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tokens: We thank C. Leonard for the ab initio curves and P. Bernath for the experimental line list. This work was supported by the ERC under the Advanced Investigator Project 267219 and made use of the DiRAC@Darwin, DiRAC@COSMOS HPC cluster and Emerald CfI cluster. DiRAC is the UK HPC facility for particle physics, astrophysics and cosmology and is supported by STFC and BIS. The authors would like to acknowledge the work presented here made use of the EMERALD high performance computing facility provided via the Centre for Innovation (CfI). The CfI is formed from the universities of Bristol, Oxford, Southampton and UCL in partnership with STFC Rutherford Appleton Laboratory. We also acknowledge the networking support by the COST Action CM1405 MOLIM.