with further reference to fig1 a vessel 3 where the liquid mixture is to be prepared is provided with a syphon valve 1 . syphon valve 1 has an elongate tube 2 permanently mounted in its upper end and extending to the floor of vessel 3 . the acetone or octenol to be added to the liquid carbon dioxide , is introduced by the use of intermediate vessel 4 which is small in volume ( as compared to vessel 3 ) because the acetone or octenol is to be filled by weight . the working pressure of the intermediate vessel 4 should be equal to or higher than that of vessel 3 where the liquid mixture is to be prepared . intermediate vessel 4 is equipped with valves 5 and 6 . this allows the intermediate vessel 4 to be placed between the liquid mixture vessel 3 and a liquid carbon dioxide supply line to a tank 25 of liquid carbon dioxide . the vessel 3 where the liquid mixture is to be prepared is provided with a facility to determine its contents by weight . in the case of a high pressure vessel 3 , this can be achieved by placing the vessel 3 on a scale 8 . large bulk vessels can be weighed directly with strain gauges or indirectly by weighing the delivery vessels , before and after delivery . with suitable calibration , the liquid level in a vessel 3 can also be converted into a weight basis . an example will show the method , procedure and equipment to prepare a mixture in liquid carbon dioxide . a mixture of 5 % by weight of acetone in liquid carbon dioxide is to be prepared in a high pressure vessel 3 of 23 kg capacity . the quantity of acetone necessary for this mixture is 0 . 05 × 23 = 1 . 15 kg . acetone has a specific gravity at 20 ° c ., of 0 . 791 . therefore 1 . 15 kg represents 1 . 454 dm 3 of acetone . a standard 2 . 250 dm 3 stainless steel sampling vessel ( working pressure 12 . 5 mpa ) with two valves is a suitable intermediate vessel 4 to prepare this mixture . one valve 5 is suitably a ball valve to allow the introduction of the acetone with a suitable funnel and a second valve 6 is suitably a non - rotating stem valve equipped with a rupture disc 9 rated at a nominal bursting pressure of 13 . 1 mpa . after purging the intermediate vessel 4 with gaseous carbon dioxide , this carbon dioxide filled vessel 4 at atmospheric pressure is weighed . with a suitable funnel , a measured volume of 1 . 454 dm 3 of acetone is introduced in vessel 4 . it will be understood that at this stage intermediate vessel 4 is not connected between vessel 3 and supply line 7 and for introduction of the acetone is inverted for filling via valve 5 with use of a suitable funnel . the vessel 4 is weighed again . the amount of acetone in vessel 4 should be very close to 1 . 15 kg . a standard high pressure 23 kg vessel 3 with a syphon valve 1 , is placed under vacuum . the cylinder 3 is weighed under vacuum on scale 8 . the cylinder 3 should preferably remain on the scale 8 . as shown in fig1 the intermediate vessel 4 is connected by valve 5 to the evacuated carbon dioxide vessel 3 with a short 90 ° connection 10 , to keep the intermediate vessel 4 in a vertical position . this is to facilitate the introduction of the acetone in the intermediate vessel 4 into the evacuated carbon dioxide vessel 3 by the combined action of gravity and the vacuum in vessel 3 . the intermediate vessel 4 is connected by valve 6 to the liquid carbon dioxide supply line 7 . the line 7 may suitably be provided with pressure gauges ( not shown ) and a vacuum system ( not shown ) to vacuum and purge the supply line 7 as required . after opening syphon valve 1 of the evacuated carbon dioxide vessel 3 , the valve 5 of the intermediate vessel 4 closer to the evacuated carbon dioxide vessel 3 is opened . by the joint action of gravity and vacuum , the acetone is transferred from the intermediate vessel 4 into the evacuated carbon dioxide vessel 3 . after opening the second valve 6 of the intermediate vessel 4 , liquid carbon dioxide is allowed to flow into the evacuated carbon dioxide vessel 3 via intermediate vessel 4 . the liquid carbon dioxide introduction should be stopped when the total content in the vessel 3 is 23 kg . the actual amount of liquid carbon dioxide introduced can be calculated by the difference between the total weight and the weight of acetone . the final concentration of this mixture can be calculated from these values . the liquid carbon dioxide should preferably be introduced at very high flows , suitably at a flow rate of more than 0 . 5 kg / min ., to induce turbulence in the evacuated liquid carbon dioxide vessel 3 . this is to accelerate the mixing of the acetone and the liquid carbon dioxide . the evacuated carbon dioxide vessel 3 , which is now filled with the liquid mixture of acetone and liquid carbon dioxide , can then be disconnected from the filling system . as illustrated in fig2 the contents of this vessel 3 containing the mixture are about 90 % by weight liquid mixture 12 to 10 % gas 11 . at constant temperature , the pressure of the liquid mixture in the vessel 3 remains the same while the vessel 3 still contains the liquid mixture 12 . when the liquid mixture 12 is completely exhausted and vessel 3 contains only the gas phase 11 , the vessel 3 content is about 30 % by weight of the total mixture . from this moment on , the pressure starts to drop . generally , the vapor pressure of the chemical compounds to be dissolved in liquid carbon dioxide is lower than that of pure carbon dioxide . these chemical compounds concentrate in the liquid phase 12 . the gas phase 11 is a homogeneous gas mixture , of somewhat lower concentration , of these soluble chemical compounds in carbon dioxide . the gas phase 11 can be used as an insect attractant . the vessel 3 contains the liquid mixture 12 and by opening the syphon valve 1 , a homogeneous liquid mixture is available . the pressure in the gaseous head space 11 of the vessel 3 forces the liquid 12 into the bottom 13 of the tube 2 and up through the valve 1 . a constant liquid flow can be obtained from the liquid carbon dioxide mixture 12 in vessel 3 by means of a metering device 14 . if the liquid flow has to be changed , either a series of calibrated leaks or a fine metering valve 14 can be used . a constant liquid flow can also be obtained from the liquid carbon dioxide mixture 12 in vessel 3 by means of the system shown in fig3 . a pressure regulator 17 is located downstream of filter 15 and heating cartridge 16 if used . the required gas flow is obtained by adjusting the low pressure of pressure regulator 17 and the use of control valve 18 . the gas flow can be measured with a flowmeter 19 . a solenoid valve 20 can be used to deliver a pulsed , metered flow , of the insect attractant mixture . the solenoid valve 20 can be programmed with timer 21 . the timer 21 and solenoid valve 20 can be operated from a standard 110 v , 60 hz a . c . power supply 22 or more conveniently , for field operation , from a 12 c v d . c . standard lead acid car battery 23 . the continuous or pulsed flow of the insect attractant gas mixture is fed into a series of suitable insect traps 24 , such as &# 34 ; lard - can &# 34 ; trap 24 , arranged in grid configurations . the insects will collect in the traps for further disposal . metering of the liquid flow , either with calibrated leaks , metering valves or pressure regulator systems , requires the use of fine porosity filters 15 , typically 0 . 5 to 2 micrometers porosity . the filter 15 should be located immediately ahead of the liquid metering device 14 to reduce the possibility of malfunctioning by plugging with particulate matter potentially present in the liquid mixture . the vaporization of the metered liquid flow requires heat . the amount of heat necessary is the latent heat of vaporization . at 20 ° c . and 5 . 7 mpa the latent heat of vaporization of carbon dioxide is 153 kj / kg . the heat requirement to vaporize the liquid mixture 12 depends on the total liquid flowrate . this heat requirement can be supplied , and in most cases is supplied , by the surrounding atmosphere through the vessel wall , valve , tubing , etc . if this heat input is insufficient , the liquid mixture 12 in the vessel will start to cool down . as the mixture cools , the pressure drops and therefore the flow through the metering device 14 is reduced . in such case , provision may be made for a heating cartridge 16 to supply the additional heat requirement . this heating cartridge 16 should be located between the liquid filter 15 and the liquid metering device 14 . the vessel 3 may be a high pressure vessel in which the carbon dioxide remains liquified under its own vapor pressure , or it may be a low pressure vessel in which the liquid carbon dioxide is maintained in liquid state by cooling vessel 3 with a refrigeration unit .
a method and apparatus to prepare and deliver a gas mixture of constant composition of liquid chemical compounds soluble in liquid carbon dioxide to be used as an enhanced attractant for biting insects . the mixtures can be prepared in high pressure vessels where carbon dioxide remains liquified under its own vapor pressure or in low pressure vessels where carbon dioxide is kept liquid , at low pressure , by cooling it with a refrigeration unit . direct vaporization of the liquid mixture from the vessels results in a gas mixture of constant composition . this mixture is to be delivered in a continuous or pulsed flow to an insect trap . these baited insect traps are an ecological alternative to chemical insecticide methods of insect control currently in use .