Semiconductor diodes are made of two types of semiconductors connected to each other. One type has atoms with extra electrons (called the n-side). The other type has atoms that want electrons (called the p-side). Because of this, the electricity will flow easily from the side with too many electrons to the side with too few. However, electricity will not flow easily in the reverse direction. These different types are made by doping (semiconductor). Silicon with arsenic dissolved in it makes a good n-side semiconductor, while silicon with aluminum dissolved in it makes a good p-side semiconductor. Other chemicals can also work.
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