Rubuta ci gaba don wannan sakin layi - Puyol ya lashe gasar farko ta Spain a ranar 15 ga Nuwamba 2000 a kan Netherlands, kuma ya kasance mai daidaitawa a cikin shekaru masu zuwa. Ya buga wa kasarsa wasa a gasar Olympics ta 2000, gasar cin kofin duniya ta 2002, Euro 2004
, 2006 gasar cin kofin duniya, Euro 2008, 2009 FIFA Confederations Cup da kuma 2010 gasar cin kofin duniya.