Radioluminescent paint was invented in 1908 by Sabin Arnold von Sochocky and originally incorporated radium-226. Radium paint was widely used for 40 years on the faces of watches, compasses, and aircraft instruments, so they could be read in the dark. Radium is a radiological hazard, emitting gamma rays that can penetrate a glass watch dial and into human tissue. During the 1920s and 1930s, the harmful effects of this paint became increasingly clear. A notorious case involved the "Radium Girls", a group of women who painted watchfaces and later suffered adverse health effects from ingestion, in many cases resulting in death. In 1928, Dr von Sochocky himself died of aplastic anemia as a result of radiation exposure. Thousands of legacy radium dials are still owned by the public and the paint can still be dangerous if ingested in sufficient quantities, which is why it has been banned in many countries.
Radium paint used zinc sulfide phosphor, usually trace metal doped with an activator, such as copper (for green light), silver (blue-green), and more rarely copper-magnesium (for yellow-orange light). The phosphor degrades relatively fast and the dials lose luminosity in several years to a few decades; clocks and other devices available from antique shops and other sources therefore are not luminous any more. However, due to the long 1600 year half-life of the Ra-226 isotope they are still radioactive and can be identified with a Geiger counter.
The dials can be renovated by application of a very thin layer of fresh phosphor, without the radium content (with the original material still acting as the energy source); the phosphor layer has to be thin due to the light self-absorption in the material.