Do you know natural examples of triangulated categories (or [presentable] stable $\infty$-categories) which are not compactly generated? (ideally they'd be defined algebraically, but curious to hear any examples.. the ones I know are gotten as opposites of compactly generated categories or by slightly ad hoc geometric constructions)



Categories which are not compactly generated
As David says, D(R) is compactly generated. This means Brown representability for COHOMOLOGY is automatically true, but that does NOT mean Brown representability for HOMOLOGY is true, and in fact it is not always true. That is what the Christensen-Keller-Neeman example shows. 


Let K(R) be the category of chain complexes over R and chain homotopy classes of chain maps. Then K(Z) is not compactly generated (and K(R) is not either for many R). This is proved in a paper of mine with Christensen. 


[Quillen model structures for relative homological algebra](http://journals.cambridge.org/action/displayAbstract?fromPage=online&aid=122357)


