Jennifer Aniston was married to Brad Pitt for five years.
Since Jolie filed for divorce from Pitt on September 19, 2016, they have been embroiled in a custody battle over their children
On November 22, 2001, Pitt made a guest appearance in the eighth season of the television series Friends, playing a man with a grudge against Rachel Green, played by Jennifer Aniston, to whom Pitt was married at the time

