Gelatin/DMSO: a new approach to enhancing the performance of a pyrite electrode in a lithium battery
Abstract We have studied the electrochemical behavior of natural pyrite (FeS 1.9 , n-type semiconductor) treated nonaqueously with dimethylsulfoxide (DMSO) solvent and also with a gelatin/DMSO solution. Composite electrodes (comprised of pyrite, polyvinilidene fluoride, polyethylene oxide and carbon) were characterized in a lithium cell at room temperature by cyclic voltammetry and galvanostatic measurements; the electrolyte used was LiPF 6 in a solution of ethylene carbonate and dimethyl carbonate (1 mol l −1 ). The gelatin/DMSO treatment greatly improved the reversible specific capacity of a pyrite electrode. For galvanostatic discharge/charge at a current density of 0.4 mA cm −2 and between voltage limits of 3.2 and 1.1 V, its reversible specific capacity at the 15th cycle equaled 275 mA h g −1 , an impressive value compared to less than 25 mA h g −1 for a pristine pyrite electrode.