the particular values and configurations discussed in these non - limiting examples can be varied and are cited merely to illustrate an embodiment of the present invention and are not intended to limit the scope of the invention . fig1 illustrates a schematic diagram 100 depicting a reaction between a dicarbonyl - compound and a complex of hydrazine . two cases 102 and 104 are illustrated in fig1 . in each case , the solid compounds were ball milled at room temperature in a ratio of 2 : 1 ( dicarbonyl - compound to hydrazine complex ) and a near quantitative yield was obtained . the 6 - oxo - 1 , 4 , 5 , 6 - tetrahydro - pyridazine - 3 - carbonic acid formed from the reaction of 2 - ketoglutaric acid and the hydrazine complex comprises a high melting solid ( i . e ., melting point within a range of approximately 106 ° c .– 198 ° c .). fig2 depicts a schematic diagram 200 depicting the treatment of hydrazine waste to glutamine or a derivative thereof , in accordance with a preferred embodiment of the present invention . the hydrogenization of pyridazine using 5 % pd / c can provide glutamine in a 45 % yield . although this pyridazine is not easily biodegraded , the present inventors believe that glutamine can be utilized as a plant nutrient or that it is easily biodegradable . glutamine can be specifically utilized as a source of energy and for nucleotide synthesis by all rapidly dividing cells . thus , rather than acting as an environmental hazard , glutamine or a derivative can actually benefit plants exposed to it during a hydrazine remediation process , as described herein . fig3 illustrates a schematic diagram 300 depicting a reaction of 2 - ketoglutataric acid , which provides a near quantitative conversion of hydrazine to a 6 - oxo - 1 , 4 , 5 , 6 - tetrahydro - pyridazine - 3 - carbonic acid , a preferred embodiment of the present invention . in general , the chemical transformation depicted in schematic diagram 300 of fig3 allows for the removal of hydrazine from aqueous solutions generated by the decontamination processes described herein . the reaction with concentrated hydrazine also can provide the desired product with some evolution of heat . the low solubility of the compound in water allows for the separation of most of this adduct by a simple filtration . the msds for 6 - oxo - 1 , 4 , 5 , 6 - tetrahydro - pyridazine - 3 - carbonic acid does not list any known acute toxicities and thus it should be a nonhazardous waste . however the ideal situation would be to find a method for the safe destruction or remediation of the 6 - oxo - 1 , 4 , 5 , 6 - tetrahydro - pyridazine - 3 - carbonic acid . the use of microbes ( e . g ., a pseudomonas species found in the soil ) as a method for the metabolism of a nitrogen - nitrogen bond can thus be implemented , in accordance with the methods and systems described herein . after about ten minutes thereafter , a white precipitate can be formed , which is generally characterized by nuclear magnetic resonance to be the expected product , 6 - oxo - 1 , 4 , 5 , 6 - tetrahydro - pyridazine - 3 - carbonic acid . the reaction generally appears to be a quantitative reaction with the aqueous hydrazine . fig4 depicts a schematic diagram 400 illustrating the reaction of mmh and udmh with 2 - ketoglutaric aid followed by hydrogenation , in accordance with a preferred embodiment of the present invention . the schematic diagram 400 depicted in fig4 can be implemented by adding a sample of the hydrazine derivative to a slight excess of an aqueous solution of 2 - ketoglutaric acid . note that the solution described herein ( i . e ., which includes a dicarbonyl - compound ) can be prepared as aqueous solution or a non - aqueous solution , depending on particular desired applications . thus , the use of an aqueous solution is not considered a limiting feature of the present invention . rather the use of an aqueous solution represents merely one possible embodiment of the present invention . non - aqueous solutions represent another possible embodiment of the present invention . fig5 illustrates a high - level flow chart 500 of operational steps , which can be implemented in accordance with a preferred embodiment of the present invention . as illustrated at block 502 , a solution can be prepared that includes , as indicated at next at block 504 , a dicarbonyl - compound . such a solution can be prepared in the form of a cleaning solution . the solution can be an aqueous solution or a non - aqueous solution . an example of a dicarbonyl - compound that can be utilized in accordance with the methods and systems of the present invention is a keto - acid , such as a 2 - ketoglutaric acid . once the solution has been prepared , it can provided for utilization in hydrazine remediation . as indicated next at block 506 , the solution as provided via processing of the operations described at blocks 502 and 504 can be applied to an object contaminated with a hydrazine group compound . application can occur , for example , through a rinsing of the hydrazine contaminated object with the solution that includes the dicarbonyl - compound . examples of hydrazine group compounds that may contaminate an object or area thereof can include simply hydrazine , mmh , or udmh . it can be appreciated by those skilled in the art that the application of the dicarbonyl compound solution to the hydrazine contaminated object and / or area ( e . g ., a hydrazine spill ) thereof can take place following an initial attempt at a physical removal of the hydrazine group compound from the object or area thereof . as indicated previously , wiping , sweeping , scraping , blowing , vacuuming , rinsing with water , and steam cleaning are all examples of physical methods for the removal of contaminants . such physical removal techniques can thus occur in tandem with the application of the dicarbonyl - compound solution described herein . a reaction can then occur , as illustrated at block 508 between the hydrazine group compound and the dicarbonyl - compound . as a result of this reaction , the hydrazine group compound is converted to a stable organic compound , as indicated at block 510 , in order to remediate the hydrazine group compound from the object . thus , based on the foregoing it can be appreciated that the present invention allows for the use of a solution of a dicarbonyl - compound ( e . g . 2 - ketoglutaric acid ) for the treatment of hydrazine waste . prior art solutions for the treatment of hydrazine generally involve solubilization and dilution processes . the hydrazine remediation methods and systems described herein do not only involve solubilization and dilution . rather , the present invention involves a conversion of hydrazine to a stable organic compound . such a conversion can occur after application of the dicarbonyl - compound solution through the use of solubilization and dilution processes , among others . note that the step of treating a stable organic compound with a metal catalyst and hydrogen to produce glutamine , can also includes the step of producing a derivative of glutamine , rather than simply glutamine . fig6 depicts a high - level flow chart 600 of operations illustrating logical operational steps , which can be implemented in accordance with a preferred embodiment of the present invention . once the stable organic compound has been created as a result of the reaction between hydrazine and the dicarbonyl - compound , the stable organic compound can be treated with a metal catalyst and hydrogen to produce glutamine and / or a derivative thereof . thus , as indicated at block 602 , treatment of the stable organic compound can be initiated . the compound ( or solid material formed thereof ) can be isolated as indicated at block 603 . a decision can be made , as indicated at block 604 , to determine whether or not the stable organic , should be treated at another location , or treated directly , as indicated by processes described at blocks 606 to 610 . if it is determined to isolate the stable organic compound for treatment at another location , then the operation indicated at block 610 can be processed elsewhere . as indicated at block 610 , any remaining material ( i . e ., the stable organic compound ) can simply be digested via soil microbes . if necessary , however , the stable organic compound can be treated with a metal catalyst and hydrogen as illustrated at block 606 , which follows decision block 604 . as depicted at block 606 , a reaction can occur between the metal catalyst and hydrogen and the stable organic compound . as a result of this reaction , glutamine or a glutamine derivative can be produced , as depicted at block 608 . finally , as illustrated at block 610 complete digestion with soil microbes can occur . for example , the reaction of hydrazine with a 2 - ketoglutaric acid , followed by hydrogenation , can yield glutamic acid , a compound , which has been utilized to enhance fertilizer use . a system for remediating hydrazine in accordance with the present invention thus generally includes a solution that can be formed from a dicarbonyl - compound , and an application mechanism for applying the solution to an object or area ( e . g ., a spill ) contaminated with a hydrazine group compound . a dicarbonyl - compound can be implemented as a solution ( e . g . an aqueous solution ), which can then be applied to an object or area contaminated with a hydrazine group compound . such a hydrazine group compound can include at least one of the following : hydrazine ( hz ), monomethylhdrazine ( mmh ), and 1 , 1 dimethylhydrazine ( udmh ). the application mechanism itself can be implemented as a rinsing mechanism for rinsing the object contaminated with the hydrazine group compound with the solution . such a rinsing mechanism can be , for example , a hose or other fluid delivery device and / or system . the application mechanism can also be implemented in the form of objects or devices such as sponges , pads , spray bottles , and so forth . a metal catalyst and hydrogen can thus be applied to the contaminated objects with the application mechanism to produce glutamine thereof . fig7 illustrates a plot 700 of experimental data , which can be collected in accordance with an alternative embodiment of the present invention . note that a graph 704 is associated with chart 702 , which depicts such experimental data . note that the experimental techniques utilized to collect the data depicted in fig7 represent merely one possible embodiment of the present invention . those skilled in the art can appreciate than many other embodiments can be implemented . an insulated reaction vessel can be utilized to insure that heat evolution will not be underestimated . a 1 - cup styrofoam ™ cup equipped with stir bar and thermometer , 75 ml of 2 - ketoglutaric acid solution can be added and stirred a few minutes before the addition of a 1 . 1 eq of hydrazine monohydrate . the temperature can be monitored at 30 sec to 1 - minute intervals for 15 minutes . after about 45 seconds , seed crystals of 6 - oxo - 1 , 4 , 5 , 6 - tetrahydropyridazin - 3 - carboxylic acid can be added to the solution ; otherwise two exotherms can be observed ( i . e ., one large temperature rise immediately and second smaller one after about 10 minutes associated with the heat of crystallization ). initial temperatures can be about 18 ° c ., and the highest final temperature can be approximately 84 ° c ., although the some boiling occurred in the mixing zone as the hydrazine can be added to the 41 . 5 % 2 - ketoglutarate solution . hydrazine monohydrate ( 98 %), deuterium oxide and dimehtylsulfoxide - d 6 can be utilized , along with 6 - oxo - 1 , 4 , 5 , 6 - tetrahydropyridazin - 3 - carboxylic acid ( 97 %) and 2 - ketoglutaric acid ( 98 %) to produce the following results . the reaction of solid 2 - ketoglutaric acid with hydrazine monohydrate can generally be produced as follows : a 2 - ketoglutarate ( 450 mg ) can be combined with hydrazine monohydrate ( 70 μl ), which produces heat immediately . extraction of the reaction residue with water may only partially dissolved the solid , and the solution provided an nmr spectrum consistent with unreacted starting material and the expected product . the remaining solid can be dissolved in a mixture of meoh , chloroform and dmso , and can possess nmr spectra consistent with the expected product . note that a product from one of the aforementioned reactions can be derived with n , n - bis ( trimethylsilyl ) trifluroacetamide at room temperature and analyzed by both ei and ci mass spectrometry . in the ei spectrum , several chromatographic peaks can be observed with the largest corresponding to the 6 - oxo - 1 , 4 , 5 , 6 - tetrahydropyridazin - 3 - carboxylic acid . one peak can be viewed for in a ci chromatogram with a mass spectrum dominated by 287 m / z ( m + 1 ). the mass balance of the product can be high and the melting point low , presumably owing to inclusion of the hydrazinium salt of the product . addition of a 10 % equivalent of 2 - ketoglutaric acid to consume excess hydrazine , and recrystalization from hot water can afford a material with the same melting point as the standard material , 194 – 196 ° c . nmr chemical shifts can vary with concentration and ph , and are generally identical to the standard material : h ( δ , d 2 o , meoh ref . 3 . 30 ppm , 300 mhz ) 2 . 56 ( 2h , t , j h - h 8 . 9 hz ), and 2 . 85 ( 2h , t , 8 . 9 hz ) ppm ; 13 c ( δ , d 2 o , meoh set to 49 . 0 ppm , 75 mhz ) 20 . 6 , 24 . 9 , 146 . 0 , 166 . 1 , and 170 . 9 ppm . the present invention offers a number of advantages . the removal of hydrazine according to the methods and systems described herein will allow for the remediation of hydrazine to useful by - products or biodegradable forms , which not only provide environmental benefits , but also reduces the cost of hydrazine waste disposal . the methods and systems described here can be utilized at airports , military facilities , and rocket launches and space vehicle - landing pads ( e . g ., the space shuttle ). in particular , the present invention can also find use in orbiting facilities such as the international space station in which hydrazine exposure can be problematic . the present invention has particularly useful applications to wash water cleanup and spill abatement . the embodiments and examples set forth herein are presented to best explain the present invention and its practical application and to thereby enable those skilled in the art to make and utilize the invention . those skilled in the art , however , will recognize that the foregoing description and examples have been presented for the purpose of illustration and example only . other variations and modifications of the present invention will be apparent to those of skill in the art , and it is the intent of the appended claims that such variations and modifications be covered . the description as set forth is not intended to be exhaustive or to limit the scope of the invention . many modifications and variations are possible in light of the above teaching without departing from the spirit and scope of the following claims . it is contemplated that the use of the present invention can involve components having different characteristics . it is intended that the scope of the present invention be defined by the claims appended hereto , giving full cognizance to equivalents in all respects .
methods of and systems for remediating hydrazine spills , solutions and hydrazine - contaminated objects including areas thereof . initially , an aqueous solution comprising a dicarbonyl - compound can be prepared . the aqueous solution can then be provided for application to an object contaminated with a hydrazine group compound . the hydrazine group compounds are converted to a stable organic compound as a result of a reaction of the dicarbonyl - compound and hydrazine group compound . conversion assists in the remediation of the hydrazine group compound from the object . the stable organic compound produced as a result of the reaction between the dicarbonyl - compound and hydrazine group compound can then be treated with a metal catalyst and hydrogen to produce glutamine or a derivative thereof . both the stable organic compound and glutamine can undergo microbiological degradation without further remedial intervention .