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tokens: Acknowledgements This work has made use of the VALD data base, operated at Uppsala University, the Institute of Astronomy RAS in Moscow, and the University of Vienna. This work is based on observations obtained at the Canada–France–Hawaii Telescope (CFHT) that is operated by the National Research Council of Canada, the Institut National des Sciences de l'Univers of the Centre National de la Recherche Scientifique of France, and the University of Hawaii. All authors acknowledge the advice and assistance provided on this and related projects by the members of the BinaMIcS and MiMeS collaborations. MS acknowledges the financial support provided by the European Southern Observatory studentship program in Santiago, Chile. MS and GAW acknowledge support from the Natural Sciences and Engineering Research Council of Canada (NSERC). EA acknowledges financial support from the Programme National de Physique Stellaire (PNPS) of INSU/CNRS. We acknowledge the Canadian Astronomy Data Centre (CADC). This project used the facilities of SIMBAD.