Around the year 1530, Matches appeared in Europe. The first modern, self-igniting match was invented in 1805 by K. Chancel, assistant to Professor Louis Jacques Thénard of Paris, though. The head of the match was made of a mixture of potassium chlorate, sulfur, sugar, and rubber. They were ignited by dipping the tip of the match in a small asbestos bottle filled with sulfuric acid. This kind of match was quite expensive and its usage was dangerous, so Chancel's matches never gained much popularity.