ELECTRON VACANCY LOCALIZATION IN A SINGLE-MOLECULAR SWITCH BASED ON A TWELVE-NUCLEAR RHENIUM CLUSTER
Data of 13С NMR and quantum chemical methods is used to show that a change in the oxidation degree of 12-nuclear rhenium cluster complexes [Re12CS17(CN)6]n- from n = 6 to n = 8 leads to electron vacancy localization on the rhenium atoms surrounding the central carbon atom.