Nanomaterials as Photocatalysts—Synthesis and Their Potential Applications

Increasing demand for energy and environmental degradation are the most serious problems facing the man. An interesting issue that can contribute to solving these problems is the use of photocatalysis. According to literature, solar energy in the presence of a photocatalyst can effectively (i) be converted into electricity/fuel, (ii) break down chemical and microbial pollutants, and (iii) help water purification. Therefore, the search for new, efficient, and stable photocatalysts with high application potential is a point of great interest. The photocatalysts must be characterized by the ability to absorb radiation from a wide spectral range of light, the appropriate position of the semiconductor energy bands in relation to the redox reaction potentials, and the long diffusion path of charge carriers, besides the thermodynamic, electrochemical, and photoelectrochemical stabilities. Meeting these requirements by semiconductors is very difficult. Therefore, efforts are being made to increase the efficiency of photo processes by changing the electron structure, surface morphology, and crystal structure of semiconductors. This paper reviews the recent literature covering the synthesis and application of nanomaterials in photocatalysis.