Miocene-Holocene paleoenvironmental changes in the Tinto River estuary (SW Spain) evidenced by sedimentology, geochemistry and fauna

This paper investigates the paleoenvironmental evolution of a long core extracted in a small cove located in the Tinto-Odiel estuary (SW Spain). The inferred reconstruction is supported by sedimentological, geochemical, paleontological data and dating. Seven phases have been identified, with the transit from Late Neogene marine environments to a subrecent freshwater pond and a final anthropic filling. On the basis of these data, this area was flooded during the maximum of the MIS-1 transgression (6.5-5.2 cal. kyr BP), with the temporary presence of a subtidal channel with phanerogam meadows. During this evolution, three geochemical peaks have been detected, which correspond to 1) the first evidence of mining activities (~4.5 cal. kyr BP), 2) an interval of intensive mining (1850-1960) and 3) an industrial period (1966-1985), affected by the dumping of highly polluting waste into this estuary.