A ranar 22 ga Maris, 2013, Ramos ya yi bikin cika shekaru 100 da buga wasa ta hanyar bude raga a wasan da suka yi da Finland a Gijón don wasannin neman shiga gasar cin kofin duniya ta 2014. Ya zama matashin ɗan wasan Turai da ya taɓa kaiwa wannan adadi a cikin aikin, ya wuce Lukas Podolski na Jamus. A watan Yuni, Ramos ya yi takara a gasar cin kofin FIFA ta 2013 a Brazil, inda ya fara kowane wasa yayin da Spain ta yi rashin nasara ga masu karɓar bakuncin a wasan karshe. Ya zama kyaftin din kungiyar a wasan rukuni na biyu, nasara 10-0 a kan Tahiti a Maracanã, wanda shine babbar nasara a cikin aikinsa. A ranar 30 ga Yuni, ya rasa bugun fanareti a cikin 3-0
Brazil ta yi rashin nasara a wasan karshe na gasar cin kofin duniya.