Pedzisa mutsara unotevera: Puyol akahwina mutambo wake wekutanga weSpain musi wa15 Mbudzi 2000 vachipesana neNetherlands, uye akaramba ari mutambi wenguva dzose mumakore anotevera. Akatambira nyika yake paOlympics ya2000, 2002 World Cup,
Euro 2004, 2006 World Cup, Euro 2008, 2009 FIFA Confederations Cup uye 2010 World Cup.