Kammala wannan jumla: A shekara ta 1797, Azurduy ta koma zama a gonar mahaifinta, tana ciyar da kwanakinta tare da 'yan asalin ƙasar da ke zaune a ƙasarsa. Ta shaida zaluncin aikinsu a cikin ma'adinan azurfa na Spain, kuma ta zama ƙaunatacciyar ƙawance ga 'yan asalin ƙasar
juyin juya hali. A cikin 1805, Azurduy ta auri maƙwabcinta kuma abokiyar ƙuruciya Manuel Ascencio Padilla, ɗan juyin juya hali wanda ya bar makarantar lauya ta Royalist don shiga ƙungiyar 'yanci. Auren su ya kasance mai ci gaba sosai, tare da Padilla yana tsaye tare da matarsa a fagen fama da waje. Kafin rikicin soja ya fara, Padillas suna da 'ya'ya maza biyu. Dukansu biyu za su mutu cikin bala'i saboda rashin lafiya da rashin abinci mai gina jiki a sansanin soja.