In 1914, Franck teamed up with Hertz to perform an experiment to investigate fluorescence. They designed a vacuum tube for studying energetic electrons that flew through a thin vapour of mercury atoms. They discovered that when an electron collided with a mercury atom it could lose only a specific quantity (4.9 electron volts) of its kinetic energy before flying away. A faster electron does not decelerate completely after a collision, but loses precisely the same amount of its kinetic energy. Slower electrons just bounce off mercury atoms without losing any significant speed or kinetic energy.
These experimental results provided confirmation of Albert Einsteins photoelectric effect and Plancks relation (E = fh) linking energy (E) and frequency (f) arising from quantisation of energy with Plancks constant (h). But they also provided evidence supporting the model of the atom that had been proposed the previous year by Niels Bohr. Its key feature was that an electron inside an atom occupies one of the atoms "quantum energy levels". Before a collision, an electron inside the mercury atom occupies its lowest available energy level. After the collision, the electron inside occupies a higher energy level with 4.9 electron volts (eV) more energy. This means that the electron is more loosely bound to the mercury atom. There were no intermediate levels or possibilities.
In a second paper presented in May 1914, Franck and Hertz reported on the light emission by the mercury atoms that had absorbed energy from collisions. They showed that the wavelength of this ultraviolet light corresponded exactly to the 4.9 eV of energy that the flying electron had lost. The relationship of energy and wavelength had also been predicted by Bohr. Franck and Hertz completed their last paper together in December 1918. In it, they reconciled the discrepancies between their results and Bohrs theory, which they now acknowledged. In his Nobel lecture, Franck admitted that it was "completely incomprehensible that we had failed to recognise the fundamental significance of Bohrs theory, so much so, that we never even mentioned it once". On 10 December 1926, Franck and Hertz were awarded the 1925 Nobel Prize in Physics "for their discovery of the laws governing the impact of an electron upon an atom.".