Talbot invented a process for creating reasonably light-fast and permanent photographs that was the first made available to the public; however, his was neither the first such process invented nor the first one publicly announced.
Shortly after Louis Daguerres invention of the daguerreotype was announced in early January 1839, without details, Talbot asserted priority of invention based on experiments he had begun in early 1834. At a Friday Evening Discourse at the Royal Institution on 25 January 1839, Talbot exhibited several paper photographs he had made in 1835. Within a fortnight, he communicated the general nature of his process to the Royal Society, followed by more complete details a few weeks later. Daguerre did not publicly reveal any useful details until mid-August, although by the spring it had become clear that his process and Talbots were very different.
Talbot's early "salted paper" or "photogenic drawing" process used writing paper bathed in a weak solution of ordinary table salt (sodium chloride), dried, then brushed on one side with a strong solution of silver nitrate, which created a tenacious coating of very light-sensitive silver chloride that darkened where it was exposed to light. Whether used to create shadow image photograms by placing objects on it and setting it out in the sunlight, or to capture the dim images formed by a lens in a camera, it was a "printing out" process, meaning that the exposure had to continue until the desired degree of darkening had been produced. In the case of camera images, that could require an exposure of an hour or two if something more than a silhouette of objects against a bright sky was wanted. Earlier experimenters such as Thomas Wedgwood and Nicéphore Niépce had captured shadows and camera images with silver salts years before, but they could find no way to prevent their photographs from fatally darkening all over when exposed to daylight. Talbot devised several ways of chemically stabilizing his results, making them sufficiently insensitive to further exposure that direct sunlight could be used to print the negative image produced in the camera onto another sheet of salted paper, creating a positive.