for a better understanding of the invention , it is explained in more detail based on the following description . the prophylactic article according to the invention in addition to gloves , in particular medical operation or examination gloves , can also be condoms , finger stalls or protective gloves for work in cleanroom areas , etc . prophylactic articles of this type have already been adequately described in the applicant &# 39 ; s at 413 471 b or at 503 090 a with respect to their composition regarding the elastomer , i . e ., the natural or synthetic latices , e . g ., natural rubber , neoprene , synthetic polyisoprene , nitrile - butadiene and styrene - butadiene rubber , or a mixture thereof , and regarding the optionally arranged sliding layer , wherein this sliding layer can be formed by a sliding film , for example , a silicone oil , but also from the latex itself , for example through halogenation , such as , e . g ., chlorination , or by certain surface modifications and designs , also with respect to the microcapsules used , in particular the size in the range between 0 . 1 μm to 100 μm , wherein in the scope of the present invention microcapsules are preferably used which have a size selected from a range between 0 . 1 μm and 10 μm , as with respect to the capsule material itself , wherein here preferably a polymer on a melamine - formaldehyde basis , e . g ., according to de 29 40 786 a is used . the application of the microcapsules themselves on or in the prophylactic article through the production of corresponding suspensions or emulsions from the latices , has already been dealt with extensively in these documents , so that a more detailed discussion is not necessary at this point and reference is therefore made to these two documents for these points of the invention , which in this respect are therefore part of the content of the present invention . preferably the prophylactic articles are produced in a dipping process with corresponding dipping forms . however , these can also be , e . g ., sprayed , etc . the microencapsulation of the combination of active substances , in particular of the oil , has the advantage that active substances can thus also be used , which are incompatible or compatible only to a lesser extent with respect to the carrier material or a possibly present sliding layer . in other words , the microcapsules have a protective function for the active substance ( s ) of the prophylactic article . moreover , the oil can thus be prevented from diffusing into the prophylactic article and thus is available for the actual function only to a reduced extent . it is therefore achieved thereby that the combination of active substances is better available for the wearer &# 39 ; s skin . the ingredients of the combination of active substances provided according to the invention have already been sufficiently described above . at this point , therefore , only the individual effect will be briefly described , wherein it is noted that these are conventional active substances , which are used in the cosmetics industry and thus the action thereof per se has already been adequately documented . this active ingredient makes the skin supple and smoothes it . moreover , it makes it possible to easily distribute the combination of active substances on the skin . the preferred proportion in the combination of active substances is between 25 % by weight and 50 % by weight , or between 30 % by weight and 40 % by weight . this active ingredient makes the skin supple and smoothes it . moreover the skin is protected from dryness and chapping . the preferred proportion is between 10 % by weight and 25 % by weight or between 15 % by weight and 20 % by weight . this active ingredient also makes the skin supple and smoothes it , without visibly greasing . the preferred proportion is 10 % by weight and 30 % by weight or between 15 % by weight and 20 % by weight . olive oil has a high proportion of unsaturated fatty acids for strengthening the skin barrier . this active ingredient also makes the skin supple and smoothes it . the preferred proportion is between 10 % by weight and 25 % by weight or between 15 % by weight and 20 % by weight . again this active ingredient — it is a type of silicone oil — has a smoothing effect on the skin and makes it supple . furthermore , cyclomethicone has an antistatic effect , whereby the production of the microcapsules can be improved , a film - forming , viscosity - regulating and moisturizing effect . this is also a moisturizing factor . the preferred proportion is between 1 % by weight and 5 % by weight , or 2 % by weight and 3 % by weight . in addition to the effect that this active substance makes the skin supple and smoothes it , squalane has a regreasing effect , in general conditioning for the skin . it is an extract of olive oil . the preferred proportion is between 1 % by weight and 5 % by weight or between 2 % by weight and 3 % by weight , but in individual exemplary embodiments can also be up to 20 % by weight . borage oil makes the skin supple and smoothes it . the preferred proportion is between 1 % by weight and 5 % by weight or between 2 % by weight and 3 % by weight , but in individual exemplary embodiments can also be up to 25 % by weight . shea butter or a liquid extract thereof has a particularly marked conditioning and skin - friendly effect . the preferred proportion is between 1 % by weight and 5 % by weight , in particular between 2 % by weight and 3 % by weight . however / the proportion can also be up to 40 % by weight . macadamia oil has an excellent conditioning effect , since it is rich in unsaturated fatty acids . the preferred proportion is between 1 % by weight and 5 % by weight or between 2 % by weight and 3 % by weight . however , the proportion can also be up to 40 % by weight . benzyl alcohol has a preservative effect , primarily inhibits the development of microorganisms in the combination of active substances . furthermore , benzyl alcohol gives the combination of active substances a jasmine - like scent . the preferred proportion is up to a max . of 0 . 5 % by weight , in particular up to a max . of 0 . 1 % by weight . benzyl benzoate is a very well tolerated preservative and has a similar effect to benzyl alcohol , but without giving the combination of active substances a specific scent . the preferred proportion is up to a max . of 0 . 5 % by weight or max . of 0 . 1 % by weight . potassium sorbate is used in particular for prophylactic articles that must have a particularly high tolerance level by the skin , i . e ., in particular for gloves , the wearers of which quickly react to latices with a skin irritation . this is a mild preservative , which gives the combination of active substances longer durability . the preferred proportion is up to a max . of 0 . 5 % by weight or a max . of 0 . 1 % by weight . sodium hydroacetate is likewise a preservative that is well tolerated , similar to potassium sorbate . the preferred proportion is in turn up a max . of 0 . 5 % by weight or a max . of 0 . 1 % by weight . these active ingredients have a masking effect , prevent or inhibit the odor of the combination of active substances . the preferred proportion is up to a max . of 5 % by weight or a max . of 0 . 5 % by weight or a max . of 0 . 1 % by weight for each of these active substances , if they are contained individually in the combination of active substances . linalool has a deodorizing effect . the preferred proportion is up to a max . of 0 . 5 % by weight or up to a max . of 0 . 1 % by weight . limonene has a skin - conditioning and odor - inhibiting effect . the preferred proportion is up to a max . of 0 . 5 % by weight or up to a max . of 0 . 1 % by weight . these are antioxidants , i . e ., these active ingredients prevent individual constituents of the combination of active substances from oxidizing due to longer storage or also already during production and are thus impaired in their effect or prevent the odor from any odor - forming breakdown products of the combination of active substances that may develop . these are usually radical interceptors . the preferred proportion of each of these representatives of the antioxidants is up to a max . of 0 . 5 % by weight or up to a max . of 0 . 1 % by weight . these active substances are humectant factors , i . e ., they prevent the skin from drying out . each of these active substances can preferably be present in a proportion of up to a max . of 3 % by weight or up to a max . of 1 % by weight , wherein these active substances in total are contained in a proportion of a max . of 3 % by weight , if several of these humectant factors are used . the humectant factors can be contained in particular individually in a proportion of 0 . 1 % by weight to 1 % by weight . geraniol has a strengthening effect and produces a pleasant feeling on the skin . moreover it can be used for odor correction . the preferred proportion is up to a max . of 0 . 3 % by weight or up to a max . of 0 . 1 % by weight . allantonin , arnica extract ( arnica montana ), oat extract ( avena sativa ), calendula oil ( calendula officinalis ), chamomile extract ( chamomilla recutita ), ethylhexyl stearate , azulene ( guajazulene ): allantonin has a soothing effect on the skin and promotes the formation of tissues , i . e ., it has a positive effect when the wearer of the prophylactic article has a superficial skin injury . arnica extract has a regenerating effect and stimulates the blood flow . oat extract has a mild conditioning effect , soothes the skin and is antipruritic . calendula oil has a skin soothing and regenerating effect in the case of chapped and cracked skin . chamomile extract is used in particular when the wearer of the prophylactic article has a very tender , sensitive skin . ethylhexyl stearate improves the dispersibility of the combination of active substances on the skin . the preferred proportion of these active ingredients can be individually up to a max . of 10 % by weight or up to 5 % by weight or up to a max . of 2 . 5 % by weight , wherein , if several of these active ingredients are contained , the total proportion in the combination of active substances is a max . of 10 % by weight . the combination of active substances is given a specific fragrance direction by perfume active substances and the basic odor of the combination of active substances can also be better covered thereby . the preferred proportion of perfume ingredients is up to a max . of 1 . 5 % by weight or preferably between 0 . 1 % by weight and 1 % by weight . in order to be better able to encapsulate the combination of active substances produced by mixing the individual ingredients , as already stated above , this skin protection oil can be diluted . in this respect , reference is made to the above statements . furthermore , extracts or at least partially hydrated representatives of these active substances can be used . the combination of active substances can contain up to 98 % by weight of at least one of the skin conditioning agents . in this case proportions of preservatives , odor - inhibiting agents and antioxidants are restricted to a total of a max . of 2 % by weight . on the other hand it is possible for the combination of active substances to contain a max . of 90 % by weight of skin conditioning substances , so that the other ingredients of the combination of active substances therefore have a proportion of a max . of 10 % by weight . the constituent amounts of the dilution relate to the entire combination of active substances , i . e ., the relative proportions of the individual ingredients in the combination of active substances with respect to one another are not changed by the dilution . since it is not possible to list all of the combinations of active substances within the scope of this description , only the particularly preferred exemplary embodiments are listed below . the data given on the constituent amounts are thereby to be understood as % by weight . the respectively preferred ranges of the compounds are given in parentheses , within which the respective ingredients or active substances can be varied . the active substances are commercially available products . microcapsules were produced with these combinations of active substances , optionally after the dilution described above , with a method according to the prior art for the microencapsulation of active substances . these microcapsules were subsequently added to a conventional elastomer compound corresponding to the prior art in a concentration of between 0 . 1 % by weight and 10 % by weight , based on the total latex dispersion . from this subsequently gloves were produced by means of a conventional dipping process , as is described , for example , in the applicant &# 39 ; s two above - referenced documents from the prior art . to evaluate the functional properties , gloves of this type with combinations of active substances according to the exemplary embodiments 1 through 6 were worn by respectively 100 test persons over a period of respectively 8 hours . each of these test persons thereby wore respectively one glove according to exemplary embodiments 1 through 6 . after the end of 8 hours , on the one hand , the skin of the test persons was visually evaluated , on the other hand , the subjective perception of these test persons was verified by means of questionnaires that did not reveal the respective identities and contained questions regarding itchy feeling during wear , etc . it turned out that virtually 100 % of the test persons found a glove with a combination of active substances according to exemplary embodiment 4 the most pleasant to wear . embodiments of a glove with combinations of active substances according to exemplary embodiments 1 through 3 and 5 and 6 were evaluated by between 97 % and 99 % of the test persons as very positive with regard to wearing comfort and the feeling on the skin . the visual evaluation of the skin after the gloves were removed from the hands of the test persons did not show a reddening of the skin in any of the cases . the combinations of active substances according to exemplary embodiments 1 through 6 all have an oily consistency . as already stated above , to increase the lipid penetration through the combination of active substances , i . e ., individual constituents of this combination of active substances , the viscosity of this combination of active substances at 37 ° c . can have a value of a max . of 250 mpas and / or a saponification value according to din 53401 of no more than 250 . to adjust these values the individual ingredients can be varied according to their proportion in the combination of active substances . to further improve the lipid penetration , it is advantageous if the proportion of triglyceride skin conditioning agents in the combination of active substances is no more than 50 % by weight . all of the data on value ranges in this specification are to be understood to cover any and all partial ranges therefrom , e . g ., 1 - 10 is to be understood in that all partial ranges starting from the lower limit 1 and the upper limit 10 are covered , i . e ., all partial ranges begin with a lower limit of 1 or greater and end with an upper limit of 10 or less , e . g ., 1 to 1 . 7 , or 3 . 2 to 8 . 1 or 5 . 5 to 10 . the exemplary embodiments show possible embodiment variants of the prophylactic article , wherein it is noted at this point that the invention is not limited to the embodiment variants of the same specifically shown , but instead various combinations of the individual embodiment variants among one another are possible and this variation possibility based on the teaching for technical actions through the present invention lies within the ability of one skilled in the art in this technical field .
the invention relates to a prophylactic article with a carrier element , which comprises at least in part a natural or synthetic elastomer , and with a combination of active substances that is contained in microcapsules , wherein the microcapsules are arranged at least in part in and / or on the carrier element . the combination of active substances contains at least one skin care agent , at least one preservative , at least one odor - inhibiting agent and at least one antioxidant .