Puyol akahwina mukombe wake wekutanga weSpain musi wa15 Mbudzi 2000 vachipesana neNetherlands, uye akaramba ari mutambi wenguva dzose mumakore anotevera. Akatambira nyika yake kumaOlympics a2000, 2002 World Cup, Euro 2004
, 2006 World Cup, Euro 2008, 2009 FIFA Confederations Cup uye 2010 World Cup.