl, ?CO2?(C1-C6)-alkyl, CONR7R8, CONR8R9, ?CO2?(CH2)qR7, ?(CH2)qR7, ?(CH2)qR10, COR8, SO2R13 or COR17; or (C1-C6)-alkyl unsubstituted or substituted by one or more R11 radicals; W is N, C?CH3 or C-halogen; R2 is hydrogen, CH3 or halogen; R3 is halo, (C1-C3)-alkyl, (C1-C3)-haloalkyl, (C1-C3)-haloalkoxy, S(O)p?(C1-C3)-haloalkyl or SF5; R4 is H, (C3-C6)-alkenyl, (C3-C6)-haloalkenyl, (C3-C6)-alkynyl, (C3-C6)-haloalkynyl, (C3-C7)-cycloalkyl, ?CO2?(C1-C6)-alkyl, ?CO2?(C3-C7)-cycloalkyl, ?CO2?(C1-C4)-alkyl-(C3-C7)-cycloalkyl, ?CO2?(C3-C6)-alkenyl, ?CO2?(CH2)qR7, CONR8R9, ?CO2?(CH2)qR10, ?(CH2)qR7, ?(CH2)qR10, COR8 or COCH2O?(C1-C4)-alkyl; or (C1-C6)-alkyl unsubstituted or substituted by one or more R11 radicals; R5 is H, (C2-C6)-alkynyl, ?CO2?(C1-C6)-alkyl, (C3-C7)-cycloalkyl or ?SO2R12; or (C1-C6)-alkyl, (C2-C6)-alkenyl or CO?(C1-C6)-alkyl which last three mentioned groups are unsubstituted or substituted by one or more R11 radicals; R6 and R13 are each independently (C1-6)-alkyl, (C1-C6)-haloalkyl, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl or (C3-C7)-cycloalkyl; R7 is phenyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, CN, NO2, S(O)qR13 and NR9R14; R8 is H, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C3-C7)-cycloalkyl, ?(C1-C4)-alkyl-(C3-C7)-cycloalkyl, ?(CH2)qR7 or ?(CH2)qR10; R9 and R14 are each independently H, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C3-C7)-cycloalkyl or ?(C1-C4)-alkyl-(C3-C7)-cycloalkyl; or R8 and R9 together with the attached N atom form a five- or six-membered saturated ring which optionally contains an additional hetero atom in the ring which is selected from O, S and N, the ring being unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl and halogen; R10 is heterocyclyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C4)-alkyl, (C1-C4)-haloalkyl, (C1-C4)-alkoxy, S(O)pR13, OH and oxo; R11 is halogen, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, (C3-C7)-cycloalkyl, S(O)pR13, ?CO2?(C1-C6)-alkyl, ?O(C?O)?(C1-C6)-alkyl, CO?(C1-C6)-alkyl, CO?(C1-C6)-haloalkyl, NR8R9, CONR8R9, SO2NR8R9, OH, CN, NO2, OR7, NR8COR14, NR8SO2R13 or OR10; R12 is (C3-C7)-cycloalkyl, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl or R10; or phenyl unsubstituted or substituted by one or more radicals selected from R15; or is (C1-6)-alkyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-6)-alkoxy, (C1-6)-haloalkoxy, (C3-6)-alkenyloxy, (C3-C6)-haloalkenyloxy, (C3-C6)-alkynyloxy, (C3-C6)-haloalkynyloxy, (C3-C7)-cycloalkyl, S(O)pR7, S(O)pR10, S(O)pR13, CN, NO2, OH, COR8, NR8COR14, NR8SO2R13, CONR8R9, NR8R9, OR7, OR10, R16, R10 and CO2R8; R15 is halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, CN, NO2, S(O)pR13, NR8R9, COR13, COR7, CONR8R9, SO2NR8R9, R7, SF5, OH, OR7, R18, OR18, SO3H or (C1-C6)-alkylideneimino; R16 is phenyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, CN, NO2, S(O)pR13, NR8R9, COR13, COR7, CONR8R9, SO2NR8R9, OH, SO3H and (C1-C6)-alkylideneimino; R17 is (C1-C6)-alkyl which is substituted by (C1-C6)-alkoxy, S(O)p?(C1-C6)-alkyl or S(O)p?(C1-C6)-haloalkyl; R18 is a heteroaromatic radical selected from the group consisting of pyridyl, pyrimidinyl, pyridazinyl, pyrazinyl, triazinyl, thienyl, thiazolyl, thiadiazolyl, oxazolyl, isoxazolyl, furyl, pyrrolyl, pyrazolyl, imidazolyl and triazolyl, which groups are unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl and (C1-C6)-alkoxy; R19 is a heteroaromatic radical selected from the group consisting of pyridyl, pyrimidinyl, pyridazinyl, pyrazinyl, triazinyl, thienyl, thiazolyl, thiadiazolyl, oxazolyl, isoxazolyl, furyl, pyrrolyl, pyrazolyl, imidazolyl and triazolyl, which is unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl and (C1-C6)-alkoxy, and which heteroaromatic radical is substituted by R7, R18 or OR7; m is 1 or 2; n and p are each independently zero, one or two; q is zero or one; and each heterocyclyl in the above-mentioned radicals is independently a heterocyclic radical having 3 to 6 ring atoms and 1, 2 or 3 hetero atoms in the ring selected from the group consisting of N, O and S; or a pesticidally acceptable salt thereof. 
살충성 1-아릴-3-아마이독심-피라졸 유도체본 발명은 하기 화학식 Ia 또는 Ib의 1-아릴피라졸 3-치환된 아마이독심 유도체 또는 이의 염, 및 이의 살충 조성물, 이의 제조방법, 및 절지동물(곤충류 및 진드기류를 포함함) 및 기생충(선충류을 포함함)을 구제하기 위한 이의 용도에 관한 것이다: 화학식 Ia  화학식 Ib  상기 식에서, 다양한 기호는 본 명세서에 정의된 바와 같다.하기 화학식 Ia 또는 Ib의 화합물 또는 이의 살충학적으로 허용가능한 염: 화학식 Ia [이미지] 화학식 Ib [이미지] 상기 식에서, R1은 비치환되거나 또는 하나 이상의 R15 라디칼로 치환된 아릴, 또는 R10 또는 R19이고; X 및 Y는 각각 독립적으로 H, (C3-C6)-알켄일, (C3-C6)-할로알켄일, (C3-C6)-알카인일, (C3-C6)-할로알카인일, (C3-C7)-사이클로알킬, -(C1-C4)-알킬-(C3-C7)-사이클로알킬, -CO2-(C1-C6)-알킬, CONR7R8, CONR8R9, -CO2-(CH2)qR7, -(CH2)qR7, -(CH2)qR10, COR8, SO2R13 또는 COR17이거나, 또는 비치환되거나 또는 하나 이상의 R11 라디칼로 치환된 (C1-C6)-알킬이고; W는 N, C-CH3 또는 C-할로겐이고; R2는 수소, CH3 또는 할로겐이고; R3은 할로, (C1-C3)-알킬, (C1-C3)-할로알킬, (C1-C3)-할로알콕시, S(O)p-(C1-C3)-할로알킬 또는 SF5이고; R4는 H, (C3-C6)-알켄일, (C3-C6)-할로알켄일, (C3-C6)-알카인일, (C3-C6)-할로알카인일, (C3-C7)-사이클로알킬, -CO2-(C1-C6)-알킬, -CO2-(C3-C7)-사이클로알킬, -CO2-(C1-C4)-알킬-(C3-C7)-사이클로알킬, -C02-(C3-C6)-알켄일, -C02-(CH2)qR7, CONR8R9, -CO2-(CH2)qR10, -(CH2)qR7, -(CH2)qR10, COR8 또는 COCH20-(C1-C4)-알킬, 또는 비치환되거나 또는 하나 이상의 R11 라디칼로 치환된 (C1-C6)-알킬이고; R5는 H, (C2-C6)-알카인일, -CO2-(C1-C6)-알킬, (C3-C7)-사이클로알킬 또는 -SO2R12, 또는 (C1-C6)-알킬, (C2-C6)-알켄일 또는 CO-(C1-C6)-알킬이고, 이중 (C1-C6)-알킬, (C2-C6)-알켄일 또는 CO-(C1-C6)-알킬은 비치환되거나 또는 하나 이상의 R11 라디칼로 치환되고; R6 및 R13은 각각 독립적으로 (C1-C6)-알킬, (C1-C6)-할로알킬, (C2-C6)-알켄일, (C2-C6)-할로알켄일, (C2-C6)-알카인일, (C2-C6)-할로알카인일 또는 (C3-C7)-사이클로알킬이고; R7은 비치환되거나 또는 할로겐, (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-알콕시, (C1-C6)-할로알콕시, CN, N02, S(O)pR13 및 NR9R14로 이루어진 군으로부터 선택된 하나 이상의 라디칼로 치환된 페닐이고; R8은 H, (C1-C6)-알킬, (C1-C6)-할로알킬, (C3-C7)-사이클로알킬, -(C1-C4)-알킬-(C3-C7)-사이클로알킬, -(CH2)qR7 또는 -(CH2)qR10이고; R9 및 R14는 각각 독립적으로 H, (C1-C6)-알킬, (C1-C6)-할로알킬, (C3-C7)-사이클로알킬 또는 -(C1-C4)-알킬-(C3-C7)-사이클로알킬이거나; 또는 R8 및 R9는 부착된 N 원자와 함께, O, S 및 N으로 이루어진 군으로부터 선택된 추가의 헤테로원자를 고리 중에 선택적으로 함유하는 5원 또는 6원 포화 고리를 형성하고, 이때 고리는 비치환되거나 또는 할로겐, (C1-C6)-알킬, (C1-C6)-할로알킬 및 할로겐으로 이루어진 군으로부터 선택된 하나 이상의 라디칼로 치환되고; R10은 비치환되거나 또는 할로겐, (C1-C4)-알킬, (C1-C4)-할로알킬, (C1-C4)-알콕시, S(O)pR13, OH 및 옥소로 이루어진 군으로부터 선택된 하나 이상의 라디칼로 치환된 헤테로사이클릴이고; R11은 할로겐, (C1-C6)-알콕시, (C1-C6)-할로알콕시, (C3-C7)-사이클로알킬, S(O)pR13, -CO2-(C1-C6)-알킬, -O(C=O)-(C1-C6)-알킬, CO-(C1-C6)-알킬, CO-(C1-C6)-할로알킬, NR8R9, CONR8R9, SO2NR8R9, OH, CN, N02, OR7, NR8COR14, NR8SO2R13 또는 OR10이고; R12는 (C3-C7)-사이클로알킬, (C2-C6)-알켄일, (C2-C6)-할로알켄일 또는 R10이거나, 비치환되거나 또는 R15로부터 선택된 하나 이상의 라디칼로 치환된 페닐이거나, 또는 비치환되거나 또는 할로겐, (C1-C6)-알콕시, (C1-C6)-할로알콕시, (C3-C6)-알켄일옥시, (C3-C6)-할로알켄일옥시, (C3-C6)-알카인일옥시, (C3-C6)-할로알카인일옥시, (C3-C7)-사이클로알킬, S(O)pR7, S(O)pR10, S(O)pR13, CN, NO2, OH, COR8, NR8COR14, NR8SO2R13, CONR8R9, NR8R9, OR7, OR10, R16, R10 및 CO2R8로 이루어진 군으로부터 선택된 하나 이상의 라디칼로 치환된 (C1-C6)-알킬이고; R15는 할로겐, (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-알콕시, (C1-C6)-할로알콕시, CN, NO2, S(O)pR13, NR8R9, COR13, COR7, CONR8R9, SO2NR8R9, R7, SF5, OH, OR7, R18, OR18, SO3H 또는 (C1-C6)-알킬리덴이미노이고; R16은 비치환되거나 또는 할로겐, (C1-C6)-알킬, (C1-C6)-할로알킬, (C1-C6)-알콕시, (C1-C6)-할로알콕시, CN, NO2, S(O)pR13, NR8R9, COR13, COR7, CONR8R9, SO2NR8R9, OH, S03H 및 (C1-C6)-알킬리덴이미노로 이루어진 군으로부터 선택된 하나 이상의 라디칼로 치환된 페닐이고; R17은 (C1-C6)-알콕시, S(O)p-(C1-C6)-알킬 또는 S(O)p-(C1-C6)-할로알킬로 치환된 (C1-C6)-알킬이고; R18은 비치환되거나 또는 할로겐, (C1-C6)-알킬, (C1-C6)-할로알킬 및 (C1-C6)-알콕시로 이루어진 군으로부터 선택된 하나 이상의 라디칼로 치환된, 피리딜, 피리미딘일, 피리다진일, 피라진일, 트라이아진일, 티에닐, 티아졸릴, 티아다이아졸릴, 옥사졸릴, 아이속사졸릴, 퓨릴, 피롤릴, 피라졸릴, 이미다졸릴 및 트라이아졸릴로 이루어진 군으로부터 선택된 헤테로방향족 라디칼이고; R19는 비치환되거나 또는 할로겐, (C1-C6)-알킬, (C1-C6)-할로알킬 및 (C1-C6)-알콕시로 이루어진 군으로부터 선택된 하나 이상의 라디칼로 치환된, 피리딜, 피리미딘일, 피리다진일, 피라진일, 트라이아진일, 티에닐, 티아졸릴, 티아다이아졸릴, 옥사졸릴, 아이속사졸릴, 퓨릴, 피롤릴, 피라졸릴, 이미다졸릴 및 트라이아졸릴로 이루어진 군으로부터 선택된 헤테로방향족 라디칼이고, 이때 헤테로방향족 라디칼은 R7, R18 또는 OR7로 치환되고; m은 1 또는 2이고; n 및 p는 각각 독립적으로 0, 1 또는 2이고; q는 0 또는 1이고; 상기 언급된 라디칼에서 헤테로사이클릴은 독립적으로 3 내지 6개의 고리원자를 갖고 N, O 및 S로 이루어진 군으로부터 선택된 1, 2 또는 3개의 헤테로원자를 고리 중에 갖는 헤테로환 라디칼이다.