Unique Synthetic Approach toward a Phosphaalkene: Synthesis of a Selenium-substituted Phosphaalkene with Bulky Substituents
A selenium-substituted phosphaalkene, (Me3Si)2C=PSeTrp (1, Trp: 9-triptycyl), was synthesized by two methods, substitution reaction of (Me3Si)2C=PCl (3) with TrpSeLi, and treatment of TsiP(Cl)SeTrp...