Width and Shape of a Raman Peak in Nanopowders of Nonpolar Crystals: I. Analytical Treatment
Microscopic description of Raman spectra in nanopowders of nonpolar crystals is accomplished by developing the theory of disorder-induced broadening of nanoparticle vibrational eigenmodes. Analytical treatment of this problem is performed, and line shape and width are determined as functions of quantum numbers, nanoparticle shape, size, and the strength of disorder. The results are found to be strongly dependent on either the broadened line is separated or it is overlapped with other lines of the spectrum. Three models of disorder, i.e. weak point-like impurities, weak smooth random potential, and strong rare impurities are investigated in details. The possibility to form the phonon-impurity bound state is also studied.