Long-term evolution of terrestrial inputs from the Ediacaran to early Cambrian: Clues from Nd isotopes in shallow-marine carbonates, South China
Abstract The emergence and radiation of metazoans have been widely attributed to a progressively more oxidizing surface environment through the Ediacaran–Cambrian transition interval. However, the root causes for atmospheric and oceanic oxygenation are still disputed. Long-term tectonic changes could possibly have led to atmospheric oxygenation but geochemical evidence for this linkage remains elusive. In this study, we analyzed the radiogenic Nd isotopic compositions (eNd) of shallow-marine carbonates from South China in order to track secular variations in terrestrial inputs from Ediacaran to early Cambrian time. Compared with most other geochemical indices, the Nd isotope system in carbonates is less susceptible to early diagenetic exchange and can thus act as a robust proxy for continental materials undergoing weathering. We interpret an abrupt excursion to lower eNd values during the middle Ediacaran as due to rapid exchange of different water masses. However, the more gradual trend towards lower Nd isotope values from the Ediacaran to early Cambrian, accompanied by increasing 87Sr/86Sr ratios of the studied carbonates, likely indicates the enhanced weathering of old continental rock following the assembly of Gondwana. Increased net accumulation of atmospheric oxygen as a result of enhanced organic carbon burial may have benefited from intense continental denudation.