The daughter of Louis Charles d'Albert, Dukes of Luynes (1620–1690) and his second wife Anne de Rohan (1644–1684), she had five full siblings.
Fiică a lui Louis Charles d'Albert, Duce de Luynes (1620–1690) și a celei de-a doua soții, Anne de Rohan (1644–1684), ea a avut cinci frați.