Carotenoids Recovery Enhancement by Supercritical CO2 Extraction from Tomato Using Seed Oils as Modifiers

The food, cosmetic and pharmaceutical industries have strong demands for lycopene, the carotenoid with the highest antioxidant activity. Usually, this carotenoid is extracted from tomatoes using various extraction methods. This work aims to improve the quantity and quality of extracts from tomato slices by enhancing the recovery of the carotenoids from the solid matrix to the solvent using 20 w/w% seeds as modifiers and supercritical CO2 extraction with optimal parameters as the method. Tomato (TSM), camelina (CSM) and hemp (HSM) seeds were used as modifiers due to their quality (polyunsaturated fatty acids content of 53–72%). A solubility of ~10 mg carotenoids/100 g of oil was obtained for CSM and HSM, while, for TSM, the solubility was 28% higher (due to different compositions of long carbon chains). An increase in the extraction yield from 66.00 to 108.65 g extract/kg dried sample was obtained in the following order: TSM < HSM < CSM. Two products, an oil rich in carotenoids (203.59 mg/100 g extract) and ω3-linolenic acid and a solid oleoresin rich in lycopene (1172.32 mg/100 g extract), were obtained using SFE under optimal conditions (450 bar, 70 °C, 13 kg/h and CSM modifier), as assessed by response surface methodology. A recommendation is proposed for the use of these products in the food industry based on their quality.