The oldest known magnetic material, magnetite, is a ferrimagnetic substance. The tetrahedral and octahedral sites of its crystal structure exhibit opposite spin. Other known ferrimagnetic materials include yttrium iron garnet (YIG); cubic ferrites composed of iron oxides with other elements such as aluminum, cobalt, nickel, manganese, and zinc; and hexagonal or spinel type ferrites, including rhenium ferrite, ReFeO, PbFeO and BaFeO and pyrrhotite, FeS.
Ferrimagnetism can also occur in single-molecule magnets. A classic example is a dodecanuclear manganese molecule with an effective spin S = 10 derived from antiferromagnetic interaction on Mn(IV) metal centers with Mn(III) and Mn(II) metal centers.