Hi all! I'm having a bit of a panic attack so any advice would be highly appreciated!

I recently went for an interview for a job in my desired career (this will be my first job after taking my university degree in the subject, however I am currently still completing my dissertation until the beginning of September), heard back from them that I got the job mid this week. I've been very nervous and panicky about it as it'll be my first proper full time job and I have anxiety, so I get very worked up and overthink literally everything all the time. The guy on the phone said I had the job, and that I'd hear from them the end of next week, so I was okay with that because I had time to mentally prepare for it, get everything sorted like clothes etc. and also have a week to make some good progress on my dissertation so when I started the job I wouldn't have too much left to juggle for the due in date. 

However, the workplace just contacted me today asking if I can start working tomorrow and I'm completely having a meltdown, as soon as I read the message I had an instant pit in my chest and started panicking. I spoke to my mum about it and she's of the mindset I need to just start and deal with it, that I'm being dumb for panicking and what would be difference be if I started tomorrow or next Monday (my stance is everything because mentally I'd be more prepared than being shocked into starting the job), but she's never been someone who's had to deal with anxiety so she never understands.

I'm just completely lost and I'm not sure what to do. Is it fair of me to say I'm not available until later on in the week so I have time to be ready, or do I just start even if I'm having constant anxiety and panic attacks. I don't want to start off my new job like this, but If I say to them I'm not available yet my parents will be very upset with me (I live with them, so I'd have to endure their anger).

Please help, and thank you for anyone who chooses to comment! 

TL;DR: I got a job and they said I'd start end of next week, and have asked me to start tomorrow. I am mentally and physically not prepared to start, is it okay to say I'm not available even if my parents will be angry If I do?