In-Situ Catalytic Preparation of Two-Dimensional BCN/Graphene Composite for Anti-Corrosion Application

In-situ catalytic growth of two-dimensional materials shows great potential for metal surface protection because of the impermeability and strong interaction of the materials with metal surfaces. Two-dimensional hexagonal boron-carbon nitrogen (h-BCN) is composed of alternating boron, carbon, and nitrogen atoms in a two-dimensional honeycomb lattice, which is similar to graphene. The corrosion caused by defects such as grain boundary of two-dimensional materials can be weakened by dislocation overlap via the transfer method. However, two-dimensional composite films prepared using the transfer method have problems, such as the introduction of impurities and poor adhesion, which limit their corrosion resistance. In this study, a layer of BCN/Gr two-dimensional composite was directly grown on the surface of copper foil using the CVD in-situ catalysis method, and its anti-corrosion performance was characterized by electrochemical and salt spray experiments. The results showed that the directly grown two-dimensional composite had better adhesion to the substrate and the advantage of grain boundary dislocation, thus showing a better anti-corrosion capability.