tokens: The authors warmly thank Evelyne Roueff, Jonathan Tennyson and Alexandre Faure for numerous fruitful discussions. We acknowledge the support of the European COST Actions ‘Our Astrochemical History’ CM1401 and ‘Molecules in motion’ (MOLIM) CM1405. We are grateful to the International Atomic Energy Agency (IAEA, Vienna) for scientific and financial support through the Contract No. 16712 with the University of Douala (CAMEROON) and through the Coordinated Research Projects ‘Atomic and Molecular Data for State-Resolved Modelling of Hydrogen and Helium and their Isotopes in Fusion Plasmas’ and ‘Light Element Atom, Molecule and Radical Behaviour in the Divertor and Edge Plasma Regions’. We thank the financial support from the French CNRS via the programmes ‘Physique et Chimie du Milieu Interstellaire’, the ‘Physique théorique et ses interfaces’ projects TheMS, TPCECAM and ‘InPhynity MEXAT’. We are very grateful for the generous support of Agence Nationale de la Recherche via the projects ‘SUMOSTAI’ (ANR-09-BLAN-020901) and ‘HYDRIDES’ (ANR-12-BS05-0011-01), of IFRAF-Triangle de la Physique via the project ‘SpecoRyd’, and of Fédération de Recherche Fusion par Confinement Magnétique - ITER. We acknowledge the constant financial support from La Région Haute-Normandie via the CPER ‘THETE’ project, and the GRR Electronique, Energie et Matériaux. Part of this work has been performed in the frame of the ‘Fédération de Recherche Energie, Propulsion, Environnement’, and of the LabEx EMC 3 , via the project PicoLIBS (ANR-10-LABX-09-01). Finally, MDEE and OM thank the Laboratoire Ondes et Milieux Complexes of the University of Le Havre for hospitality.
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