The match finally ended with 10 men for both sides with Materazzi was himself sent off in the 104th minute .
Materazzi was involved in the infamous head butt incident with legendary Frenchman Zinedine Zidane in the 2006 World Cup final .
The match finally ended with 10 men for both sides with Materazzi , who was involved in the infamous head butt incident with legendary Frenchman Zinedine Zidane in the 2006 World Cup final , was himself sent off in the 104th minute .