Kibi Presbyterian College of Education's longest serving principal is Rev. E.Y. Omenako, serving for 19 years, followed by Mrs. Elizabeth Addo's decade of service.
List of principals: Miss Martha Baehler 1963  1969 Mrs. Elizabeth Addo 1970  1980 Rev. Bruce K. Asare 1980  1988 Mr. E.O. Gyarteng 1988 1995 Rev. E.Y. Omenako 1995 - 2013 Rev. Dr. B. N. Kyeremateng 2013 - 2017 Rev. Charles Fosu Ayarkwa 2017 - 
