The Effect of Interrupted Homogenization on β-Al5FeSi → α-Alx (Fe and Mn) Si Transformation in the A6063 Aluminum Alloy

The aluminum alloys corresponding to the 6000 series are mainly manufactured by mechanical forming processes. Their properties are enhanced by the homogeneous distribution of intermetallic phases such as β-Al5FeSi or α-Alx (Fe, Mn) Si. By thermal homogenization treatment, the intermetallic compound β-Al5FeSi changes its morphology from a needle type with a monoclinic structure to an acicular form known as α-Al12(Fe, Mn)3Si with an fcc structure. In the present study, samples of the 6063 alloy were subjected to different temperatures of homogenization (798, 823, and 848 K) and treatment times from 0 to 660 min (in intervals of 30 min) to evaluate their effects on the microstructures and morphologies of the intermetallic phases. For the kinetic study, the microstructures of the β and α intermetallic phases were quantified using the Image-Pro software. The results indicate that as the temperature and homogenization time increase, the percentage of phase α also increments. The results of the kinetic analysis revealed that the β → α transformation is controlled by two stages; the first corresponds to the diffusion of Mn atoms from the matrix to the interface of reaction for the formation of the intermetallic phases, while the second corresponds to the nucleation and growth of the iron- and manganese-rich intermetallic phases.