text: SPME is a technique of extraction not exhaustive [26], in which an optical fiber coated by sorbent/adsorbent materials is exposed to the headspace above the sample or where the fiber is immersed into the aqueous phase. The extraction of analytes can be attributed to their characteristics associated with the fiber coating. Fibers of nonpolar coatings such as PDMS are more suitable for the analysis of nonpolar compounds; PDMS/DVB (bipolar fiber) applied to volatile and nonvolatile low-to-high polarity and polyacrlate (PA) (polar fiber) the volatile compounds extraction of medium to high polarity [22, 34]. For tools fibers the extraction time was short to avoid saturation of the coating of the fiber due to that the oil is highly volatile. Thus there was no saturation of the mass spectrometer detector. A total of sixty-one compounds were identified and compared with the retention KI for oil and volatile composition. The composition of oil evaluated was eighty-seven percent, while for the profile of volatiles it was performed with SPME fiber above ninety-two percent.