Mechanical Performances and Frost Resistance of Alkali-Activated Coal Gangue Cementitious Materials

The coal gangue after composite activation treatment is considered a potential low-carbon and green cementitious material, so the feasibility of employing composite-activated gangue to partially or entirely replace cement for building materials is systematically studied in this paper. The effects of alkali content, slag content, and water-to-binder ratio on the mechanical properties and frost resistance of alkali-activated coal gangue mortar (AACGM) were experimentally investigated. An ESEM was employed to observe the microstructure of the AACGM. Moreover, the microstructure damage to the AACGM was analyzed by a pixel-based image processing algorithm. The research was carried out in accordance with standards JGJ/T70-2009 and GB/T 50082-2009. Experimental results indicated that the mechanical properties and frost resistance of the AACGM were superior to those of ordinary Portland cement mortar (OPCM). Compared with the OPC group, the compressive and flexural strength of the W0.50 group increased by 16.01% and 14.19%. Moreover, the loss rate of mass, flexural strength, compressive strength, and microstructure damage of the AACGM were less than those of the OPCM. Between freeze–thaw cycles 25 and 100, the cracks and pores of specimens gradually grew, and the maximum crack width increased by 277.78%. In addition, the slag was beneficial in improving the flexural strength, compressive strength, and frost resistance of the AACGM. Finally, the freeze–thaw damage mechanism of the CGBG mortar was systematically analyzed.