Fast molecular dynamics: Novel effects studied by 3 cm and 2 mm band EPR
1: Abstract - Motional characteristics were calculated for new type or free radicals starting from the anisotropic parameters obtained with the high resolution 2 mm band EPR. The general approach for derivinp; parameters of molecular tumbling and chemical exchange in the same experiment is discussed. A rather strong correlation between molecular and chemical dynamics of free radicals has been observed.