Piqué ya kasance memba ne na ƙungiyar Spain ta ƙasa da 19 wanda ya lashe gasar cin kofin Turai ta 2006 a Poland. A wasan karshe na 2 × 1 da Scotland, Piqué ya yi rawar gani a cikin tsaro, ya buga giciye tare da kai, kuma ya ba da burin na biyu ga dan wasan Alberto Bueno. Daga bisani, ya taka leda a gasar cin kofin duniya ta FIFA ta 2007, ya fara dukkan wasanni shida na Spain kuma ya zira kwallaye a cikin nasarar da tawagar ta samu daga baya 4 × 2 a kan Brazil a zagaye na 16. Duk da haka, Piqué ya rasa hukuncin yanke hukunci a wasan da aka yi da Jamhuriyar Czech da Spain aka fitar da su a zagaye na karshe. Tambaya: Pique an san shi a matsayin memba na kungiyar?
Spain karkashin-19