DECOMPOSITION OF A NUMBER OF LIQUID EXPLOSIVES AND THEIR SOLUTIONS IN THE DETONATION WAVE
In article results of the collaborations which have been carried out on chair of chemistry and technology of organic compounds of nitrogen of the St. Petersburg institute of technology, in SKTB "Technolog" and at Institute of chemical physics of Russian Academy of Sciences, on research of critical diameters of a detonation of liquid explosives and their solutions in each other and in inert organic solvents are stated. Nitrates of alcohols (izopropylnitrate, glycerintrinitrate, propylenglycoldinitratе etc.), bisfluorodinitroethylformal, 1,6-diazido-2-acetoxyhexane, nitromethane were chosen as objects of research. The admissibility of use in forecasts of critical diameters of a detonation of energy of activation of the thermal disintegration, found at significantly smaller temperatures in a gas phase is shown. Possibility of identification of the component, conducting decomposition behind the front of a detonation wave, in solutions of two explosives and comparisons on the basis of it relative times of decomposition of components is shown also