Wheatstone and others also contributed to early spectroscopy through the discovery and exploitation of spectral emission lines.
As John Munro wrote in 1891, "In 1835, at the Dublin meeting of the British Association, Wheatstone showed that when metals were volatilised in the electric spark, their light, examined through a prism, revealed certain rays which were characteristic of them. Thus the kind of metals which formed the sparking points could be determined by analysing the light of the spark. This suggestion has been of great service in spectrum analysis, and as applied by Robert Bunsen, Gustav Robert Kirchhoff, and others, has led to the discovery of several new elements, such as rubidium and thallium, as well as increasing our knowledge of the heavenly bodies."