COMPOSITION, STABILITY AND STRUCTURE СITRATES OF ZIRCONIUM (IV) IN THE AQUEOUS SOLUTIONS
By the methods of pH-measuring system and mathematical simulation of equilibria composition, stability and the share of the accumulation of the citrate complexes of zirconium (IV) in the aqueous solution with molar ratio the metal: ligand 1:1, 1:3 over a wide range of pH are determined. The authors carried out the quantum-chemical calculation of the structure of monocitrate of zirconium (IV) taking into account the second hydrated sphere.