What is meant by "vastness of space, which now filled a volume of a hundred million light years"? I am reading the book Cosmic biology: How life could evolve on other worlds (citation below) and do not understand the meaning of the following paragraph from page 4 (emphasis mine):

It took 200,000 years or more for the universe to cool to 2700 °C, a temperature at which the protons and neutron-proton aggregates could start capturing the free flying electrons to form the first atoms of hydrogen and helium.  As the dense fog of electrons condensed into newly formed atoms, the opaqueness cleared and photons could stream without interruption across the vastness of space, which now filled a volume of a hundred million light years.

I am under the assumption that a light-year is a unit of measurement for distance and spatial volume is expressed as though it fills a cube (e.g., 100 ly^3).  Even if this practice of denoting volume was unintentionally omitted, the claim does not satisfy my attempt to calculate the spherical volume:
Given 200,000 years of elapsed time since Big Bang -&gt; photons could have traveled a distance of 200,000 ly in any direction.
Formula for radius of a sphere: $$\frac{4}{ 3} \pi r ^ 3 = \frac43  \pi  (200,000 ^ 3) = 3.35\times 10^{16} ly.$$
This result is much larger than &quot;[one] hundred million light years.&quot;
Am I misreading this paragraph?

Irwin, Louis Neal, and Dirk Schulze-Makuch. Cosmic biology: How life could evolve on other worlds. Springer Science &amp; Business Media, 2010.
I think this is at best a weird typo, but more likely a confusion by the authors (who are not cosmologists or astronomers, but a biologist and a geologist).
The book is 10 years old, but our view of the timeline of the evolution of the Universe was pretty much the same then. Note that the calculation of the size of the Universe as a function of time is a bit more complicated than you assert, because it expands while photons are traveling.
The three number that the authors give — $200\,000\,\mathrm{yr}$, $2\,700\,^\circ\mathrm{C}$, and 100 million lightyears (Mlyr) — do not correspond to the same epochs, as I will discuss here:
Recombination began at t ~ 200,000 yr
The process the authors discuss is known as the recombination of hydrogen, followed by the decoupling of light from the gas. At an age of $200\,000\,\mathrm{yr}$, the Universe had cooled to $4\,500\,\mathrm{K}$, and atoms began to recombine. At this point, the region that is the observable Universe today had a radius of almost 30 Mlyr, i.e. a volume of some $10^5\,\mathrm{Mlyr}^3$. However, the observable Universe at that time was much smaller, because light hadn't traveled so far — the radius was less than half a Mlyr.
Photons decoupled at T ~ 2,700 ºC
The photons didn't decouple yet, though. Exactly when this happened is a somewhat extended period of time, but can be taken to be the time when the mean free path of a photon is of the order of the size of the observable Universe. This happened around when the Universe was $380\,000\,\mathrm{yr}$, at which time it had cooled to $3000\,\mathrm{K}$, or $2\,700\,^\circ\mathrm{C}$. At this time the radius of today's observable Universe was still only around 40 Mlyr, while the observable Universe at that time was still less than 1 Mlyr.
The diameter of the Universe reached 100 Myr much later
When the Universe was roughly half a million years old, the radius of today's observable Universe had expanded to 50 Mlyr, so its diameter was 100 Mlyr. But firstly, this was quite a lot later than the recombination/decoupling, and secondly it doesn't make much sense to refer to the size of today's observable Universe, since that had no physical significance at that time. The radius of the then's observable Universe didn't reach 100 Mlyr until the Universe was almost 20 million years old
Summary in a figure
The figure below shows how the progression of recombination, from ~100% ionized gas when the Universe was around $200\,000\,\mathrm{yr}$, to ~100% neutral gas when it was $\sim 400\,000\,\mathrm{yr}$. I calculated this by solving the Saha equation assuming a pure hydrogen gas, i.e. neglecting helium, but this is a minor contribution so I think it should be okay.
Along the line you see corresponding temperatures in red, and ratios between the photon mean free path and Hubble distance (~size of the Universe) in green. When this ratio is of order unity, photons decouple. The secondary $x$ axis show the corresponding redshift.