Importance of tunneling in H-abstraction reactions by OH radicals - The case of CH4 + OH studied through isotope-substituted analogs
We present a combined experimental and theoretical study focussing on the quantum tunneling of atoms in the reaction between CH 4 and OH. The importance of this reaction pathway is derived by investigating isotope substituted analogs. Quantitative reaction rates needed for astrochemical models at low temperature are currently unavailable both in the solid state and in the gas phase. Here, we study tunneling effects upon hydrogen abstraction in CH 4 + OH by focusing on two reactions: CH 4 + OD → CH 3 + HDO and CD 4 + OH → CD 3 + HDO. The experimental study shows that the solid-state reaction rate R CH 4 + OD is higher than R CD 4 + OH at 15 K. Experimental results are accompanied by calculations of the corresponding unimolecular and bimolecular reaction rate constants using instanton theory taking into account surface effects. For the work presented here, the unimolecular reactions are particularly interesting as these provide insight into reactions following a Langmuir-Hinshelwood process. The resulting ratio of the rate constants shows that the H abstraction ( k CH 4 + OD ) is approximately ten times faster than D-abstraction ( k CD 4 + OH ) at 65 K. We conclude that tunneling is involved at low temperatures in the abstraction reactions studied here. The unimolecular rate constants can be used by the modeling community as a first approach to describe OH-mediated abstraction reactions in the solid phase. For this reason we provide fits of our calculated rate constants that allow the inclusion of these reactions in models in a straightforward fashion.