Effect of σ-Phase on the Strength, Stress Relaxation Behavior, and Corrosion Resistance of an Ultrafine-Grained Austenitic Steel AISI 321

This paper reported the results of research into the effect of Equal Channel Angular Pressing (ECAP) temperature and 1-hour annealing temperature on mechanical properties, stress-relaxation resistance, and corrosion resistance of austenitic steel AISI 321L with strongly elongated thin δ-ferrite particles in its microstructure. The formation of α′-martensite and fragmentation of austenite grains takes place during ECAP. Ultrafine-grained (UFG) steels demonstrate increased strength. However, we observed a reduced Hall–Petch coefficient as compared with coarse-grained (CG) steels due to the fragmentation of δ-ferrite particles. UFG steel specimens were found to have 2–3 times higher stress-relaxation resistance as compared with CG steels. For the first time, the high stress-relaxation resistance of UFG steels was shown to stem from a internal stress-relaxation mechanism, i.e., the interaction of lattice dislocations with non-equilibrium grain boundaries. Short-time 1-hour annealing of UFG steel specimens at 600–800 °C was found to result in the nucleation of σ-phase nanoparticles. These nanoparticles affect the grain boundary migration, raise strength, and stress-relaxation resistance of steel but reduce the corrosion resistance of UFG steel. Lower corrosion resistance of UFG steel was shown to be related to the formation of α′-martensite during ECAP and the nucleation of σ-phase particles during annealing.