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tokens: Acknowledgements We thank the anonymous referee for their careful reading of and helpful suggestions on the manuscript, and Andreas Korn for providing the FOCES spectra used in this work. AMA and KL acknowledge funds from the Alexander von Humboldt Foundation in the framework of the Sofja Kovalevskaja Award endowed by the Federal Ministry of Education and Research, and KL also acknowledges funds from the Swedish Research Council (grant 2015-004153) and Marie Skłodowska Curie Actions (cofund project INCA 600398). TN and MA acknowledge funding from the Australian Research Council (grant DP150100250), and MA also acknowledges funding through ARC Laureate Fellowship (FL110100012). Parts of this research were conducted by the Australian Research Council Centre of Excellence for All Sky Astrophysics in 3 Dimensions (ASTRO 3D), through project number CE170100013. PSB acknowledges financial support from the Swedish Research Council and the project grant “The New Milky Way” from the Knut and Alice Wallenberg Foundation. Funding for the Stellar Astrophysics Centre is provided by The Danish National Research Foundation (grant DNRF106). This work made use of data from the UVES Paranal Observatory Project (ESO DDT Program ID 266.D-5655). This work was supported by computational resources provided by the Australian Governmentthrough the National Computational Infrastructure (NCI) under the National Computational Merit Allocation Scheme.