Some of the principals that worked at Enchi College of Education are Mr. Djeo Addison (who served from 1965 until 1973), Mr. D.M. Korwumu (who served from 1974-1976), Mr. John Attipila (who served from 1976-1980), and Mr. Assifuah Nunoo (who served from 1980-1983).
List of principals: Mr. Djeo Addison 1965  1973 Mr. D.M. Korwumu 1974  1976 Mr. John Attipila 1976  1980 Mr. Assifuah Nunoo 1980  1983 
