Raw cacao powder is the same as raw cocoa powder -- cacao and cocoa are used interchangeably to refer to the basic powder made from whole, roasted cacao beans that have been ground up.acao powder can be added to a variety of baked goods. You can also mix in a tablespoon or two of raw cacao with juices or smoothies, or try sprinkling it on top of frozen yogurt for a healthy way to add chocolate flavor.