title: Self-cleaning surfaces
context: The first instance of a self-cleaning surface was created in 1995.[1] Paz et al. created a transparent titanium dioxide (TiO2) film that was used to coat glass and provide the ability for the glass to self-clean. The first commercial application of this self-cleaning surface, Pilkington Activ, was developed by Pilkington glass in 2001. This product implements a two-stage cleaning process. The first stage consists of photocatalysis of any fouling matter on the glass. This stage is followed by the glass becoming superhydrophilic and allowing water to wash away the catalyzed debris on the surface of the glass. Since the creation of self-cleaning glass, titanium dioxide has also been used to create self-cleaning nanoparticles that can be incorporated into other material surfaces to allow them to self-clean.[2]
question: Who developed the first synthetic self-cleaning surface?
answers.text: Paz et al Paz et al