The photochemical mechanisms that give rise to the ozone layer were discovered by the British physicist Sydney Chapman in 1930. Ozone in the Earth's stratosphere is created by ultraviolet light striking ordinary oxygen molecules containing two oxygen atoms (O), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines with unbroken O to create ozone, O. The ozone molecule is unstable (although, in the stratosphere, long-lived) and when ultraviolet light hits ozone it splits into a molecule of O and an individual atom of oxygen, a continuing process called the ozone-oxygen cycle. Chemically, this can be described as:
About 90 percent of the ozone in the atmosphere is contained in the stratosphere. Ozone concentrations are greatest between about , where they range from about 2 to 8 parts per million. If all of the ozone were compressed to the pressure of the air at sea level, it would be only  thick.