4-Bromothiophenol
# 4-Bromothiophenol

4-Bromothiophenol is an organic compound with the formula $BrC_6H_4SH.$ It forms colorless crystals.

## Synthesis

4-Bromothiophenol can be synthesized via the reduction of 4-bromo-benzenesulfonyl chloride by red phosphorus and iodine in an acidic solution. Hydrogenation of 4,4'-dibromodiphenyl disulfide also produces 4-bromothiophenol.

## Reactions

It reacts with acetylacetone in the presence of cesium carbonate to give 3-(4-bromophenylthio)pentane-2,4-dione. 4,4'-Dibromophenyl disulfide is also produced as the intermediate.

Like other thiols, it reacts with silver nitrate to produce silver 4-bromothiophenolate.

