The theory of atomic-molecular transformations in condensed phase at low temperatures
Abstract The probability of the elementary act of a nonadiabatic chemical reaction in condensed medium at low temperature is calculated. General results are illustrated by the formulas for Debye-type and resonance-type absorption spectra of the medium. For the reactions involving the reorganization of the intramolecular structure of the reactants the limiting cases of both weak and strong coupling of the reactants with the medium are considered.