sucralose , or 4 , 1 ′, 6 ′- trichloro - 4 , 1 ′, 6 ′- trideoxygalactosucrose , a sweetener with a sweetness intensity several hundred times that of sucrose , is derived from sucrose by replacing the hydroxyl groups in the 4 , 1 ′, and 6 ′ positions with chlorine . synthesis of sucralose is technically challenging because of the need to selectively replace specific hydroxyl groups with chlorine , while preserving other hydroxyl groups including a highly reactive primary hydroxyl group . numerous approaches to this synthesis are known . sucralose from these and other methods of synthesis may be advantageously used for in the compositions and devices of this invention . such useful sucralose is not limited to any material obtained from any particular synthetic route . because of its intense sweetness , other advantageous sensory attributes , and its good stability in solution , sucralose may be advantageously used in the compositions and devices of the present invention . in addition to sucralose , other sweeteners may be used within the meaning of his in this invention . such sweeteners include aspartame , neotame , saccharin , cyclamate , acesulfame , thaumatin ( or katemfe ), neohesperidin , and other high intensity sweeteners with sufficient solubility in water or other food grade solvents . additional sweeteners suitable for the purposes of this invention include stevia ( extract of the leaf of stevia rebaudiana ); hernandulcin ( extract of phyla scaberrima ); monellin , an extract of the serendipity berry ( dioscorophyllum cumminsii ); brazzein , an extract of the fruit of pentadiplandra brazzeana ; and mogroside , from the fruit of siraitia grosvernorii . for the purposes of this invention , any of the aforementioned sweeteners may be used alone , or they may be used in combination with other his . sweetness intensity of the compositions of the present invention can of course be increased by increasing the concentration of sucralose to levels of up to 300 mg / ml . the actual level of sweetener in the concentrate or solution is determined by the sweetening needs of the intended product applications and the volume of material dispensed at each use . the sweeteners herein described may also be termed “ non - nutritive sweeteners .” although some of these sweeteners may be metabolized by the body and yield some slight nutrient value , any nutrient value will be quite small because the levels of ingestion of these sweeteners is quite low under normal circumstances . hence the term “ non - nutritive sweeteners ” is appropriate for these materials regardless of their metabolic fate . in preparing the spray sweetener according to the present invention , an appropriate amount of sucralose , other his , or a mixture thereof is dissolved in water , or another appropriate food grade solvent , such as , ethanol , to achieve the desired sweetness delivery amount . this produces a high intensity sweetener solution or concentrate . the specific concentration of his is determined in part by the intensity of the selected sweetener or sweeteners used and the amount of solution dispensed as an aerosol during use . the amount and coverage of the high intensity sweetener solution dispensed should be sufficient to provide uniform coverage of the solution over the surface of the food to which it is applied . however , the volume of solution dispensed should not be so great as to cause sogginess or other obvious alterations in the textural properties of the food to which it is applied . the composition of the present invention may utilize a single high intensity sweetener such as sucralose , or it may contain a combination of sweeteners such as sucralose and saccharin . when sucralose is used as the only his in the his solution , the concentration of sucralose is from about 0 . 01 to about 30 weight percent of the his solution , or from about 0 . 1 to about 5 weight percent of the his solution , or from about 0 . 2 to about 3 weight percent of the his solution . other high intensity sweeteners may of course be used at concentrations that will provide equivalent levels of sweetness . the amount of high intensity sweetener solution delivered to the food product is preferably about 0 . 1 ml to about 5 ml , more preferably about 0 . 2 ml to about 2 . 5 ml , and most preferably about 0 . 5 ml to about 1 . 5 ml . also important is avoiding foam generation on the surface of the treated food , as the foam is visually unappealing in many applications and often indicates less than uniform coverage of the high intensity sweetener solution . for the purposes of this invention , “ non - foam forming ” means that no foam from the application of the high intensity sweetener solution remains on the surface of the food for more than 10 seconds after application . to aid in preparing a non - foam forming composition an antifoam agent may be added to the sweetener solutions . examples of suitable antifoam agents include simethicone , dimethicone , polydimethylsiloxane , and mixtures thereof . the high intensity sweetener concentrate may contain only the his dissolved in a suitable solvent , or it may additionally include buffers , stabilizers , preservatives , flavors , and mixtures thereof . examples of sucralose solutions include those embodied in examples i through xii of u . s . pat . no . 5 , 384 , 311 , which is incorporated herein in entirety by reference . the his solution may be delivered by a spray device . such device includes pump - type or squeeze - type sprayer , or alternatively , incorporated into a pressurized aerosol container . the compositions embodied in this invention are free of added nutritive sweeteners . such nutritive sweeteners include , but are not limited to , sucrose , glucose , high fructose corn syrup , or fructose . as a result of the low sweetness potency of these sweeteners ( compared to his ), relatively little additional sweetness is provided by incorporating these nutritive sweeteners into the spray compositions that are dispensed in small volumes . frequently food ingredients , such as , flavors that may be used in this invention , contain some levels of nutritive sweeteners to serve as fillers or stabilizing agents . therefore , the compositions of this invention may contain small amounts of nutritive sweeteners introduced from other ingredients . it is contemplated that generally any nutritive sweetener introduced from other food ingredients will be less than about 5 to about 10 weight percent of the final composition . although nutritive sweeteners do not contribute substantially to the sweetness imparted by the compositions disclosed herein , inclusion of these nutritive sweeteners into the spray composition would provide an excellent substrate for the growth of many microorganisms . to control this susceptibility to microbial growth , there is a need to incorporate into nutritive sweetener containing spray compositions substantial levels of antimicrobial preservatives such as benzoic acid , sorbic acid , methyl paraben , propyl paraben , butyl paraben , and mixtures thereof . these antimicrobial preservatives have significant adverse taste impacts , contributing notes of bitterness or sourness . alternatively , pastuerization or sterilization techniques could be used to prevent microbial spoilage of sweetener spray compositions containing nutritive sweeteners . however , such techniques add cost and complexity to manufacturing operations , and the heat exposure resulting from these processes can also have adverse effects on taste of the sweetener composition . his spray compositions without added nutritive sweeteners thus provide a better tasting composition with less risk of microbial spoilage , in contrast to sweetener compositions that also contain nutritive sweeteners . sucralose is especially desirable for the compositions of this invention because of its resistance to attack by microorganisms . the amount of antimicrobial preservatives needed to attain adequate preservation in a sucralose solution can be reduced in comparison to the amount needed in a nutritive sweetener containing composition . a variety of mechanical approaches may be used to dispense the sweetener compositions described herein . one contemplated embodiment of the invention is dispensing the his solution from a squeeze bottle , which generates a spray by means of a pump handle or by a squeeze mechanism by which physical pressure is exerted on the container holding the sweetener composition , and the solution is expelled through a narrow orifice , creating a spray or aerosol . the above described squeeze bottle is distinguished from aerosol containers , in which a propellant is incorporated inside a pressure - resistant vessel in which the sweetener composition is also contained . a number of propellant gases may be used , including , but not limited to , propane , butane , carbon dioxide , compressed air , fluorocarbon derivatives , and mixtures thereof . the fluorocarbon derivatives are generally less suitable because of possible adverse environmental consequences of their use . the propellant and sweetener concentrate may be contained within the same chamber of the aerosol container . alternatively , the aerosol container may be partitioned into two or more separate chambers by the use flexible membranes or diaphragms . in this embodiment , the pressure of the propellant squeezes the membrane or diaphragm , thereby indirectly causing the sweetener composition to be under pressure . the invention of this disclosure includes the physical means of generating and dispersing a spray or aerosol as mentioned above , and include but are not limited to spray bottles , squeeze bottles , and pressurized or aerosol devices . one embodiment of the present invention is an aerosol spray that delivers the sweetness equivalent of one teaspoon of sugar each time the spray actuator is fully depressed or the pump spray handle depressed or the bottle squeezed . one teaspoon of sugar ( table sugar , or sucrose from a beet or cane source ) weighs about 4 g . since sucralose is about 600 times as sweet as table sugar , the amount of sucralose needed to provide equivalent sweetness is about 0 . 0067 g or 6 . 7 mg . if the amount of solution dispensed per use is designed to be 1 . 0 ml , then the concentration of sucralose would be 6 . 67 mg / ml , or 6 . 67 g / l ( 0 . 667 % weight / volume ). a 150 ml portion of water was placed in container , and 350 mg of sucralose was added , and the contents were stirred to dissolve . this yielded a high intensity sweetener concentrate containing about 2 . 3 mg / ml of sucralose . the solution so obtained was placed in a pump spray bottle ( ace hardware all purpose sprayer ). each full depression of the spray bottle handle dispensed a mean of 1 . 35 ml of the high intensity sweetener solution . the spray bottle so prepared was used to spray the solution onto a bowl of cereal ( cheerios ®, general mills , inc .) to which skim milk had been previously added . one depression of the spray bottle handle was made while the spray bottle nozzle was held about 20 cm from the cereal , and the spray bottle was rotated over the top of the bowl in a circular manner during dispensing of the sweetener . the cereal in the bowl was found to be lightly but pleasantly sweetened . in particular , the sweetness remained localized on the surface of the cereal , instead of becoming generally dispersed in the milk . a more microbiologically stable form of example 1 is prepared by adding 150 mg each of potassium sorbate and sodium benzoate to the solution prepared as described in example 1 , and then stirring to achieve dissolution of these materials . finally , 272 mg of anhydrous citric acid and 258 mg of sodium citrate dihydrate are added , and stirring is continued until all materials are fully dissolved . this composition is resistant to growth of spoilage microorganisms . a sucralose solution containing antimicrobial preservatives and a buffer system is prepared as described in example 2 . approximately 200 ml of solution are placed in an empty steel aerosol can . the can is then pressurized by the addition of a charge of liquid propane , and the can is sealed and fitted with a spray actuator . the orifice of the spray actuator is designed so that , when the can is fully charged with propellant , about 0 . 5 ml of solution is dispensed over a 5 second interval . approximately one cup of sliced , capped strawberries is placed in an open bowl . the actuator of the aerosol can is held about 10 cm above the surface of the strawberries , and the actuator is depressed for 5 seconds while the spray is gently directed over the entire surface of the fruit . the fruit is found to be evenly sweetened on the surface , and the addition of sweetener by this method does not result in powdered material on the surface of the fruit , or an excessive amount of moisture on the fruit . one liter of ingestible grade , non - denatured 70 % ethanol is placed into a large covered beaker . with gentle stirring , 6 . 67 g of sucralose are gradually added , and stirring is maintained until dissolution is complete . ethyl vanillin ( 1 g ) is then added , and dispersed in the solution by stirring . the solution is then dispensed into a pump - type spray dispenser bottle as described in example 1 . sliced bread made from white wheat flour is gently toasted , and spread with a thin coating of benecol ® spread ( mcneil nutritionals ). the spray bottle is held about 15 cm above the surface of each slice of toast , and the spray handle is squeezed once over each slice of toast . the toast possesses a pleasant sweet taste with a vanilla note ; the toast remains crisp , and is not rendered soggy by the amount of solution sprayed onto the surface . one liter of ingestible grade , non - denatured 70 % ethanol is placed into a large covered beaker . with , gentle stirring , 6 . 67 g of sucralose is gradually added , and stirring maintained until dissolution is complete . caramel flavor ( 1 g ) is added , along with caramel color ( 1 g ). these materials are dispersed by stirring , and the solution is dispensed into a pump - type spray dispenser bottle as described in example 1 . popcorn is prepared in a microwave corn popper to provide approximately one liter of popped corn . while the corn is still warm , the spray bottle is held about 20 cm above the surface of the popcorn , and the spray handle is squeezed 10 times while the popcorn is stirred with a spoon . the corn is found to have a sweet , caramel taste and a pleasing color . the composition of example 1 is prepared . additionally , 0 . 1 ml of a 1 : 10 aqueous dilution of antifoam af emulsion ( 30 % simethicone polymers , dow corning ) is added with through mixing , and the solution is placed in a spray bottle . the solution is sprayed onto the surface of a food product ; no residual foam remains on the surface of the food . the antifoam agent can be used to prevent the formation of foam when other materials with a foaming tendency are also incorporated into the composition .
a composition and a device for sweetening products including a sweetening solution , wherein the sweetening solution consists essentially of a high intensity sweetener and a solvent , and a spraying apparatus are disclosed .