Structure of Organoantimony Compounds [C<sub>5</sub>H<sub>4</sub>Mn(CO)<sub>3</sub>]Sb, (4-Me<sub>2</sub>NC<sub>6</sub>H<sub>4</sub>)<sub>3</sub>SbI<sub>2</sub>, Ph<sub>3</sub>Sb[OC(O)C<sub>6</sub>H<sub>3</sub>(NO<sub>2</sub>)<sub>2</sub>-3,5]<sub>2</sub>, (3-MeC<sub>6</sub>H<sub>4</sub>)<sub>3</sub>Sb[OC(O)C<sub>6</sub>H<sub>3</sub>(NO<sub>2</sub>)<sub>2</sub>-3,5]<sub>2</sub>×PhH, and (3-FC<sub>6</sub>H<sub>4</sub>)<sub>3</sub>Sb[OC(O)C<sub>6</sub>H<sub>3</sub>(NO<sub>2</sub>)<sub>2</sub>-3,5]<sub>2</sub>×PhH
The structure of five organoantimony compounds [C5H4Mn(CO)3]Sb (1), (4-Me2NC6H4)3SbI2 (2), Ph3Sb[OC(O)C6H3(NO2)2-3,5]2 (3), (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2×PhH (4), and (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2×PhH (5) was determined by X-ray diffraction analysis. X-ray diffraction of the compounds was carried out on an automatic four-circle diffractometer D8 Quest Bruker (Мо Кα , λ = 0.71073 Å, 293 К. [C5H4Mn(CO)3]Sb (1), crystal size 0.53×0.4×0.22 mm, R -3, a = 19.221(6), b = 19.221(6), c = 11.935(4) Å, a = 90.00, β = 90.00, g = 120.00 deg., V = 3818.6(17) Å3, Z = 2, R 1 = 0.0484, wR 2 = 0.0900. (4-Me2NC6H4)3SbI2 (2), crystal size 0.26 × 0.19 × 0.16 mm, Ia -3, a = 22.238(13), b = 22.238(13), c = 22.238(13) Å, a = 90.00, β = 90.00, g = 90.00 deg., V = 10997(19) Å3, Z = 48, R 1 = 0.0372, wR 2 = 0.0855. Ph3Sb[OC(O)C6H3(NO2)2-3,5]2 (3), crystal size 0.39×0.29×0.19 mm, P -1, a = 11.985(8), b = 12.186(7), c = 14.292(10) Å, a = 72.30(3), β = 69.64(3), g = 61.79(3) deg., V = 1699.8(19) Å3, Z = 2, R 1 = 0.0388, wR 2 = 0.1246. (3-MeC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2×PhH (4), crystal size 0.2 × 0.17 × 0.07 mm, P -1, a = 12.654(8), b = 13.217(9), c = 14.672(13) Å, a = 64.42(3), β = 79.73(3), g = 65.66(2) deg., V = 2017(3) Å3, Z = 2, R 1 = 0.0350, wR 2 = 0.0870. (3-FC6H4)3Sb[OC(O)C6H3(NO2)2-3,5]2×PhH (5), crystal size 0.55×0.4×0.19 мм, P -1, a = 12.34(3), b = 12.95(2), c = 14.41(2) Å, a = 81.73(6), β = 66.94(10), g = 66.31(7) deg., V = 1940(6) Å3, Z = 2, R 1 = 0.0721, wR 2 = 0.1558.