Aishwarya Rai is a brand ambassador for several business organizations and campaigns.
 Rai with her husband Abhishek Bachchan appeared on The Oprah Winfrey Show on 28 September 2009
 Many times, international agencies like United Nations also appoint ambassadors to achieve the objectives of a particular mission, like the appointment of goodwill ambassador Bollywood film actress Priyanka Chopra for UNICEF

